Storage bag for polycrystalline silicon ingot, method for packing polycrystalline silicon ingot, and method for producing CZ silicon single crystal

Patent metadata

Field	Value
Publication number	US-10266964-B2
Application number	US-201515534102-A
Country	US
Kind code	B2
Filing date	Dec 4, 2015
Priority date	Dec 17, 2014
Publication date	Apr 23, 2019
Grant date	Apr 23, 2019

Abstract

In the present invention, as a bag to store polycrystalline silicon ingots, there is used a bag in which the concentration of paraffinic hydrocarbons in a concentrate of solvent-soluble components obtained by Soxhlet extraction using acetone as a solvent is lower than 300 ppmw as a value measured by GC-MS method; the concentration of antioxidants, lower than 10 ppmw; the concentration of ultraviolet absorbents, lower than 5 ppmw; and the concentration of antistatic agents and surfactants, lower than 50 ppmw. Then, when the polycrystalline silicon ingots are packed, preferably, the polycrystalline silicon ingots are put in the storage bag; thereafter, the storage bag is sealed; further, the storage bag is put and sealed in a linear low-density polyethylene bag containing an antistatic agent or a surfactant added in the bag material.

First claim

The invention claimed is:

1. A method for packing a polycrystalline silicon ingot, comprising: putting the polycrystalline silicon ingot in a first storage bag; thereafter sealing the first storage bag; further putting the first storage bag in a second storage bag; and sealing the second storage bag, wherein the first storage bag is composed of a first bag material comprising a linear low-density polyethylene, wherein the second storage bag is composed of a second bag material comprising a linear low-density polyethylene and at least one of an antistatic agent and a surfactant, and wherein a concentration of paraffinic hydrocarbons eluted from the first storage bag is lower than 300 ppmw, as measured by subjecting a sheet of 1 g cut-out as a specimen of the first storage bag to the Soxhlet extraction using acetone as the solvent for 8 hours.

2. A method for producing Czochralski (CZ) silicon single crystal, comprising: performing a Czochralski (CZ) single crystal growth process using a polycrystalline silicon ingot put and stored in a first storage bag as a raw material, wherein the first storage bag is composed of a first bag material comprising a linear low-density polyethylene, wherein a concentration of paraffinic hydrocarbons eluted from the first storage bag is lower than 300 ppmw, as determined by obtaining a concentrate by Soxhlet extraction using acetone as a solvent and then measuring the concentration by a gas chromatography-mass spectrometry (GC-MS) method, and wherein a total concentration of organic substances eluted from the first storage bag onto a surface of the polycrystalline silicon ingot is lower than 4 ppbw, as measured by a gas chromatograph-mass spectrometry (GC-MS) method.

3. A method for producing (CZ) silicon single crystal, comprising:
performing a Czochralski (CZ) single crystal growth process using a polycrystalline silicon ingot packed by a method according to claim 1 as a raw material.

4. The method according to claim 1 ,
wherein the first bag material further comprises at least one additive selected from the group consisting of an antioxidant, an ultraviolet absorbent, an antistatic agent, and a surfactant, and
wherein when the first bag material contains the antioxidant, a concentration of the antioxidant eluted from the first storage bag is lower than 10 ppmw, as determined by obtaining a concentrate by Soxhlet extraction using acetone as a solvent and then measuring the concentration by the gas chromatography-mass spectrometry (GC-MS) method.

Assignees

• Shinetsu Chemical Co

Inventors

• Miyao Shuichi
• Okada Junichi

Classifications

• C30B15/00

  Single-crystal growth by pulling from a melt, e.g. Czochralski method (under a protective fluid C30B27/00) · CPC title

• C01B33/02

  Silicon (forming single crystals or homogeneous polycrystalline material with defined structure C30B) · CPC title

• C30B29/06 Primary

  Silicon · CPC title

• B65D81/24

  Adaptations for preventing deterioration or decay of contents; Applications to the container or packaging material of food preservatives, fungicides, pesticides or animal repellants (with thermal insulation B65D81/38) · CPC title