Bioerodible magnesium alloy microstructures for endoprostheses
US-9522220-B2 · Dec 20, 2016 · US
US10260130B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-10260130-B2 |
| Application number | US-201514657360-A |
| Country | US |
| Kind code | B2 |
| Filing date | Mar 13, 2015 |
| Priority date | Mar 31, 2010 |
| Publication date | Apr 16, 2019 |
| Grant date | Apr 16, 2019 |
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Disclosed is a magnesium alloy material having excellent tensile strength and favorable ductility. Therefore, the magnesium alloy sheet material formed by rolling a magnesium alloy having a long period stacking order phase crystallized at the time of casting includes in a case where a sheet-thickness traverse section of an alloy structure is observed at a substantially right angle to the longitudinal direction by a scanning electron microscope, a structure mainly composed of the long period stacking order phase, in which, at least two or more αMg phases having thickness in the observed section of 0.5 μm or less are laminated in a layered manner with the sheet-shape long period stacking order phase.
Opening claim text (preview).
The invention claimed is: 1. A manufacturing method of a magnesium alloy sheet material comprising the steps of: forming a cast material by casting a dissolved magnesium alloy, wherein the cast material formed comprises a long period stacking order phase crystallized during said casting and a plurality of α-magnesium phases; after forming said cast material, plastic working said cast material to form a magnesium alloy sheet material having an improved tensile strength and elongation capability relative to the cast material prior to extrusion, and wherein said long period stacking order phase has a first shape; after said plastic working, performing a heat treatment to said magnesium alloy sheet material to spread out the long period stacking order phase into a sheet shape; and after said heat treatment that spreads the long period stacking order phase, rolling said magnesium alloy sheet material to either one or both of shear-deform or compression-deform the long period stacking order phase and thereby introduce a kink deformation into the long period stacking order phase which further improves tensile strength and ductility of the magnesium alloy sheet material; wherein, after rolling, said magnesium alloy sheet material comprises: in a case where a sheet-thickness traverse section of an alloy structure is observed at a substantially right angle to the longitudinal direction by a scanning electro-microscope, a structure mainly composed of said long period stacking order phase, in which at least two or more of said αMg phases having thickness in the observed section of 0.5 μm or less are laminated in a layered manner with said long period stacking order phase of the sheet shape, and wherein said magnesium alloy sheet material comprises 2 atomic % of Zn, 2 atomic % of Y, and the remaining part including Mg and unavoidable impurities. 2. The manufacturing method of the magnesium alloy sheet material according to claim 1 , wherein said heat treatment is performed within a temperature range of 400° C. or more and 500° C. or less and within a time range of 0.5 hours or more and 10 hours or less. 3. The manufacturing method of the magnesium alloy sheet material according to claim 1 , wherein said long period stacking order phase in the laminated structure has maximum thickness in the observed section of 9 μm or less. 4. The manufacturing method of the magnesium alloy sheet material according to claim 1 , wherein in the laminated structure, said long period stacking order phase of the sheet shape and said αMg phases having smaller-thickness in the observed section than said long period stacking order phase are laminated in a layered manner. 5. The manufacturing method of the magnesium alloy sheet material according to claim 1 , wherein said long period stacking order phase of the sheet shape in the laminated structure has minimum thickness in the observed section of 0.25 μm or more. 6. The manufacturing method of the magnesium alloy sheet material according to claim 1 , wherein the laminated structure includes an intermetallic compound. 7. The manufacturing method of the magnesium alloy sheet material according to claim 1 , wherein at least part of the laminated structure is shear-deformed or compression-deformed. 8. The manufacturing method of the magnesium alloy sheet material according to claim 1 , wherein at least part of the laminated structure is curved or bent. 9. The manufacturing method of the magnesium alloy sheet material according to claim 1 , wherein the laminated structure includes Mg 3 Zn 3 Y 2 , the Mg 3 Zn 3 Y 2 is spread in said long period stacking order phase or said αMg phases. 10. The manufacturing method of the magnesium alloy sheet material according to claim 1 , wherein said further improvement of tensile strength and ductility of the magnesium alloy sheet material during the rolling step comprises at least a 5% improvement in ductility. 11. The manufacturing method of the magnesium alloy sheet material according to claim 1 , wherein said further improvement of tensile strength and ductility of the magnesium alloy sheet material during the rolling step comprises at least a 10% improvement in ductility.
of magnesium or alloys based thereon · CPC title
Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working (apparatus for mechanical working of metal B21, B23, B24) · CPC title
with zinc or cadmium as the next major constituent · CPC title
containing zinc · CPC title
with a rare earth metal as the next major constituent · CPC title
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