Resin dispersion, coating material, laminate, and processes for their production

Patent metadata

Field	Value
Publication number	US-10259966-B2
Application number	US-201414512574-A
Country	US
Kind code	B2
Filing date	Oct 13, 2014
Priority date	Mar 10, 2006
Publication date	Apr 16, 2019
Grant date	Apr 16, 2019

Abstract

A resin dispersion having, dispersed in water with a 50% particle diamter of at most 0.5 μm, a polymer (C) having a hydrophilic polymer (B) or an acidic group bonded to a propylene/α-olefin copolymer (A) as a copolymer of propylene with an α-olefin other than propylene, where the copolymer (A) has a propylene content of at least 50 mol% and less than 100 mol% and the copolymer (A) has a weight average molecular weight Mw of at least 10,000 and a molecular weight distribution Mw/Mn of at most 3.5, and the resin dispersion has a surfactant content of at most 15 parts by weight per 100 parts by weight of the polymer (C).

First claim

The invention claimed is:

1. A resin dispersion having, dispersed in water with a 50% particle diameter of at most 0.5 μm, a polymer (C) having a hydrophilic polymer (B) bonded to a propylene/α-olefin copolymer (A) as a copolymer of propylene with an α-olefin other than propylene, wherein the hydrophilic polymer (B) is a polyether resin having an amino group as a reactive group, wherein:
the copolymer (A) has a propylene content of at least 50 mol % and less than 100 mol % and the copolymer (A) has a weight average molecular weight Mw of at least 10,000 and a molecular weight distribution Mw/Mn of at most 3.5 and a heat of crystal fusion ΔH of at most 60 J/g and at least 10 J/g;
the resin dispersion has a surfactant content of at most 15 parts by weight per 100 parts by weight of the polymer (C),
an amount of the hydrophilic polymer (B) bonded to the copolymer (A) is from 0.01 to 0.3 mmol/g per 1 g of the copolymer (A),
the copolymer (A) elutes at least 95% at a temperature of at most 60° C. in temperature rising elution fractionation,
the copolymer (A) elutes at most 20% at a temperature of at most 30° C. in temperature rising elution fractionation, and
the copolymer (A) is produced by means of a single-site catalyst.

2. The resin dispersion according to claim 1 , wherein the copolymer (A) has a melting point Tm of at most 100° C.

3. The resin dispersion according to claim 1 , wherein the copolymer (A) contains substantially no chlorine.

4. The resin dispersion according to claim 1 , wherein the polymer (C) is dispersed in water with a 50% particle diameter of at most 0.3 μm.

5. The resin dispersion according to claim 1 , wherein the polymer (C) has a hydrophilic polymer (B) bonded to the copolymer (A) in a ratio of (A):(B)=100:1 to 100:500 (weight ratio).

6. The resin dispersion according to claim 1 , wherein the polymer (C) is a graft copolymer having a hydrophilic polymer (B) graft-bonded to the copolymer (A).

7. The resin dispersion according to claim 1 , which contains substantially no surfactant.

8. The resin dispersion according to claim 1 , wherein the copolymer (A) elutes at most 20% at a temperature of at most 20° C. in temperature rising elution fractionation.

9. The resin dispersion according to claim 1 , wherein the copolymer (A) has a weight average molecular weight of at least 50,000.

10. A coating material containing the resin dispersion according to claim 1 .

11. A laminate having the coating material according to claim 10 , on a thermoplastic resin-molded product (F).

12. A laminate having a resin layer formed by applying and heating the resin dispersion according to claim 1 , on a thermoplastic resin-molded product (F).

13. The resin dispersion according to claim 1 , wherein the copolymer (A) elutes at most 5% at a temperature of at most 20° C. in temperature rising elution fractionation, at most 10% at a temperature of at most 30° C. in temperature rising elution fractionation, and at least 97% at a temperature of at most 60° C. in temperature rising elution fractionation.

14. A laminate having formed on a thermoplastic resin-molded product (F) a layer comprising a polymer (C) having a hydrophilic polymer (B) bonded to a propylene/α-olefin copolymer (A) as a copolymer of propylene with an α-olefin other than propylene,
wherein:
the hydrophilic polymer (B) is a polyether resin having an amino group as a reactive group, wherein the copolymer (A) has a propylene content of at least 50 mol % and less than 100 mol %, an amount of the hydrophilic polymer (B) bonded to the copolymer (A) is from 0.01 to 0.3 mmol/g per 1 g of the copolymer (A), and the copolymer (A) has a weight average molecular weight Mw of at least 10,000 a molecular eight distribution Mw/Mn of at most 3.5 and a heat of crystal fusion ΔH of at most 60 Jig and at least 10 J/g;
a surfactant content is at most 15 parts by weight per 100 parts by weight of the polymer (C);
the copolymer (A) elutes at least 95% at a temperature of at most 60° C. in temperature rising elution fractionation, and the copolymer (A) is produced by means of a single-site catalyst.

15. A process for producing a laminate, which comprises applying and heating the resin dispersion according to claim 1 , to form a resin layer on a thermoplastic resin-molded product (F).

16. A process for producing a laminate, which comprises applying the coating material according to claim 10 on a thermoplastic resin-molded product (F).

Assignees

• Mitsubishi Chem Corp

Inventors

• Onoe Masato
• Seko Toshiya

Classifications

• C08J7/0427

  with only one layer of a composition containing a polymer binder (with more layers C08J7/042) · CPC title

• C08F255/00

  Macromolecular compounds obtained by polymerising monomers on to polymers of hydrocarbons as defined in group C08F10/00 · CPC title

• C08F255/08

  on to polymers of olefins having four or more carbon atoms · CPC title

• C09D151/006

  grafted on to block copolymers containing at least one sequence of polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds · CPC title

• C08L51/006

  grafted on to block copolymers containing at least one sequence of polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds · CPC title