Adhesive film and method of making a graphic

Patent metadata

Field	Value
Publication number	US-10259258-B2
Application number	US-201213714657-A
Country	US
Kind code	B2
Filing date	Dec 14, 2012
Priority date	Dec 15, 2011
Publication date	Apr 16, 2019
Grant date	Apr 16, 2019

Abstract

The present application relates to an adhesive film comprising a polyvinyl chloride film having opposite first and second major sides. The first major side has an adhesive layer protected by a release liner and a primer layer arranged between the polyvinyl chloride film and the adhesive layer. The primer layer comprises an aminoplast and a polyester and/or a curing product.

First claim

The invention claimed is:

1. A conformable adhesive film comprising:
a polyvinyl chloride film having opposite first and second major sides when in a flat position, the first major side having an adhesive layer protected by a release liner and a primer layer arranged between the polyvinyl chloride film and the adhesive layer, the primer layer comprising an aminoplast and a urethane extended polyester and/or a curing product thereof, and the adhesive layer being at least one of topologically structured or having at least one microstructured surface;
wherein the conformable adhesive film adheres to uneven or complex-shaped painted surfaces without lifting or popping-up from the surface when heated at a temperature of 70 degrees Celsius for seven days.

2. The adhesive film according to claim 1 , wherein the polyvinyl chloride film is colored.

3. The adhesive film according to claim 1 , wherein the adhesive film has a thickness of more than 10 microns.

4. The adhesive film according to claim 1 wherein the aminoplast in the primer layer is an alkylated melamine formaldehyde resin.

5. The adhesive film according to claim 4 wherein the aminoplast is an n-butylated melamine formaldehyde resin.

6. The adhesive film according to claim 1 wherein the weight ratio of polyester to aminoplast in the primer layer is between 70 and 2.2.

7. The adhesive film according to claim 1 wherein the primer layer further comprises one or more white pigments.

8. The adhesive film according to claim 1 wherein the polyvinyl chloride film comprises one or more color pigments and has a color other than white or black.

9. The adhesive film according to claim 1 wherein the polyvinyl chloride film has a thickness of 25 to 100 micrometer.

10. The adhesive film according to claim 1 wherein the second major side has a clear transparent top layer comprising polyvinyl chloride.

11. The adhesive film according to claim 10 wherein the top layer has a thickness of 1to 50 micrometer.

12. The adhesive film according to claim 1 wherein the release liner comprises on the major surface contacting the adhesive layer a series of ridges along at least two in-plane directions whereby the ridges are interconnected thereby defining a number of recesses enclosed by ridges.

13. The adhesive film according to claim 12 , wherein the ridges have an average height of not more than 30 microns.

14. Method for producing a graphic on a substrate, the method comprising
providing an adhesive film as defined in claim 1 ,
removing the release liner,
applying the adhesive film on the substrate.

15. The method according to claim 14 wherein the substrate comprises an uneven surface and wherein the adhesive film is applied over the uneven surface conforming thereto.

16. The method according to claim 14 wherein the substrate comprises a vehicle.

17. The method according to claim 16 wherein the vehicle is a car, a bus, a tram, a train or an airplane.

18. A method of making a decoration comprising a plurality of discrete units of the adhesive film according to claim 1 , the method comprising:
providing a colored graphics film comprising a polyvinyl chloride film comprising on a major side thereof said adhesive layer and said primer layer arranged between said adhesive layer and the polyvinylchloride film, the adhesive layer being protected by a release liner;
cutting the polyvinyl chloride film, the primer layer and the adhesive layer of the colored graphics film to define therein said plurality of discrete units,
delaminating the cut polyvinyl chloride film, the primer layer and the adhesive layer from the release liner of said colored graphics film so as to leave the plurality of discrete units on said release liner;
applying an adhesive application tape over the said plurality of discrete units;
removing the release liner thereby leaving the plurality of discrete units attached to the adhesive application tape
applying the adhesive application tape with the plurality of discrete units to a surface to be decorated so as to sandwich the plurality of discrete units between the surface and the adhesive application tape; and
removing the application tape.

19. The method according to claim 18 wherein the surface to be decorated is uneven and wherein the colored adhesive film is applied over the uneven surface conforming thereto.

20. The method according to claim 18 wherein the surface to be decorated is the surface of a vehicle.

21. The method according to claim 20 wherein the vehicle is a motor vehicle.

22. The method according to claim 20 wherein the vehicle is a car, a bus, a train, a tram or an airplane.

23. The method according to claim 18 wherein the polyvinyl chloride film is colored and/or the primer layer is colored.

24. A method for making an adhesive film suitable for use in a method as defined in claim 1 , the method comprising (i) applying on a carrier web in the order given: the polyvinyl chloride film layer, primer layer, adhesive layer and release liner and (ii) removing the carrier web.

25. The method according to claim 24 wherein the carrier web comprises a release layer and the polyvinyl chloride film layer is applied thereto by applying a polyvinyl chloride organosol composition, heating and drying the applied organosol.

26. The method according to claim 24 , wherein the primer layer is applied by applying on the polyvinyl chloride film a composition comprising an aminoplast and a polyester, heating and drying the applied composition.

27. The method according to claim 24 , wherein the adhesive layer and release liner are applied by laminating a laminate of adhesive layer and release liner to the primer layer.

Assignees

• 3M Innovative Properties Co

Inventors

• Loescher Claus W
• Dannewitz Viktor
• Krybus Kirstin
• Kolowrot Dirk

Classifications

• Y10T156/10

  Methods of surface bonding and/or assembly therefor · CPC title

• B44C1/18 Primary

  Applying ornamental structures, e.g. shaped bodies consisting of plastic material · CPC title

• Y10T428/1424

  Halogen containing compound · CPC title

• C09J7/50

  characterised by a primer layer between the carrier and the adhesive · CPC title

• C09J2467/003

  in the primer coating · CPC title