Composition for polarizing plate, polarizing plate protective film, cellulose acylate film, polarizer, polarizing plate, and display

Patent metadata

Field	Value
Publication number	US-10253201-B2
Application number	US-201514980253-A
Country	US
Kind code	B2
Filing date	Dec 28, 2015
Priority date	Dec 26, 2014
Publication date	Apr 9, 2019
Grant date	Apr 9, 2019

Abstract

A composition for a polarizing plate containing a polymer having a partial structure represented by the following ring structure α or β in the molecule, a polarizing plate protective film, a cellulose acylate film, a polarizer, a polarizing plate, and a display;

wherein L 1 represents a single bond, —C(═O)—, —C(═S)—, an alkylene group, or an arylene group; and the symbol * designates a boning hand, or a site to which a hydrogen atom, a substituent, or a linking group binds.

First claim

The invention claimed is:

1. A composition for a polarizing plate comprising:
a polymer having a partial structure represented by the following ring structure α or β in the molecule:

wherein L 1 represents a single bond, —C(═O)—, —C(═S)—, an alkylene group, or an arylene group; and
wherein the symbol * designates a boning hand, or a site to which a hydrogen atom, a substituent, or a linking group binds;
a resin, wherein the resin is a cellulose acylate or a polyvinyl alcohol-based resin;
wherein the content of the polymer is from 0.01 to 40 parts by mass with respect to 100 parts by mass of the resin, and
wherein the mass-average molecular weight of the polymer is from 2,000 to 100,000.

2. The composition for a polarizing plate according to claim 1 , wherein the polymer has a partial structure represented by the following Formula (1) or (2) at a main chain or a side chain of the recurring unit thereof:

wherein L 1 represents a single bond, —C(═O)—, —C(═S)—, an alkylene group, or an arylene group; R 1a represents a methylene group substituted with a hetero atom, an ethylene group substituted with an electron-withdrawing group, an acyl group, an carbamoyl group in which at least one of two hydrogen atoms on the nitrogen atom is substituted with a group independently selected from an alkyl group, a cycloalkyl group, or an aryl group, an alkoxycarbonyl group, an aryloxycarbonyl group, a silyl group, or a sulfonyl group having an alkyl group or an aryl group; R 2a represents an alkyl group, an alkenyl group, a cycloalkyl group, a cycloalkenyl group, an aryl group, a nitro group, a formyl group, a heterocyclic group, or a halogen atom; R 3a and R 4a each independently represent a hydrogen atom, an alkyl group, an alkenyl group, a cycloalkyl group, a cycloalkenyl group, an aryl group, or a heterocyclic group; and each group of R 1a , R 2a , R 3a and R 4a may further have a substituent; and it is noted, however, that in Formula (1), at least one of R 1a to R 4a while in Formula (2), at least one of R 2a to R 4a is incorporated into the main chain or the side chain in the the form of a boning hand.

3. The composition for a polarizing plate according to claim 1 , wherein the polymer is a poly(meth)acrylate, a substituted polystylene, a polyvinylacylate, a polyester, a polycarbonate, a polymaleimide, or a polyurethane, each of which may be a homopolymer or a copolymer.

4. The composition for a polarizing plate according to claim 1 , wherein the polymer has a recurring unit represented by any of the following Formulae (Pa) to (Ph):

wherein, in Formulae (Pa) to (Ph), W 1 represents an univalent group in the partial structure represented by the ring structure α or β; W 2 represents a divalent group in the partial structure represented by the ring structure α or β; R represents a hydrogen atom or a methyl group; G represents —O—C(═O)—*, —O—C(═O)—O—*, —C(═O)—O—*, —C(═O)—*, or a phenylene group; here, the boning hand in the side of the symbol * binds to L; L, La 1 , La 2 , Lb 1 , Lb 2 , Lc 1 and Lc 2 each independently represent a single bond or a divalent linking group; and E 1 to E 3 each independently represent a divalent linking group.

5. The composition for a polarizing plate according to claim 4 , wherein W 1 represents an univalent group in the partial structure represented by the ring structure α or β; and W 2 represents a divalent group in the partial structure represented by the ring structure β.

6. The composition for a polarizing plate according to claim 1 , wherein the the polymer has a recurring unit represented by the following Formula (Pa1):

wherein, in formula (Pa1), R, G and L have the same meaning as the R, G and L of Formula (Pa); Moreover, L 1 , R 2a , R 3a and R 4a have the same meaning as the L 1 , R 2a , R 3a and R 4a of Formula (1).

7. The composition for a polarizing plate according to claim 4 , wherein L represents *-Ld-[C(═O)]n- or *-Ld-[-O—C(═O)]n-; Ld represents a single bond or a divalent linking group; n represents 0 or 1; and the boning hand in the side of the symbol * binds to G or a nitrogen atom.

8. The composition for a polarizing plate according to claim 1 , containing a polyvinyl alcohol-based resin, or an acylated or ketalated polyvinyl alcohol, and a dichroic dye.

9. A polarizing plate protective film formed by the composition for a polarizing plate according to claim 1 .

10. A cellulose acylate film comprising:
a cellulose acylate and a polymer having a partial structure represented by the following ring structure α or β in the molecule:

wherein L 1 represents a single bond, —C(═O)—, —C(═S)—, an alkylene group, or an arylene group; and
wherein the symbol * designates a boning hand, or a site to which a hydrogen atom, a substituent, or a linking group binds, and
wherein the mass-average molecular weight of the polymer is from 2,000 to 100,000.

11. The cellulose acylate film according to claim 10 , wherein the cellulose acylate film contains a laminate film having at least 2 layers, and in the case of 2 layers, either only one of the layers contains the polymer and in the case of at least 3 layers, at least one of the outer-most surface layers contains the polymer.

12. A polarizer formed by a composition for a polarizing plate according to claim 1 .

13. A polarizing plate having the polarizing plate protective film according to claim 9 .

14. A polarizing plate having a polarizer according to claim 12 .

15. A display having a polarizing plate according to claim 13 .

16. The composition for a polarizing plate according to claim 6 , wherein L represents *-Ld-[C(═O)]n- or *-Ld-[-O—C(═O)]n-; Ld represents a single bond or a divalent linking group; n represents 0 or 1; and the boning hand in the side of the symbol * binds to G or a nitrogen atom.

17. A polarizing plate having the cellulose acylate film according to claim 10 .

18. A cellulose acylate film containing a cellulose acylate and a polymer having a partial structure represented by the following ring structure α or β in the molecule:

wherein L 1 represents a single bond, —C(═O)—, —C(═S)—, an alkylene group, or an arylene group; and
wherein the symbol * designates a boning hand, or a site to which a hydrogen atom, a substituent, or a linking group binds,
wherein the cellulose acylate film further contains a resin, and the content of the polymer is from 0.01 to 40 parts by mass with respect to 100 parts by mass of the resin, and
wherein the mass-average molecular weight of the polymer is from 2,000 to 100,000.

19. A polarizing plate having the cellulose acylate film according to claim 18 .

Assignees

• Fujifilm Corp

Inventors

• Yoshida Aiko
• Shimoju Naoya
• Nojiri Mayumi
• Fukagawa Nobutaka

Classifications

• C08F220/346

  and further oxygen · CPC title

• C08L2203/16

  used for films · CPC title

• G02B5/3033

  in the form of a thin sheet or foil, e.g. Polaroid · CPC title

• G02B1/04

  made of organic materials, e.g. plastics (G02B1/08 takes precedence) · CPC title

• C08L33/14

  of esters containing halogen, nitrogen, sulfur, or oxygen atoms in addition to the carboxy oxygen · CPC title