Composition comprising HF and 2,3,3,3-tetrafluoropropene

US10252913B2 · US · B2

Patent metadata
FieldValue
Publication numberUS-10252913-B2
Application numberUS-201414772950-A
CountryUS
Kind codeB2
Filing dateFeb 21, 2014
Priority dateMar 20, 2013
Publication dateApr 9, 2019
Grant dateApr 9, 2019

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  2. Abstract

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  5. First independent claim

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Abstract

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An azeotropic or quasi-azeotropic composition including hydrogen fluoride, 2,3,3,3-tetrafluoropropene and one or more (hydro)halogen-carbon compounds including between 1 and 3 carbon atoms. Also a azeotropic or quasi-azeotropic composition including hydrogen fluoride, 2,3,3,3-tetrafluoropropene, and one or more organic compounds selected from among 1,1,1,2,2-pentafluoropropane, E-1,3,3,3-tetrafluoropropene, Z-1,3,3,3-tetrafluoropropene, 3,3,3-trifluoropropene, 3,3,3-trifluoro-2-chloropropene, E-3,3,3-trifluoro-1-chloropropene, trifluoropropyne, 1,1,1,3,3-pentafluoropropane, 1,1,1,3,3-pentafluoropropene, Z-1,1,1,2,3-pentafluoropropene and 2-chloro,1,1,1,2-tetrafluoropropane.

First claim

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The invention claimed is: 1. An azeotropic or quasi-azeotropic composition comprising hydrogen fluoride, 2,3,3,3-tetrafluoropropene, and one or more organic compounds selected from the group consisting of E-1,3,3,3-tetrafluoropropene, Z-1,3,3,3-tetrafluoropropene, 3,3,3-trifluoropropene, 3,3,3-trifluoro-2-chloropropene, E-3,3,3-trifluoro-1-chloropropene, 1,1,1,3,3-pentafluoropropane, 2-chloro,1,1,1,2-tetrafluoropropane, trifluoropropyne, Z-1,1,1,2,3-pentafluoropropene and 1,1,1,3,3-pentafluoropropene, in which the boiling point of said composition is between −20° C. and 80° C., and at a pressure of between 0.1 and 44 bar absolute. 2. The composition as claimed in claim 1 , wherein the composition comprises hydrogen fluoride, 2,3,3,3-tetrafluoropropene and one or more organic compounds chosen from E-1,3,3,3-tetrafluoropropene, Z-1,3,3,3-tetrafluoropropene, 3,3,3-trifluoropropene, 3,3,3-trifluoro-2-chloropropene, E-3,3,3-trifluoro-1-chloropropene, 1,1,1,3,3-pentafluoropropane, 2-chloro,1,1,1,2-tetrafluoropropane, trifluoropropyne, Z-1,1,1,2,3-pentafluoropropene and 1,1,1,3,3-pentafluoropropene. 3. The composition as claimed in claim 1 , wherein the composition comprises hydrogen fluoride, 2,3,3,3-tetrafluoropropene, and one or more organic compounds chosen from E-1,3,3,3-tetrafluoropropene, Z-1,3,3,3-tetrafluoropropene, 3,3,3-trifluoropropene, 3,3,3-trifluoro-2-chloropropene and E-3,3,3-trifluoro-1-chloropropene. 4. The composition as claimed in claim 1 , wherein the composition is heteroazeotropic or quasi-heteroazeotropic. 5. The composition as claimed in claim 1 , wherein the composition comprises hydrogen fluoride, 2,3,3,3-tetrafluoropropene, 1,1,1,2,2-pentafluoropropane and at least one compound chosen from E-1,3,3,3-tetrafluoropropene, Z-1,3,3,3-tetrafluoropropene, 3,3,3-trifluoropropene, 3,3,3-trifluoro-2-chloropropene, E-3,3,3-trifluoro-1-chloropropene, 1,1,1,3,3-pentafluoropropane, 2-chloro,1,1,1,2-tetrafluoropropane, trifluoropropyne, Z-1,1,1,2,3-pentafluoropropene and 1,1,1,3,3-pentafluoropropene. 6. The composition as claimed in claim 1 , wherein the composition comprises hydrogen fluoride, 2,3,3,3-tetrafluoropropene, E-1,3,3,3-tetrafluoropropene and optionally at least one compound chosen from Z-1,3,3,3-tetrafluoropropene, 3,3,3-trifluoropropene, 3,3,3-trifluoro-2-chloropropene, E-3,3,3-trifluoro-1-chloropropene, 1,1,1,3,3-pentafluoropropane, 2-chloro,1,1,1,2-tetrafluoropropane, trifluoropropyne, Z-1,1,1,2,3-pentafluoropropene and 1,1,1,3,3-pentafluoropropene. 7. The composition as claimed in claim 1 , wherein the composition comprises hydrogen fluoride, 2,3,3,3-tetrafluoropropene, Z-1,3,3,3-tetrafluoropropene and optionally at least one compound chosen from 3,3,3-trifluoropropene, 3,3,3-trifluoro-2-chloropropene, 1,1,1,3,3-pentafluoropropane and E-3,3,3-trifluoro-1-chloropropene. 8. The composition as claimed in claim 1 , wherein the composition comprises hydrogen fluoride, 2,3,3,3-tetrafluoropropene, 3,3,3-trifluoropropene and optionally at least one compound chosen from 3,3,3-trifluoro-2-chloropropene and E-3,3,3-trifluoro-1-chloropropene. 9. The composition as claimed in claim 1 , wherein the composition comprises hydrogen fluoride, 2,3,3,3-tetrafluoropropene, 3,3,3-trifluoro-2-chloropropene and optionally E-3,3,3-trifluoro-1-chloropropene. 10. The composition as claimed in claim 1 , wherein the composition comprises hydrogen fluoride, 2,3,3,3-tetrafluoropropene and E-3,3,3-trifluoro-1-chloropropene. 11. The composition as claimed in claim 1 , wherein, in which the composition comprises from 1% to 85% by weight of hydrogen fluoride and from 99% to 15% by weight of the sum of the organic compounds. 12. The composition as claimed in claim 1 , wherein, in which the composition comprises from 5% to 80% by weight of hydrogen fluoride and from 95% to 20% by weight of the sum of the organic compounds. 13. The composition as claimed in claim 1 , wherein, in which the boiling point of said composition is between 0° C. and 40° C. and at a pressure of between 0.7 and 18 bar absolute. 14. The composition as claimed in claim 1 , wherein, in which the boiling point of said composition is between 0° C. and 40° C. and at a pressure of between 0.9 and 12.5 bar absolute. 15. The composition as claimed in claim 1 , comprising two or more organic compounds selected from the group consisting of E-1,3,3,3-tetrafluoropropene, Z-1,3,3,3-tetrafluoropropene, 3,3,3-trifluoropropene, 3,3,3-trifluoro-2-chloropropene, E-3,3,3-trifluoro-1-chloropropene, 1,1,1,3,3-pentafluoropropane, 2-chloro,1,1,1,2-tetrafluoropropane, trifluoropropyne, Z-1,1,1,2,3-pentafluoropropene and 1,1,1,3,3-pentafluoropropene. 16. An azeotropic or quasi-azeotropic composition comprising hydrogen fluoride, 2,3,3,3-tetrafluoropropene and three or more organic compounds selected from the group consisting of 1,1,1,2,2-pentafluoropropane, E-1,3,3,3-tetrafluoropropene, Z-1,3,3,3-tetrafluoropropene, 3,3,3-trifluoropropene, 3,3,3-trifluoro-2-chloropropene, E-3,3,3-trifluoro-1-chloropropene, 1,1,1,3,3-pentafluoropropane, 2-chloro,1,1,1,2-tetrafluoropropane, trifluoropropyne, Z-1,1,1,2,3-pentafluoropropene and 1,1,1,3,3-pentafluoropropene.

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What does patent US10252913B2 cover?
An azeotropic or quasi-azeotropic composition including hydrogen fluoride, 2,3,3,3-tetrafluoropropene and one or more (hydro)halogen-carbon compounds including between 1 and 3 carbon atoms. Also a azeotropic or quasi-azeotropic composition including hydrogen fluoride, 2,3,3,3-tetrafluoropropene, and one or more organic compounds selected from among 1,1,1,2,2-pentafluoropropane, E-1,3,3,3-tetraf…
Who is the assignee on this patent?
Arkema France
What technology area does this patent fall under?
Primary CPC classification C01B7/191. Mapped technology areas include Chemistry & Metallurgy.
When was this patent published?
Publication date Tue Apr 09 2019 00:00:00 GMT+0000 (Coordinated Universal Time) (B2). Legal status and post-grant events are not shown on this page.
What related patents are in patentsdb?
We list 12 related publications on this page (citations in our corpus or others sharing the same primary CPC).