Method of manufacturing electrode

Patent metadata

Field	Value
Publication number	US-10243214-B2
Application number	US-201213480628-A
Country	US
Kind code	B2
Filing date	May 25, 2012
Priority date	Jun 3, 2011
Publication date	Mar 26, 2019
Grant date	Mar 26, 2019

Abstract

To increase the conductivity and electric capacity of an electrode which includes active material particles and the like and is used in a battery, a graphene net including 1 to 100 graphene sheets is used instead of a conventionally used conduction auxiliary agent and binder. The graphene net which has a two-dimensional expansion and a three-dimensional structure is more likely to touch active material particles or another conduction auxiliary agent, thereby increasing the conductivity and the bonding strength between active material particles. This graphene net is obtained by mixing graphene oxide and active material particles and then heating the mixture in a vacuum or a reducing atmosphere.

First claim

The invention claimed is:

1. A method of manufacturing an electrode comprising a graphene net, comprising steps of:
making a mixture of graphene oxide and a plurality of active material particles;
applying the mixture onto a current collector after making the mixture; and
heating the mixture at 200° C. or higher after applying the mixture, wherein the graphene oxide is reduced by heating the mixture,
wherein the plurality of active material particles comprises lithium-containing composite oxide.

2. The method of manufacturing the electrode according to claim 1 ,
further comprising a step of adding a conduction auxiliary agent comprising acetylene black, graphite particles, or carbon fibers to the mixture.

3. The method of manufacturing the electrode according to claim 1 ,
further comprising a step of adding a binder comprising a polymer organic compound to the mixture.

4. The method of manufacturing the electrode according to claim 1 ,
wherein surfaces of the plurality of active material particles are coated with a conductive film comprising carbon.

5. The method of manufacturing the electrode according to claim 1 ,
wherein a proportion of elements other than carbon and hydrogen in the graphene net is lower than or equal to 15 atomic %.

6. The method of manufacturing the electrode according to claim 1 ,
wherein an average particle size of the plurality of active material particles is smaller than or equal to 150 nm.

7. The method of manufacturing the electrode according to claim 1 ,
wherein an average particle size of the plurality of active material particles is greater than or equal to 20 nm and smaller than or equal to 100 nm.

8. The method of manufacturing the electrode according to claim 1 ,
wherein the plurality of active material particles are particles of lithium cobaltate, lithium iron phosphate, or lithium manganese phosphate.

9. The method of manufacturing the electrode according to claim 1 ,
wherein the heating step is performed under a vacuum or a reducing atmosphere.

10. The method of manufacturing the electrode according to claim 1 ,
wherein the graphene net has a portion partially wrapped around the active material particles, and
wherein the graphene net includes an open portion exposing the active material particles.

11. A method of manufacturing an electrode, comprising steps of:
making a mixture of graphene oxide and a plurality of active material particles;
applying the mixture onto a current collector after making the mixture; and
reducing the mixture on the current collector so as to form a graphene net after applying the mixture,
wherein the current collector comprises aluminum, and
wherein the plurality of active material particles comprises lithium-containing composite oxide.

12. The method of manufacturing the electrode according to claim 11 ,
further comprising a step of adding a conduction auxiliary agent comprising acetylene black, graphite particles, or carbon fibers to the mixture.

13. The method of manufacturing the electrode according to claim 11 ,
further comprising a step of adding a binder comprising a polymer organic compound to the mixture.

14. The method of manufacturing the electrode according to claim 11 ,
wherein surfaces of the plurality of active material particles are coated with a conductive film comprising carbon.

15. The method of manufacturing the electrode according to claim 11 ,
wherein a proportion of elements other than carbon and hydrogen in the graphene net is lower than or equal to 15 atomic %.

16. The method of manufacturing the electrode according to claim 11 ,
wherein an average particle size of the plurality of active material particles is smaller than or equal to 150 nm.

17. The method of manufacturing the electrode according to claim 11 ,
wherein an average particle size of the plurality of active material particles is greater than or equal to 20 nm and smaller than or equal to 100 nm.

18. The method of manufacturing the electrode according to claim 11 ,
wherein the plurality of active material particles are particles of lithium cobaltate, lithium iron phosphate, or lithium manganese phosphate.

19. The method of manufacturing the electrode according to claim 11 ,
wherein the reducing step is performed under a vacuum or a reducing atmosphere.

20. The method of manufacturing the electrode according to claim 11 ,
wherein the graphene net has a portion partially wrapped around the active material particles, and
wherein the graphene net includes an open portion exposing the active material particles.

21. A method of manufacturing an electrode, comprising steps of:
making a slurry comprising a piece of graphene oxide and a particle of an active material;
applying the slurry onto a current collector to form an active material layer comprising the piece of graphene oxide and the particle of the active material after making the slurry; and
reducing the graphene oxide in the active material layer.

22. The method of manufacturing an electrode according to claim 21 ,
wherein the slurry consists of the piece of graphene oxide, the particle of the active material, and a solvent by making the slurry.

23. The method of manufacturing an electrode according to claim 21 ,
wherein the active material is a positive electrode material, and
wherein an average particle size of the particle of the active material is smaller than or equal to 150 nm.

24. A method of manufacturing a power storage device, comprising steps of:
manufacturing an electrode according to claim 21 ; and
providing a negative electrode through a separator interposed therebetween.

Assignees

• Todoriki Hiroatsu
• Momo Junpei
• Oguni Teppei
• Inoue Nobuhiro
• Semiconductor Energy Lab

Inventors

• Todoriki Hiroatsu
• Momo Junpei
• Oguni Teppei
• Inoue Nobuhiro

Classifications

• H01M4/625

  Carbon or graphite · CPC title

• H01M10/0525

  Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries · CPC title

• H01M4/587

  for inserting or intercalating light metals · CPC title

• H01M4/525

  of mixed oxides or hydroxides containing iron, cobalt or nickel for inserting or intercalating light metals, e.g. LiNiO2, LiCoO2 or LiCoOxFy · CPC title

• H01M4/627

  Expanders for lead-acid accumulators · CPC title