Method for forming positive electrode for lithium-ion secondary battery

Patent metadata

Field	Value
Publication number	US-9373834-B2
Application number	US-201213710497-A
Country	US
Kind code	B2
Filing date	Dec 11, 2012
Priority date	Dec 16, 2011
Publication date	Jun 21, 2016
Grant date	Jun 21, 2016

Abstract

To provide a positive electrode for a lithium-ion secondary battery, which is highly filled with a positive electrode active material and has a high-density positive electrode active material layer. To provide a lithium-ion secondary battery having high capacity and improved cycle characteristics with use of the positive electrode. After graphene oxide is dispersed in a dispersion medium, a positive electrode active material is added and mixed to form a mixture. A binder is added to the mixture and mixed to form a positive electrode paste. The positive electrode paste is applied to a positive electrode current collector and the dispersion medium contained in the positive electrode paste is evaporated, and then, the graphene oxide is reduced, so that a positive electrode active material layer containing graphene is formed over the positive electrode current collector.

First claim

What is claimed is:

1. A method for forming a positive electrode of a battery, comprising the steps of:
dispersing graphene oxide in a first medium;
adding the first medium comprising the graphene oxide to form a first mixture comprising the graphene oxide and the positive electrode active material;
mixing the first mixture to reduce aggregation of the positive electrode active material and the graphene oxide;
adding a binder and a second medium to the first mixture to form a second mixture after mixing the first mixture;
applying the second mixture to a positive electrode current collector; and
drying the second mixture after applying the second mixture to the positive electrode current collector to form a positive electrode active material layer over the positive electrode current collector so that at least a part of the graphene oxide is reduced in the positive electrode active material layer.

2. The method for forming the positive electrode of the battery according to claim 1 ,
wherein the positive electrode active material is lithium iron phosphate, LiFeO 2 , LiCoO 2 , LiNiO 2 , LiMn 2 O 4 , V 2 O 5 , Cr 2 O 5 , MnO 2 , LiMPO 4 , Li (2-j) MSiO 4 , or a lithium-containing composite oxide having an olivine structure,
wherein M is one or more of Fe, Mn, Co, and Ni, and
wherein j is equal to 2 or less.

3. The method for forming the positive electrode of the battery according to claim 1 , wherein the binder is a polymer organic compound.

4. The method for forming the positive electrode of the battery according to claim 1 , wherein the binder is polyvinylidene fluoride.

5. The method for forming the positive electrode of the battery according to claim 1 , wherein the battery is a lithium ion secondary battery.

6. The method for forming the positive electrode of the battery according to claim 1 , wherein the graphene oxide comprises one or more groups selected from an epoxy group, a carbonyl group, a carboxyl group, and a hydroxyl group.

7. The method for forming the positive electrode of the battery according to claim 1 , wherein a proportion of oxygen in the reduced graphene oxide is higher than or equal to 2% and lower than or equal to 11%.

8. The method for forming the positive electrode of the battery according to claim 1 , wherein the first medium and the second medium are a same material.

9. The method for forming the positive electrode of the battery according to claim 1 , wherein the second mixture comprises the first medium in the step of adding the binder and the second medium.

10. A method for manufacturing a battery comprising a positive electrode, a negative electrode, an electrolyte solution, and a separator,
wherein a method of forming the positive electrode comprises the steps of:
dispersing graphene oxide in a first medium;
adding a positive electrode active material to the first medium comprising the graphene oxide to form a first mixture comprising the graphene oxide and the positive electrode active material;
mixing the first mixture to reduce aggregation of the positive electrode active material and the graphene oxide;
adding a binder and a second medium to the first mixture to form a second mixture after mixing the first mixture;
applying the second mixture to a positive electrode current collector; and
drying the second mixture after applying the second mixture to the positive electrode current collector to form a positive electrode active material layer over the positive electrode current collector so that at least a part of the graphene oxide is reduced to be graphene in the positive electrode active material layer.

11. The method for manufacturing the battery according to claim 10 ,
wherein the positive electrode active material is lithium iron phosphate, LiFeO 2 , LiCoO 2 , LiNiO 2 , LiMn 2 O 4 , V 2 O 5 , Cr 2 O 5 , MnO 2 , LiMPO 4 , Li (2-j) MSiO 4 , or a lithium-containing composite oxide having an olivine structure,
wherein M is one or more of Fe, Mn, Co, and Ni, and
wherein j is equal to 2 or less.

12. The method for manufacturing the battery according to claim 10 , wherein the binder is a polymer organic compound.

13. The method for manufacturing the battery according to claim 10 , wherein the binder is polyvinylidene fluoride.

14. The method for manufacturing the battery according to claim 10 , wherein the battery is a lithium ion secondary battery.

15. The method for forming the battery according to claim 10 , wherein a proportion of oxygen in the reduced graphene oxide is higher than or equal to 2% and lower than or equal to 11%.

16. The method for forming the battery according to claim 10 , wherein the first medium and the second medium are a same material.

17. The method for forming the positive electrode of the battery according to claim 10 , wherein the second mixture comprises the first medium in the step of adding the binder and the second medium.

18. A method for forming a positive electrode of a battery, comprising the steps of:
mixing a first mixture comprising a positive electrode active material, graphene oxide and a first medium so that aggregation of the positive electrode active material and the graphene oxide is reduced in comparison with aggregation of the positive electrode active material before mixing the first mixture;
adding a binder and a second medium to the first mixture to form a second mixture after mixing the first mixture;
applying the second mixture to a positive electrode current collector; and
drying the second mixture after applying the second mixture to the positive electrode current collector to form a positive electrode active material layer over the positive electrode current collector so that at least a part of the graphene oxide is reduced in the positive electrode active material layer.

19. The method for manufacturing the positive electrode of the battery according to claim 18 ,
wherein the positive electrode active material is lithium iron phosphate, LiFeO 2 , LiCoO 2 , LiNiO 2 , LiMn 2 O 4 , V 2 O 5 , Cr 2 O 5 , MnO 2 , LiMPO 4 , Li (2-j) MSiO 4 , or a lithium-containing composite oxide having an olivine structure,
wherein M is one or more of Fe, Mn, Co, and Ni, and
wherein j is equal to 2 or less.

20. The method for manufacturing the positive electrode of the battery according to claim 18 , wherein the binder is polyvinylidene fluoride.

21. The method for manufacturing the positive electrode of the battery according to claim 18 , wherein the battery is a lithium ion secondary battery.

22. The method for forming the positive electrode of the battery according to claim 18 , wherein a proportion of oxygen in the reduced graphene oxide is higher than or equal to 2% and lower than or equal to 11%.

23. The method for forming the positive electrode of the battery according to claim 18 , wherein the first medium and the second medium are a same material.

24. The method for forming the positive electrode of the battery according to claim 18 , wherein the second mixture comprises the first medium in the step of adding the binder and the second medium.

Assignees

• Semiconductor Energy Lab

Inventors

• Yamakaji Masaki
• Yatabe Rika
• Todoriki Hiroatsu

Classifications

• H01M2004/028

  Positive electrodes · CPC title

• H01M10/0525

  Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries · CPC title

• H01M4/625

  Carbon or graphite · CPC title

• H01M4/5825

  Oxygenated metallic salts or polyanionic structures, e.g. borates, phosphates, silicates, olivines · CPC title

• H01M4/1397 Primary

  of electrodes based on inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy · CPC title