Apparatus and methods of collecting and sampling hydrocarbon fluids

Patent metadata

Field	Value
Publication number	US-10241010-B2
Application number	US-201514676577-A
Country	US
Kind code	B2
Filing date	Apr 1, 2015
Priority date	Apr 4, 2014
Publication date	Mar 26, 2019
Grant date	Mar 26, 2019

Abstract

Methods and apparatus for the collection, transportation, and analysis of gas samples which may be required in various scientific, environmental, and natural resource contexts is provided. An isolating container for removing a component from a fluid sample includes a body defining a sampling chamber having a first end and a second end; a first valve assembly coupled to the first end; a reactant material positioned within the sampling chamber for reacting with the component; and a second valve assembly coupled to the second end, wherein the fluid sample enters the sampling chamber through the first valve assembly and exits through the second valve assembly.

First claim

The invention claimed is:

1. A sampling assembly, comprising:
an isolating container for removing a component from a fluid sample containing hydrocarbons, comprising:
a body defining a sampling chamber having a first end and a second end;
a first valve assembly coupled to the first end;
a reactant material positioned within the sampling chamber for reacting with the component, wherein the reactant material is substantially unreactive with hydrocarbons in the fluid sample; and
a second valve assembly coupled to the second end, wherein the hydrocarbons of the fluid sample enters the sampling chamber through the first valve assembly and exits through the second valve assembly, wherein the hydrocarbons of the fluid sample exiting through the second valve assembly is collected for isotopic analysis;

a syringe for supplying the fluid sample to the first end of the isolating containing container; and
a sample container connected to the second end for collecting the hydrocarbons of the fluid sample exiting the second end.

2. The isolating container of claim 1 , wherein at least one of the first valve assembly and the second valve assembly is a self-closing valve assembly.

3. The isolating container of claim 2 , wherein at least one of the first valve assembly and the second valve assembly comprises a Luer activated valve.

4. The isolating container of claim 1 , further comprising a filtering material positioned within the sampling chamber.

5. The isolating container of claim 4 , wherein the filtering material is selected from the group consisting of: polyethylene (PE) and polytetrafluoroethylene (PTFE) based materials.

6. The isolating container of claim 1 , wherein the component is hydrogen sulfide (H 2 S) and the reactant material converts hydrogen sulfide (H 2 S) to an inert form.

7. The isolating container of claim 1 , wherein less than 5% of the hydrocarbons in the fluid sample are affected isotopically by the reactant material.

8. The isolating container of claim 1 , wherein less than 2% of the hydrocarbons in the fluid sample are affected isotopically by the reactant material.

9. The isolating container of claim 8 , wherein the reactant material is iron III oxide hydrate (2FeO(OH)).

10. The isolating container of claim 9 , wherein the fluid sample comprises natural gas.

11. The isolating container of claim 1 , wherein less than 1% of the hydrocarbons in the fluid sample are affected isotopically by the reactant material.

12. The isolating container of claim 1 , wherein an effect of the reactant material on a hydrocarbon ratio of the fluid sample is less than 5%.

13. The isolating container of claim 1 , wherein the reactant material is iron III oxide hydrate (2FeO(OH)).

14. The sampling assembly of claim 1 , wherein the reactant material converts the component to an inert form.

15. The sampling assembly of claim 14 , wherein the reactant material is selected from the group consisting of: zinc carbonate hydroxide (Zn 5 (CO 3 ) 2 (OH) 6 ), iron III oxide hydrate (2FeO(OH)), zinc acetate (2(C 2 H 3 O 2 ) 2 Zn), iron oxide (Fe 2 O3), and combinations thereof.

Assignees

• Weatherford Tech Holdings Llc

Inventors

• Coleman Todd M
• Rice Corben C
• Coleman Dennis D

Classifications

• G01N31/224

  for investigating presence of dangerous gases · CPC title

• G01N1/22 Primary

  in the gaseous state {(specially adapted for biological material G01N33/497; measuring breath flow A61B5/087)} · CPC title

• G01N1/2202 Primary

  involving separation of sample components during sampling · CPC title

• B65D75/5883

  connected to the package at the sealed junction of two package walls · CPC title

• G01N1/405

  by adsorption or absorption · CPC title