Bromide removal from aqueous solutions

Patent metadata

Field	Value
Publication number	US-10240242-B2
Application number	US-201515510926-A
Country	US
Kind code	B2
Filing date	Sep 11, 2015
Priority date	Sep 11, 2014
Publication date	Mar 26, 2019
Grant date	Mar 26, 2019

Abstract

Systems and processes for removing and purifying bromide from an aqueous bromide solution are described. Electrochemistry is used to either convert bromide to bromine to allow its extraction in an organic phase, or to cause deposition of bromine onto an electrode. In either case, once removed from the aqueous bromide solution, the bromide can be recovered and purified.

First claim

What is claimed is:

1. A process for removing and purifying bromide from an aqueous bromide solution, comprising the steps of:
contacting an aqueous bromide solution with a suitable organic solvent and an electrode positioned between the aqueous bromide solution and the suitable organic solvent;
applying a positive voltage to the electrode causing bromine to form and migrate into the suitable organic solvent to form a concentrated organic bromine solution; and
removing the concentrated organic bromine solution from contact with the aqueous bromide solution and the electrode.

2. The process of claim 1 , wherein the suitable organic solvent is carbon tetrachloride, chloroform, or carbon disulfide.

3. The process of claim 1 , wherein the electrode is a porous electrode.

4. The process of claim 1 , wherein the electrode comprises platinum.

5. The process of claim 1 , wherein the aqueous bromide solution, the suitable organic solvent, and the concentrated organic bromine solution are in continuous flow.

6. The process of claim 1 , wherein the aqueous bromide solution is brine.

7. The process of claim 1 , wherein a positive voltage of about 1.2 to about 1.4 volts is applied to the electrode.

8. The process of claim 1 , further comprising the steps of contacting the concentrated organic bromine solution with a water solution and an electrode positioned between the concentrated organic bromine solution and the water solution; applying a negative voltage to the electrode to cause bromide to form and migrate into the water solution to form a concentrated bromide solution; and removing the concentrated bromide solution from contact with the concentrated organic bromine solution and the electrode.

9. A system for removing and purifying bromide from an aqueous bromide solution, comprising:
a first container configured to hold an aqueous bromide solution layer and a suitable organic solvent layer, and a first electrode positioned between the aqueous bromide solution layer and the suitable organic solvent layer, wherein the suitable organic solvent layer becomes a concentrated organic bromine solution layer upon applying a voltage to the first electrode;
a second container configured to hold a concentrated organic bromine solution layer and a water solution layer, and a second electrode positioned between the concentrated organic bromine solution layer and the water solution layer;
means for transferring the concentrated organic bromine solution layer from the first container to the second container; and
a power source for applying a voltage to the first electrode and the second electrode.

10. The system of claim 9 , wherein the suitable organic solvent used in the suitable organic solvent layer is carbon tetrachloride, chloroform, or carbon disulfide.

11. The system of claim 9 , wherein the first and second electrodes are porous electrodes.

12. The system of claim 9 , wherein the first and second electrodes comprise platinum.

13. A process for removing and purifying bromide from an aqueous bromide solution, comprising the steps of:
contacting an aqueous bromide solution with an electrode; applying a positive voltage to the electrode to form a bromine-coated electrode as a result of bromine adsorption; moving the bromine-coated electrode to a water solution, and applying a negative voltage to the bromine-coated electrode to release bromide into the water solution, thereby forming a concentrated bromide solution.

14. The process of claim 13 , wherein the electrode comprises silver or bismuth.

15. The process of claim 13 , wherein the aqueous bromide solution and the water solution are in continuous flow.

16. The process of claim 13 , wherein the aqueous bromide solution is brine.

17. The process of claim 13 , wherein the electrode comprises a separately polarizable unit of a multi-electrode conveyor belt.

18. The process of claim 13 , wherein a positive voltage of about 0.1 to about 1.0 volts is applied to the electrode to form a bromine-coated electrode.

19. A system for removing and purifying bromide from an aqueous bromide solution, comprising:
a first container holding an aqueous bromide solution;
an electrode;
a second container holding water; and
a power source for applying a voltage to the electrode;
wherein the purified bromide solution is prepared by positioning the electrode in the first container and positively polarizing the electrode, providing sufficient time for bromine to adhere to the electrode, and then positioning the electrode in the second container and negatively polarizing the electrode to release bromide into the water to form a purified bromide solution.

20. The system of claim 19 , wherein the electrode comprises silver or bismuth.

21. The system of claim 19 , wherein the electrode comprises a separately polarizable unit of a multi-electrode conveyor belt that is in contact with the solutions in both the first and second containers.

22. The system of claim 21 , wherein the first and second containers are configured for continuous flow.

Assignees

• Univ Case Western Reserve

Inventors

• Scherson Daniel A

Classifications

• C25B9/06

  Chemistry & Metallurgy · mapped topic

• B01D11/0492

  Applications, solvents used · CPC title

• C25B11/035

  Chemistry & Metallurgy · mapped topic

• C02F2001/46123

  Movable electrodes · CPC title

• C02F1/469

  by electrochemical separation, e.g. by electro-osmosis, electrodialysis, electrophoresis · CPC title