Preparation of nanoparticle materials

Patent metadata

Field	Value
Publication number	US-10227529-B2
Application number	US-201615217387-A
Country	US
Kind code	B2
Filing date	Jul 22, 2016
Priority date	Apr 30, 2004
Publication date	Mar 12, 2019
Grant date	Mar 12, 2019

Abstract

A method of producing nanoparticles comprises effecting conversion of a nanoparticle precursor composition to the material of the nanoparticles. The nanoparticle precursor composition comprises a first precursor species containing a group 13 element to be incorporated into the nanoparticles and a separate second precursor species containing either a group 15 or a group 16 element to be incorporated into the nanoparticles. The conversion is effected in the presence of molecular cluster compounds under conditions permitting seeding and growth of the nanoparticles on the molecular cluster compounds. The molecular cluster compounds and nanoparticle precursor composition can be dissolved in a solvent at a first temperature to form a solution and the temperature of the solution can then be increased to a second temperature sufficient to initiate seeding and growth of the nanoparticles on the molecular cluster compounds.

First claim

What is claimed is:

1. A method of producing nanoparticles comprising:
effecting conversion of a nanoparticle precursor composition to a material of the nanoparticles,
said precursor composition comprising a first precursor species containing a group 13 element to be incorporated into the nanoparticles and a separate second precursor species containing either a group 15 or a group 16 element to be incorporated into the nanoparticles,
wherein said conversion is effected in the presence of molecular cluster compounds under conditions permitting seeding and growth of the nanoparticles on the molecular cluster compounds.

2. The method of claim 1 , wherein the Group 13 element is indium (In) and the Group 15 element is phosphorus (P).

3. The method of claim 1 , wherein the Group 13 element is indium (In) and the Group 16 element is sulfur (S).

4. The method of claim 1 , wherein the Group 13 element is indium (In) and the Group 16 element is selenium (Se).

5. The method of claim 1 , wherein the first precursor species comprises a group 13 element and a carboxylate.

6. The method of claim 5 , wherein the carboxylate is acetate.

7. The method of claim 5 , wherein the carboxylate is stearate.

8. The method of claim 1 , wherein the second precursor species comprises PH 3 .

9. The method of claim 1 , wherein the second precursor species comprises a group 15 element and a trimethylsilyl group.

10. The method of claim 1 , wherein said conversion effected in the presence of a molecular cluster compound under conditions permitting seeding and growth of quaternary or ternary nanoparticles on the molecular cluster compounds.

11. A method of producing nanoparticles comprising:
effecting conversion of a of a nanoparticle precursor composition to a material of the nanoparticles,
said precursor composition comprising a first precursor species containing a group 13 element to be incorporated into the nanoparticles and a separate second precursor species containing either a group 15 or a group 16 element to be incorporated into the nanoparticles,
wherein said conversion is effected in the presence of molecular cluster compounds under conditions permitting seeding and growth of the nanoparticles on the molecular cluster compounds, and
wherein the molecular cluster compounds and nanoparticle precursor composition are dissolved in a solvent at a first temperature to form a solution and the temperature of the solution is then increased to a second temperature which is sufficient to initiate seeding and growth of the nanoparticles on the molecular cluster compounds.

12. The method of claim 11 , wherein the Group 13 element is indium (In) and the Group 15 element is phosphorus (P).

13. The method of claim 11 , wherein the Group 13 element is indium (In) and the Group 16 element is sulfur (S).

14. The method of claim 11 , wherein the Group 13 element is indium (In) and the Group 16 element is selenium (Se).

15. The method of claim 11 , wherein the first precursor species comprises a group 13 element and a carboxylate.

16. The method of claim 15 , wherein the carboxylate is acetate.

17. The method of claim 15 , wherein the carboxylate is stearate.

18. The method of claim 11 , wherein the second precursor species comprises PH 3 .

19. The method of claim 11 , wherein the second precursor species comprises a group 15 element and a trimethylsilyl group.

20. The method of claim 11 , wherein said conversion effected in the presence of a molecular cluster compound under conditions permitting seeding and growth of quaternary or ternary nanoparticles on the molecular cluster compounds.

Assignees

• Nanoco Technologies Ltd

Inventors

• O'Brien Paul
• Pickett Nigel

Classifications

• Y10T428/2982

  Particulate matter [e.g., sphere, flake, etc.] · CPC title

• C01P2004/84

  one phase coated with the other · CPC title

• C09K11/621

  Chalcogenides · CPC title

• C09K11/7492

  Arsenides; Nitrides; Phosphides · CPC title

• Y10S977/774

  Exhibiting three-dimensional carrier confinement, e.g. quantum dots · CPC title