Sheet for thin layer transfer, electrode catalyst layer-carrying sheet for thin layer transfer, method for producing sheet for thin layer transfer, and method for producing membrane electrode assembly

Patent metadata

Field	Value
Publication number	US-10224551-B2
Application number	US-201415027955-A
Country	US
Kind code	B2
Filing date	Jul 18, 2014
Priority date	Oct 11, 2013
Publication date	Mar 5, 2019
Grant date	Mar 5, 2019

Abstract

The present invention provides a sheet for thin layer transfer ( 10 ) including: a substrate ( 1 ) including a thin metal film or a thin heat-resistant resin film; and a fluorine resin layer ( 2 ) provided on at least one side of the substrate ( 1 ). The sheet for thin layer transfer thus provided can have reduced surface irregularities and be less prone to deteriorate even when subjected to repeated thermal transfer by thermocompression bonding.

First claim

The invention claimed is:

1. A sheet for thin layer transfer, comprising:
a substrate comprising a metal film or a heat-resistant resin film that is capable of withstanding a temperature of 350 degrees Celsius; and
a fluorine resin layer provided on at least one side of the substrate, the fluorine resin layer formed of a fluorine resin sintered at a temperature equal to or higher than a melting point of the fluorine resin, the fluorine resin containing polytetrafluoroethylene having a number-average molecular weight of 5,000,000 or more, and the fluorine resin layer directly adhered to the metal film or the heat-resistant resin film, wherein
the fluorine resin layer is configured to remain in the sheet after thermocompression of the sheet,
the sheet is configured such that the fluorine resin layer remains on the at least one side of the substrate when the sheet is immersed in acetone, and
the sheet satisfies at least one of following conditions (A) and (B):
(A) the substrate is a polyimide film, and
(B) the sheet has a tensile strength of 60 MPa or more.

2. The sheet for thin layer transfer according to claim 1 , wherein the fluorine resin layer is provided on both sides of the substrate.

3. The sheet for thin layer transfer according to claim 2 , wherein the fluorine resin layer is formed so as to have two portions respectively provided on both sides of the substrate, the two portions being connected to each other.

4. The sheet for thin layer transfer according to claim 1 , wherein the substrate is an aluminum film or a stainless steel film.

5. The sheet for thin layer transfer according to claim 1 , wherein the substrate is a polyimide film.

6. The sheet for thin layer transfer according to claim 1 , having a surface formed by the fluorine resin layer, the surface having an arithmetic mean roughness Ra of 1 μm or less, and the arithmetic mean roughness Ra being measured by a method according to JIS B 0601-1994.

7. The sheet for thin layer transfer according to claim 1 , having a tensile strength of 60 MPa or more.

8. An electrode catalyst layer-carrying sheet for thin layer transfer, comprising:
the sheet for thin layer transfer according to claim 1 ; and
an electrode catalyst layer for use in a membrane electrode assembly of a fuel cell, the electrode catalyst layer being stacked on the sheet for thin layer transfer.

9. The electrode catalyst layer-carrying sheet for thin layer transfer according to claim 8 , wherein the electrode catalyst layer comprises at least a polymer electrolyte and catalytic material-supporting particles.

10. A method for producing a sheet for thin layer transfer, the method comprising:
a step of providing a substrate including a metal film or a heat-resistant resin film that is capable of withstanding a temperature of 350 degrees Celsius;
an immersion coating step of immersing the substrate in a dispersion of a fluorine resin, the fluorine resin containing polytetrafluoroethylene having a number-average molecular weight of 5,000,000;
a heat drying step of, after the immersion coating step, heating a sheet including the substrate coated with the fluorine resin so as to remove a dispersion medium of the dispersion; and
a sintering step of, after the heat drying step, heating the sheet at a temperature equal to or higher than a melting point of the fluorine resin to form a fluorine resin layer that is directly adhered to the metal film or the heat-resistant resin film, wherein
the fluorine resin layer is configured to remain in the sheet after thermocompression of the sheet,
the fluorine resin layer is configured to remain on the at least one side of the substrate when the sheet immersed in acetone, and
the sheet satisfies at least one of following conditions (A) and (B):
(A) the substrate is a polyimide film, and
(B) the sheet has a tensile strength of 60 MPa or more.

11. The method for producing a sheet for thin layer transfer according to claim 10 , comprising two to five repetitions of a sequence of steps consisting of the immersion coating step, the heat drying step, and the sintering step.

12. A method for producing a membrane electrode assembly, the method comprising:
a catalyst layer stacking step of stacking an electrode catalyst layer including at least a polymer electrolyte and catalytic material-supporting particles on the sheet for thin layer transfer according to claim 1 ;
an electrolyte membrane stacking step of bringing an electrolyte membrane into contact with the electrode catalyst layer stacked on the sheet for thin layer transfer;
a thermocompression bonding step of bonding the electrode catalyst layer and the electrolyte membrane together by thermocompression; and
a peeling step of peeling the sheet for thin layer transfer from the electrode catalyst layer.

Assignees

• Nitto Denko Corp

Inventors

• Kuroki Yuta

Classifications

• B32B2457/00

  Electrical equipment · CPC title

• H01M2008/1095

  Fuel cells with polymeric electrolytes · CPC title

• H01M8/1018

  Polymeric electrolyte materials · CPC title

• B32B15/04

  comprising metal as the main or only constituent of a layer, {which is} next to another layer of {the same or of} a {different material (next to a bituminous or tarry layer B32B11/08; next to a water-setting substance layer B32B13/06; next to a glass layer B32B17/061; next to a cellulosic plastic layer B32B23/042)} · CPC title

• B32B2307/302

  Conductive · CPC title