Waste sludge incinerator using pyrolysis and gasification, and relative process

Patent metadata

Field	Value
Publication number	US-10208950-B2
Application number	US-201415025835-A
Country	US
Kind code	B2
Filing date	Oct 2, 2014
Priority date	Oct 3, 2013
Publication date	Feb 19, 2019
Grant date	Feb 19, 2019

Abstract

The present invention relates to reaction equipment for the treatment of organic and/or inorganic waste of refineries or petrochemical plants comprising: •—a drying and pyrolysis device ( 4 ) which rotates around its longitudinal, tilted rotation axis (A), •—a gasification device ( 6 ) which rotates around its longitudinal, horizontal rotation axis (B), •—a combustion device ( 14 ) comprising a burner ( 13 ) having a longitudinal horizontal axis (C), •—at least one settling chamber ( 15 ) for the collection of intermediate solid residues and the accumulation of intermediate gaseous reaction products, •—at least one outlet duct of the gaseous end-products ( 16 ), at least one outlet duct of the solid end-products ( 7 ), and at least one inlet duct of the feedstock ( 2 ) •—said combustion device ( 14 ), drying and pyrolysis device ( 4 ), gasification device ( 6 ) are physically separated and positioned on three different levels, •—the longitudinal rotation axis (A) of the drying and pyrolysis device ( 4 ) is tilted with respect to both the longitudinal rotation axis (B) of the gasification device ( 6 ) and also with respect to the longitudinal axis (C) of the combustion device ( 14 ), •—the longitudinal rotation axis (B) of the gasification device ( 6 ) is parallel to the longitudinal axis (C) of the combustion device ( 14 ), •—the combustion device ( 14 ) is in fluid communication with the drying and pyrolysis device ( 4 ), •—the drying and pyrolysis device ( 4 ) comprises, in its interior, a first indirect heat exchange device ( 3 ) in which the combustion fumes coming from the combustion device ( 14 ) flow, •—at least one settling chamber ( 15 ) in fluid communication with said drying and pyrolysis device ( 4 ) and with said gasification device ( 6 ) and with said combustion device ( 14 ), •—conveying means ( 5 ) are positioned in the settling chamber ( 15 ) and put the drying and pyrolysis device ( 4 ) in fluid communication with the gasification device, •—it comprises a second heat exchange device ( 12 ) in fluid communication with the first indirect heat exchange device ( 3 ) and the combustion device ( 14 ), •—it comprises means for the suction of the intermediate gaseous reaction products, said means being positioned in the settling chamber ( 15 ).

First claim

The invention claimed is:

1. A reaction equipment, comprising:
a drying and pyrolysis device which rotates around its longitudinal, tilted rotation axis (A),
a gasification device which rotates around its longitudinal, horizontal rotation axis (B),
a combustion device comprising a burner having a longitudinal horizontal axis (C),
at least one settling chamber for the collection of intermediate solid residues and the accumulation of intermediate gaseous reaction products,
at least one outlet duct of the gaseous end-products, at least one outlet duct of the solid end-products, and at least one inlet duct of a feedstock,
wherein:
the combustion device, drying and pyrolysis device, and gasification device are physically separated and positioned on three different levels,
the longitudinal rotation axis (A) of the drying and pyrolysis device is tilted with respect to both the longitudinal rotation axis (B) of the gasification device and also with respect to the longitudinal axis (C) of the combustion device,
the longitudinal rotation axis (B) of the gasification device is parallel to the longitudinal axis (C) of the combustion device,
the combustion device is in fluid communication with the drying and pyrolysis device,
the drying and pyrolysis device comprises, in its interior, a first indirect thermal exchange device in which the combustion fumes coming from the combustion device flow,
at least one settling chamber is in fluid communication with the drying and pyrolysis device, the gasification device and the combustion device,
conveying means are positioned in the settling chamber and put the drying and pyrolysis device in fluid communication with the gasification device,
the equipment comprises a second thermal exchange device in fluid communication with the first indirect thermal exchange device and the combustion device, and
the equipment comprises means for the suction of the intermediate gaseous reaction products, the means being positioned in the settling chamber.

2. The reaction equipment according to claim 1 , wherein the rotation rate of the drying and pyrolysis device and gasification device ranges from 1 to 3 rev./min.

3. The reaction equipment according to claim 1 , wherein the inclination of the longitudinal axis (A) of the drying and pyrolysis device with respect to the longitudinal axis (B) of the gasification device, or (C) combustion device, has a variation in height of 2 cm at the most, for each meter of length.

4. The equipment according to claim 1 , wherein regulation devices are present in the settling chamber.

5. The equipment according to claim 1 , wherein the first thermal exchange device is a duct having a circular section which comprises in its interior a second duct having a circular section, coaxial to the first, with an initial conical conveyer, the ducts forming an annular area.

6. A process for the treatment of organic and/or inorganic waste of refineries or petrochemical plants the process comprising following:
a) drying and pyrolysis by indirect heating of the waste, forming a first intermediate gaseous product comprising wet syngas and a first intermediate solid residue containing char, volatile ashes and tar;
b) separating the first intermediate gaseous produced in (a) from the first intermediate solid residue and sending the solid residue to gasification;
c) performing gasification of the intermediate solid residue obtained in (a) in the presence of a comburent consisting of a mixture of air, oxygen and water, the comburent flowing in countercurrent with respect to the solid residue, and thus forming a second intermediate gaseous product comprising syngas and a final solid residue comprising ashes;
d) separating the second intermediate gaseous product produced in (c) from the final solid residue; and
e) mixing the intermediate gaseous product produced in (a) with the intermediate gaseous product produced in (c) and performing suction of at least a part of the mixture formed to be sent either to a refinery gas supply network, after possible treatment, or to combustion for self-sustaining the process for the treatment of waste products; wherein occurs in a reaction equipment, comprising:
a drying and pyrolysis device which rotates around its longitudinal, tilted rotation axis(A),
a gasification device which rotates around its longitudinal, horizontal rotation axis (B),
a combustion device comprising a burner having a longitudinal horizontal axis (C),
at least one settling chamber for the collection of intermediate solid residues and the accumulation of intermediate gaseous reaction products,
at least one outlet duct of the gaseous end-products, at least one outlet duct of the solid end-products, and at least one inlet duct of a feedstock,
wherein: the combustion device, drying and pyrolysis device, and gasification device are physically separated and positioned on three different levels,
the longitudinal rotation axis (A) of the drying and pyrolysis device is tilted with respect to both the longitudinal rotation axis (B) of the gasification device and also with respect to the longitudinal axis (C) of the combustion device,
the longitudinal rotation axis (B) of the gasification device is parallel to the longitudinal axis (C) of the combustion device,
the combustion device is in fluid communication with the drying and pyrolysis device,
the drying and pyrolysis device comprises, in its interior, a first indirect thermal exchange device in which the combustion fumes coming from the combustion device flow,
at least one settling chamber is in fluid communication with the drying and pyrolysis device, the gasification device and the combustion device,
conveying means are positioned in the settling chamber and put the drying and pyrolysis device in fluid communication with the gasification device,
the equipment comprises a second thermal exchange device in fluid communication with the first indirect thermal exchange device and the combustion device, and
the equipment comprises means for the suction of the intermediate gaseous reaction products, the means being positioned in the settling chamber.

7. The conversion process according to claim 6 , wherein the drying and the pyrolysis are carried out at temperatures ranging from 550 to 700° C.

8. The conversion process according to claim 6 , wherein the gasification is carried out at temperatures ranging from 600 to 900° C.

9. The process according to claim 6 , wherein both the drying and pyrolysis, and also the gasification are carried out at a pressure of 15-30 Pa.

10. The process according to claim 6 , wherein the waste comprises refinery sludge having the following weight composition:
humidity from 30% to 80%;
volatile material from 10% to 60%;
fixed carbon from 5 to 40;
hydrogen (H) from 2 to 10%;
sulphur (S) from 0 to 10;
nitrogen (N) from 0% to 5%;
and the following properties:
LHV (PCI in italian) from 2800 to 4500 kcal/kg; and
kinematic viscosity from 2000 to 10000 P (Poise or cSt).

11. The process according to claim 6 , which also comprises a combustion phase between a fuel selected from the group consisting of syngas, methane, LPG, and gasoil and a comburent comprising oxygen.

12. The process according to claim 6 , which comprises a recovery phase of the heat of the exhausted combustion fumes produced during the indirect heating phase of the drying and pyrolysis.

13. The process according to claim 6 , wherein in the gasification, the comburent is introduced with a progressively differentiated flowrate, greater at the inlet and almost zero at the outlet.

14. A plant, comprising:
a pre-treatment section co

Assignees

• Eni Spa

Inventors

• Massetti Felicia
• Pistelli Maria Ilaria
• Pinti Medardo

Classifications

• F23G2900/50204

  Waste pre-treatment by pyrolysis, gasification or cracking · CPC title

• F23G2201/302

  Treating pyrosolids · CPC title

• F23G2900/50001

  Combination of two or more furnaces · CPC title

• C10J3/005

  Rotary drum or kiln gasifiers · CPC title

• F23G5/04

  drying · CPC title