Process and plant for separating heavy metals from phosphoric starting material

Patent metadata

Field	Value
Publication number	US-10081545-B2
Application number	US-201314888315-A
Country	US
Kind code	B2
Filing date	May 3, 2013
Priority date	May 3, 2013
Publication date	Sep 25, 2018
Grant date	Sep 25, 2018

Abstract

A process for separating heavy metals from phosphoric starting material comprises the following steps:
(i) heating the starting material to a temperature of 600 to 1.200° C. in a first reactor ( 1 ) and withdrawing combustion gas; (ii) using the combustion gas of step (i) to preheat an alkaline source; and (iii) transferring the heated starting material of step (i) and the heated alkaline source of step (ii) to a second reactor ( 20 ), adding an elemental carbon source, heating to a temperature of 700 to 1.100° C. and withdrawing process gas and a product stream.

First claim

The invention claimed is:

1. A process for separating heavy metals from phosphoric starting material comprising the following steps:
(i) heating the starting material to a temperature of 600 to 1.200° C. in a first reactor and withdrawing combustion gas;
(ii) using the combustion gas of step (i) to preheat an alkaline source; and
(iii) transferring the heated starting material of step (i) and the heated alkaline source of step (ii) to a second reactor, adding an elemental carbon source, heating to a temperature of 700 to 1.100° C. and withdrawing process gas and a product stream.

2. The process according to claim 1 , characterized in that the starting material is pre-heated in at least a first preheating stage to a temperature of 300 to 800° C. prior to step (i).

3. The process according to claim 1 , characterized in that the starting material is pre-heated in multiple stages prior to step (i).

4. The process according to claim 1 , characterized in that the alkaline source is pre-heated in a second preheating stage to a temperature of 200 to 500° C. prior to the introduction into the second reactor.

5. The process according to claim 1 , characterized in that the alkaline source is selected from the group consisting of sodium carbonates, sodium hydroxides, potassium carbonates and potassium hydroxides or any combination thereof.

6. The process according to claim 5 , characterized in that the alkaline source is soda ash.

7. The process according to claim 1 , characterized in that the alkaline source is added in an amount of 2 to 80 wt.-% of the starting material.

8. The process according to claim 1 , characterized in that the elemental carbon source is selected from the group consisting of pulverized lignites, dry sewage sludge, dry biomass, pulverized lignite, coal and coke or any combination thereof.

9. The process according to claim 1 , characterized in that the elemental carbon source is added in an amount of 1 to 40 wt.-% of the starting material.

10. The process according to claim 2 , characterized in that the combustion gases from step (i) are fed into a cyclone separator and subsequently into a Venturi section of the first preheating stage.

11. The process according to claim 1 , characterized in that the combustion gases from step (i) are withdrawn from a cyclone separator, enter a Venturi section and are admixed with an alkaline source according to step (ii).

12. The process according to claim 1 , characterized in that the process gas in step (iii) is cooled below the condensation temperature of the heavy metal compounds to allow for their precipitation and removal.

13. The process according to claim 12 , characterized in that the heavy metal-free process gas is recycled into the first reactor.

Assignees

• Outotec Finland Oy

Inventors

• Hermann Ludwig
• Schneider Günter
• Lohrberg Dirk

Classifications

• F23G7/001

  for sludges or waste products from water treatment installations (F23G5/008 takes precedence) · CPC title

• B01J8/24

  according to "fluidised-bed" technique (B01J8/20 takes precedence) · CPC title

• C02F9/00

  Multistage treatment of water, waste water or sewage · CPC title

• F23G2201/302

  Treating pyrosolids · CPC title

• C02F11/06

  by oxidation (incinerators for burning waste liquors, e.g. sulfite liquor from paper-making plant F23G7/04) · CPC title