Pressure-dependent foam moulding of poly(meth)acrylimide particles in closed moulds for producing rigid foam cores

Patent metadata

Field	Value
Publication number	US-10207435-B2
Application number	US-201515321845-A
Country	US
Kind code	B2
Filing date	Jun 25, 2015
Priority date	Jun 27, 2014
Publication date	Feb 19, 2019
Grant date	Feb 19, 2019

Abstract

The invention relates to a process for the production of mold-foamed poly(meth)acrylimide (P(M)I) cores, in particular of polymethacrylimide (PMI) cores, which can be used by way of example in automobile construction or aircraft construction. A feature of this process is that polymer granules or polymer powder preheated under pressure are moreover charged under pressure to a compression mold where they are foamed with depressurization. In particular, a feature of the process is that it optionally uses a preferably two-shell compression mold for the heating and also for the cooling of the granules and, respectively, the rigid foam core formed therefrom.

First claim

The invention claimed is:

1. A process for the production of a rigid poly(meth)acrylimide foam core, the process comprising:
heating poly(meth)acrylimide particles to an atmospheric-pressure-foaming temperature T 1 under a pressure p 1 wherein a volume of the poly(meth)acrylimide particles increases by at most 10% by volume in 10 min,
charging the poly(meth)acrylimide particles to a mould and closing the mould, wherein the charging takes place at a pressure p 2 ,
depressurizing a space within the mould to a pressure p 3 at a temperature T 2 and foaming the particles,
cooling the space within the mould to a temperature T 3 thereby obtaining a rigid poly(meth)acrylimide foam core,
opening the mould and removing the rigid poly(meth)acrylimide foam core.

2. The process according to claim 1 , wherein the poly(meth)acrylimide particles are prefoamed poly(meth)acrylimide particles of size from 1.0 to 25.0 mm.

3. The process according to claim 1 , wherein the poly(meth)acrylimide particles are poly(meth)acrylimide suspension polymers of size from 0.1 to 1.0 mm.

4. The process according to claim 1 , wherein the foaming is performed within a time period of at most 2 min, and
wherein the process including the heating, the charging and closing, the depressurizing and foaming, and the opening and removing together are performed within a time period of from 5 to 45 min.

5. The process according to claim 1 , wherein the charging of poly(meth)acrylimide particles to the mould and closing the mould is performed before the heating of polym(meth)acrylimide particles to an atmospheric-pressure-foaming temperature T 1 .

6. The process according to claim 1 , wherein the heating, the charging and closing, the depressurizing and foaming, and the opening and removing together are performed in sequence, and
wherein the pressure p 2 is at most 10% smaller than p 1 .

7. The process according to claim 1 , wherein the temperature T 1 is from 150 to 250° C., and wherein the pressure p 1 and the pressure p 2 are from 2 to 20 bar.

8. The process according to claim 1 , wherein the temperature T 2 is from 150 to 250° C., and wherein the pressure p 3 is from 0.1 to 2.0 bar.

9. The process according to claim 1 , wherein the temperature T 2 is from 180 to 220° C., and wherein the pressure p 3 is from atmospheric pressure to 1.5 bar.

10. The process according to claim 1 , wherein during the charging the poly(meth)acrylimide particles are sucked into the mould, blown into the mould, or both.

11. The process according to claim 1 , wherein a mould fill level reached during the charging of the poly(meth)acrylimide particles to the mould is from 50 to 100%.

12. The process according to claim 1 , wherein the particles are held during the heating of poly(meth)acrylimide particles in a holding vessel at temperature T 1 and at the pressure p 1 ,
the charging of poly(meth)acrylimide particles to the mould is performed in a batchwise manner, and
after the charging a connection between the holding vessel and the mould is closed before the depressurizing of the space within the mould to a pressure p 3 is performed.

13. The process according to claim 1 , wherein the mould comprises at least two shells and each shell comprises a cavity of thickness from 2 to 20 cm which conforms to an internal shape of the mould and which covers an area of the space within the mould in a manner such that each cavity conforms to a shape of the space within the mould,
wherein a heating liquid is optionally passed through each cavity during the depressurizing of the space within the mould to a pressure p 3 , and
wherein a cooling liquid is passed through each cavity during the cooling of the space within the mould to a temperature T 3 .

14. The process according to claim 13 , wherein
the heating liquid and the cooling liquid are both oils which do not comprise low-boiling fractions and which resist temperature up to at least 300° C., and
the heating liquid and the cooling liquid are passed from two different holding vessels with different temperatures into each cavity, in a manner such that the temperature of the heating liquid is from 180 to 250° C. and the temperature of the cooling liquid is from 20 to 40° C.

15. The process according to claim 13 , further comprising
equipping an internal side of each mould shell with prepregs or organopanels prior to the charging of the poly(meth)acrylimide particles to the mould, and
wherein the rigid poly(meth)acrylimide foam core is in the form of a composite material comprising outer layers.

16. The process according to claim 13 , wherein the heating liquid is passed through each cavity during the depressurizing of the space within the mould to a pressure p 3 .

Assignees

• Bernhard Kay
• Liebl Ina
• Denk Tim
• Becker Florian
• Richter Thomas
• Evonik Roehm Gmbh

Inventors

• Bernhard Kay
• Liebl Ina
• Denk Tim
• Becker Florian
• Richter Thomas

Classifications

• B29K2033/26

  Polymers of acrylamide or methacrylamide · CPC title

• B29K2033/00

  Use of polymers of unsaturated acids or derivatives thereof as moulding material {(B29K2035/00 takes precedence)} · CPC title

• C08J2333/24

  Homopolymers or copolymers of amides or imides · CPC title

• B32B15/18

  comprising iron or steel {(B32B15/011, B32B15/012 and B32B15/013 take precedence)} · CPC title

• B29C44/3461 Primary

  Making or treating expandable particles · CPC title