Zinc-air electrochemical cell

Patent metadata

Field	Value
Publication number	US-10205206-B2
Application number	US-201615041739-A
Country	US
Kind code	B2
Filing date	Feb 11, 2016
Priority date	Oct 8, 2014
Publication date	Feb 12, 2019
Grant date	Feb 12, 2019

Abstract

A multi-faceted zinc-air electrochemical cell design holistically leverages interactions between components, especially with respect to conductive carbons from differing sources, lamination and the resulting impact it has on the air electrode's surface and other additives that impact the relative hydrophilicity of the membrane and/or performance of the anode, to improve the overall reliability and performance of the resulting battery.

First claim

What is claimed is:

1. An electrochemical cell comprising:
an anode including zinc;
a laminated air electrode comprising dry components including a manganese dioxide catalyst, a mixture of carbons, and a binder that is both fibrillated and particulate coated to at least a portion of the carbons, and wherein the mixture of carbons includes a hard carbon and at least one activated carbon; and
an electrolyte including potassium hydroxide.

2. The cell according to claim 1 , wherein the anode further comprises at least one selected from: fumed silica, functionalized barium sulfate and a sulfotricarballylate fluorosurfactant.

3. The cell according to claim 1 wherein the laminated air electrode has a consistent pattern of at least one of protrusions and indentations along one surface of the laminated air electrode.

4. The cell according to claim 3 wherein the at least one of protrusions and indentations were created with an anilox roller.

5. A method of manufacturing a miniature zinc-air electrochemical cell, the method comprising:
selecting a mixture of carbons including a hard carbon and at least one activated carbon;
subjecting the mixture of carbons to two-stage mixing including high shear in the presence of a manganese dioxide catalyst and a binder that is both fibrillated and particulate coated to at least a portion of the carbons so as to induce the formation of particles and fibers;
forming an air electrode from the mixture of carbons, binder, and the manganese dioxide catalyst;
laminating a hydrophobic layer to one side of the air electrode using an anilox roller;
providing an anode including zinc; and
providing an electrolyte including potassium hydroxide.

6. The method of claim 5 further comprising introducing fumed silica prior to forming the air electrode.

Assignees

• Energizer Brands Llc

Inventors

• Marple Jack W
• Sherry Thomas J

Classifications

• H01M4/8896

  Pressing, rolling, calendering (membrane electrode assemblies H01M8/1004) · CPC title

• H01M4/8875

  Methods for shaping the electrode into free-standing bodies, like sheets, films or grids, e.g. moulding, hot-pressing, casting without support, extrusion without support · CPC title

• H01M12/06 Primary

  with one metallic and one gaseous electrode · CPC title

• H01M6/185

  with oxides, hydroxides or oxysalts as solid electrolytes · CPC title

• H01M4/8657

  layered · CPC title