Methods of analyzing crude oil

Patent metadata

Field	Value
Publication number	US-10197547-B2
Application number	US-201715677231-A
Country	US
Kind code	B2
Filing date	Aug 15, 2017
Priority date	Jan 31, 2013
Publication date	Feb 5, 2019
Grant date	Feb 5, 2019

Abstract

The invention generally relates to methods of analyzing crude oil. In certain embodiments, methods of the invention involve obtaining a crude oil sample, and subjecting the crude oil sample to mass spectrometry analysis. In certain embodiments, the method is performed without any sample pre-purification steps.

First claim

What is claimed is:

1. A method for quantifying a corrosion inhibitor in crude oil, the method comprising:
obtaining a crude oil sample comprising a corrosion inhibitor;
subjecting the crude oil sample to mass spectrometry analysis comprising introducing the crude oil sample to a paper substrate and applying solvent and voltage to the crude oil sample on the substrate to generate ions of the corrosion inhibitor directly and only from the crude oil sample, wherein the applying step is conducted without an external heat source; and
quantifying the corrosion inhibitor in the crude oil sample based on results of the mass spectrometry analysis, wherein the method is performed without any sample pre-purification steps.

2. The method according to claim 1 , wherein the mass spectrometer is selected from the group consisting of a bench-top mass spectrometer and a miniature mass spectrometer.

3. The method according to claim 1 , wherein the paper is filter paper.

4. The method according to claim 1 , wherein the corrosion inhibitor comprises at least one alkyl ammonium salt.

5. The method according to claim 4 , wherein the alkyl ammonium salt is selected from the group consisting of tetradodecylammonium bromide, benzylhexadecyldimethylammonium chloride, and a combination thereof.

6. The method according to claim 1 , wherein the mass spectrometer is coupled with a discontinuous atmospheric pressure interface.

7. The method according to claim 1 , wherein the solvent comprises a mixture of methanol and acetonitrile.

8. The method according to claim 1 , wherein the mass spectrometry analysis is performed in an ambient environment.

Assignees

• Purdue Research Foundation

Inventors

• Cooks Robert Graham
• Jjunju Fred Paul Mark
• Li Anyin
• Roqan Iman S

Classifications

• H01J49/0031

  Step by step routines describing the use of the apparatus (H01J49/0081 takes precedence) · CPC title

• H01J49/10

  Ion sources; Ion guns · CPC title

• H01J49/0445

  with means for introducing as a spray, a jet or an aerosol (electrospray ion sources H01J49/165) · CPC title

• G01N33/2823 Primary

  Raw oil, drilling fluid or polyphasic mixtures · CPC title

• H01J49/168

  field ionisation, e.g. corona discharge (atmospheric pressure corona discharge per se H01T19/00) · CPC title