Metal oxide composite and method of preparing the same

Patent metadata

Field	Value
Publication number	US-10177372-B2
Application number	US-201615063711-A
Country	US
Kind code	B2
Filing date	Mar 8, 2016
Priority date	Aug 13, 2015
Publication date	Jan 8, 2019
Grant date	Jan 8, 2019

Abstract

A metal oxide composite including a first metal oxide composite layer, and a second metal oxide layer, wherein the first metal oxide composite layer and the second metal oxide layer are alternately stacked in a thickness direction; and a third metal oxide layer that is disposed on a side surface of the stacked structure, wherein the third metal oxide layer includes a metal oxide that is a same metal oxide as a metal oxide included in the stacked structure.

First claim

What is claimed is:

1. A metal oxide composite comprising:
a stacked structure comprising
a first metal oxide composite layer, and
a second metal oxide layer, wherein the first metal oxide composite layer and the second metal oxide layer are alternately stacked in a thickness direction; and

a third metal oxide layer that is disposed on a side surface of the first metal oxide composite layer and a side surface of the second metal oxide composite layer and covers at least a part of the side surface of the first metal oxide composite layer and the side surface of the second metal oxide composite layer,
wherein the third metal oxide layer comprises a metal oxide that is a same metal oxide as a metal oxide contained in the stacked structure,
wherein the third metal oxide layer is disposed on a first end surface of the stacked structure and on a second end surface of the stacked structure, and
wherein the third metal oxide layer is disposed on a first side surface of the first metal oxide composite layer and a first side surface of the second metal oxide composite layer and on an opposite second side surface of the first metal oxide composite layer and an opposite second side surface of the second metal oxide composite layer.

2. The metal oxide composite of claim 1 , wherein the third metal oxide layer completely surrounds the stacked structure.

3. The metal oxide composite of claim 1 , wherein the third metal oxide layer comprises the first metal oxide or a second metal oxide, which is a same second metal oxide as a second metal oxide of the second metal oxide layer.

4. The metal oxide composite of claim 1 , wherein a thickness of the first metal oxide composite layer is about 100 micrometers or less.

5. The metal oxide composite of claim 1 , wherein the second metal oxide layer is a sacrificial layer.

6. The metal oxide composite of claim 1 , wherein a thickness of the second metal oxide layer is about 200 micrometers or less.

7. A method of preparing the metal oxide composite of claim 1 , the method comprising
alternately stacking the first metal oxide composite layer and the second metal oxide layer to prepare the stacked structure;
disposing a composition that comprises the third metal oxide on the side surface of the first metal oxide composite layer and the side surface of the second metal oxide composite layer,
wherein the third metal oxide layer is disposed on a first end surface of the stacked structure and on a second end surface of the stacked structure, and
wherein the third metal oxide layer is disposed on a first side surface of the first metal oxide composite layer and a first side surface of the second metal oxide composite layer and on an opposite second side surface of the first metal oxide composite layer and an opposite second side surface of the second metal oxide composite layer; and then
sintering the stacked structure to prepare the metal oxide composite,
wherein the composition comprising the third metal oxide comprises the metal oxide that is the same metal oxide as the metal oxide contained in the stacked structure.

8. The method of claim 7 , wherein the composition comprising the third metal oxide is in a form of a slurry, a sheet, or a powder.

9. The method of claim 8 , wherein the composition is in the form of a slurry, and
wherein the disposing of the composition comprises at least one method selected from screen printing, spin coating, brushing, and disposing a composition sheet and performing warm isostatic press of the composition sheet.

10. The method of claim 8 , wherein the composition is in the form of a powder, and
wherein the disposing of the composition comprises embedding the stacked structure within the composition.

11. The method of claim 8 , wherein the sintering of the stacked structure comprises disposing the composition on a third metal oxide layer, which is in a form of a powder.

12. The method of claim 8 , wherein, the sintering of the stacked structure comprises sintering at a temperature in a range of about 800° C. to about 1100° C. for about 1 minute to about 20 hours.

13. The metal oxide composite of claim 1 , wherein the side surface of the first metal oxide composite layer is parallel to the thickness direction of the stacked structure.

14. A metal oxide composite comprising:
a stacked structure comprising
a first metal oxide composite layer, and
a second metal oxide layer, wherein the first metal oxide composite layer and the second metal oxide layer are alternately stacked in a thickness direction; and

a third metal oxide layer that is disposed on a side surface of the stacked structure,
wherein the third metal oxide layer comprises a metal oxide that is a same metal oxide as a metal oxide contained in the stacked structure, and
wherein a thickness of the third metal oxide layer is about 50 micrometers or less,
wherein the third metal oxide layer is disposed on a first end surface of the stacked structure and on a second end surface of the stacked structure, and
wherein the third metal oxide layer is disposed on a first side surface of the first metal oxide composite layer and a first side surface of the second metal oxide composite layer and on an opposite second side surface of the first metal oxide composite layer and an opposite second side surface of the second metal oxide composite layer.

15. A metal oxide composite comprising:
a stacked structure comprising
a first metal oxide composite layer, and
a second metal oxide layer, wherein the first metal oxide composite layer and the second metal oxide layer are alternately stacked in a thickness direction; and

a third metal oxide layer that is disposed on a side surface of the stacked structure,
wherein the third metal oxide layer covers at least a part of the side surface of the first metal oxide composite layer and the side surface of the second metal oxide composite layer,
wherein the third metal oxide layer comprises a metal oxide that is a same metal oxide as a metal oxide contained in the stacked structure, and
wherein the first metal oxide composite layer comprises
a current collector layer, and
an electrode layer that is disposed on a surface of the current collector layer.

16. The metal oxide composite of claim 15 , wherein the electrode layer comprises a first electrode layer and a second electrode layer, and
wherein the current collector layer is disposed between the first electrode layer and the second electrode layer.

17. The metal oxide composite of claim 15 , wherein the electrode layer comprises a first metal oxide, and wherein the first metal oxide is selected from a lithium transition metal oxide, a lithium transition metal phosphate, and a transition metal oxide.

18. The metal oxide composite of claim 15 , wherein the current collector layer comprises at least one selected from Al, Ag, Cu, Ni, Co, Cr, W, Mo, Pd, Pt, an Ag—Pd alloy, an Ag—Pt alloy, an Ag—Pd—Pt alloy, and a Pd—Pt alloy.

Assignees

• Samsung Electronics Co Ltd

Inventors

• Park Hwiyeol
• Yang Hojung
• Cho Kyunghoon
• Heo Jin S
• Nam Seunghoon
• Jeong Huisu

Classifications

• H01M4/662

  Alloys (collectors of lead alloys H01M4/685) · CPC title

• H01M4/1391

  of electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx · CPC title

• H01M4/0414

  by screen printing · CPC title

• H01M4/485

  of mixed oxides or hydroxides for inserting or intercalating light metals, e.g. LiTi2O4 or LiTi2OxFy (H01M4/505, H01M4/525 take precedence) · CPC title

• H01M4/0471

  involving thermal treatment, e.g. firing, sintering, backing particulate active material, thermal decomposition, pyrolysis · CPC title