Liquid developer and method of producing same

Patent metadata

Field	Value
Publication number	US-10175597-B2
Application number	US-201615559580-A
Country	US
Kind code	B2
Filing date	May 27, 2016
Priority date	May 27, 2015
Publication date	Jan 8, 2019
Grant date	Jan 8, 2019

Abstract

Provided is a liquid developer that gives a high image density, has a high resistance, suppresses the appearance of image blurring, can be reused, is readily cured by ultraviolet radiation, and can accommodate higher process speeds. This liquid developer contains a carrier liquid, a toner particle insoluble in the carrier liquid, and a compound with the following formula (1)

[In formula (1), R 1 and R 2 each independently represent an alkyl group having at least 13 and not more than 23 carbons.].

First claim

The invention claimed is:

1. A liquid developer comprising:
a carrier liquid;
a toner particle that is insoluble in the carrier liquid;
a compound with formula (1)

where R 1 and R 2 each independently represent an alkyl group having 13 to 23 carbons; and
a polymer compound that has a structural unit with formula (2)

where R 3 to R 6 each independently represent a hydrogen atom or an alkyl group; A represents any of a single bond, carbonyl group, alkylene group, arylene group, or —COOR 9 — (where the carbonyl group in —COOR 9 — is bonded to a carbon atom to which R 3 is bonded and R 9 represents an alkylene having 1 to 4 carbons); and B represents an alkylene group or an arylene group, wherein
the content ratio on a molar basis of the compound with formula (1) to the polymer compound having the structural unit with formula (2) is 5:1 to 35:1.

2. The liquid developer according to claim 1 , wherein the carrier liquid contains a liquid cationically polymerizable compound.

3. The liquid developer according to claim 2 , wherein the carrier liquid contains a vinyl ether compound.

4. The liquid developer according to claim 3 , wherein the content of the compound with formula (1) in the liquid developer is 0.50 to 5.00 mass parts per 100 mass parts of the toner particle.

5. The liquid developer according to claim 4 wherein the polymer compound is formed of a copolymer that has the structural unit with formula (2) and a structural unit with formula (3)

where R 7 represents either a hydrogen atom or an alkyl group, and R 8 is any of an alkyl group, carboxylate ester group, carboxamide group, alkoxy group, or aryl group.

6. The liquid developer according to claim 3 , wherein the polymer compound is formed of a copolymer that has the structural unit with formula (2) and a structural unit with formula (3)

where R 7 represents either a hydrogen atom or an alkyl group, and R 8 is any of an alkyl group, carboxylate ester group, carboxamide group, alkoxy group, or aryl group.

7. The liquid developer according to claim 2 , wherein the content of the compound with formula (1) in the liquid developer is 0.50 to 5.00 mass parts per 100 mass parts of the toner particle.

8. The liquid developer according to claim 7 , wherein the polymer compound is formed of a copolymer that has the structural unit with formula (2) and a structural unit with formula (3)

where R 7 represents either a hydrogen atom or an alkyl group, and R 8 is any of an alkyl group, carboxylate ester group, carboxamide group, alkoxy group, or aryl group.

9. The liquid developer according to claim 2 , wherein the polymer compound is formed of a copolymer that has the structural unit with formula (2) and a structural unit with formula (3)

where R 7 represents either a hydrogen atom or an alkyl group, and R 8 is any of an alkyl group, carboxylate ester group, carboxamide group, alkoxy group, or aryl group.

10. The liquid developer according to claim 1 , wherein the carrier liquid contains a vinyl ether compound.

11. The liquid developer according to claim 10 , wherein the content of the compound with formula (1) in the liquid developer is 0.50 to 5.00 mass parts per 100 mass parts of the toner particle.

12. The liquid developer according to claim 11 , wherein the polymer compound is formed of a copolymer that has the structural unit with formula (2) and a structural unit with formula (3)

where R 7 represents either a hydrogen atom or an alkyl group, and R 8 is any of an alkyl group, carboxylate ester group, carboxamide group, alkoxy group, or aryl group.

13. The liquid developer according to claim 10 , wherein the polymer compound is formed of a copolymer that has the structural unit with formula (2) and a structural unit with formula (3)

where R 7 represents either a hydrogen atom or an alkyl group, and R 8 is any of an alkyl group, carboxylate ester group, carboxamide group, alkoxy group, or aryl group.

14. The liquid developer according to claim 1 , wherein the content of the compound with formula (1) in the liquid developer is 0.50 to 5.00 mass parts per 100 mass parts of the toner particle.

15. The liquid developer according to claim 14 , wherein the polymer compound is formed of a copolymer that has the structural unit with formula (2) and a structural unit with formula (3)

where R 7 represents either a hydrogen atom or an alkyl group, and R 8 is any of an alkyl group, carboxylate ester group, carboxamide group, alkoxy group, or aryl group.

16. The liquid developer according to claim 1 , wherein the polymer compound is formed of a copolymer that has the structural unit with formula (2) and a structural unit with formula (3)

where R 7 represents either a hydrogen atom or an alkyl group, and R 8 is any of an alkyl group, carboxylate ester group, carboxamide group, alkoxy group, or aryl group.

17. A method of producing the liquid developer according to claim 1 , comprising a step of:
applying a shear force and/or applying a heat treatment to a mixture in which the carrier liquid, the toner particle that is insoluble in the carrier liquid, and the compound with formula (1) are mixed.

Assignees

• Canon Kk

Inventors

• Shirakawa Jun
• Ito Junji
• Aichi Yasuhiro

Classifications

• C07F9/106

  Adducts, complexes, salts of phosphatides · CPC title

• G03G9/0804

  whereby the components are brought together in a liquid dispersing medium · CPC title

• C07F9/091

  with hydroxyalkyl compounds with further substituents on alkyl · CPC title

• G03G9/131

  obtained by reactions only involving carbon-to-carbon unsaturated bonds · CPC title

• G03G9/1355 Primary

  Ionic, organic compounds · CPC title