Processes and apparatuses for production of olefins

Patent metadata

Field	Value
Publication number	US-10160922-B2
Application number	US-201615331732-A
Country	US
Kind code	B2
Filing date	Oct 21, 2016
Priority date	Nov 23, 2015
Publication date	Dec 25, 2018
Grant date	Dec 25, 2018

Abstract

Processes and apparatuses for the production of olefins are provided. In an embodiment, a process for production of a process is provided for increasing light olefin yield comprising passing a hydrocarbon feedstream comprising paraffins, naphthenes and aromatic hydrocarbons to a catalytic reforming unit. The hydrocarbon feedstream is contacted with a reforming catalyst under mild reforming conditions suitable for converting naphthenes into aromatics while minimizing conversion of the paraffins, to provide a reforming effluent stream. The reforming effluent stream is passed to a solvent extraction unit to provide an overhead stream comprising predominantly paraffins and a bottoms stream comprising predominantly aromatics. Finally, the overhead stream is passed to a cracking unit to provide a product stream comprising the light olefins.

First claim

The invention claimed is:

1. A process for increasing light olefin yield comprising:
passing a hydrocarbon feedstream comprising paraffins, naphthenes and aromatic hydrocarbons to a catalytic reforming unit, the hydrocarbon feedstream being contacted with a reforming catalyst under mild reforming conditions suitable for converting naphthenes into aromatics while minimizing conversion of the paraffins, to provide a reforming effluent stream;
passing the reforming effluent stream to a solvent extraction unit to provide an overhead stream comprising predominantly paraffins and a bottoms stream comprising predominantly aromatics, wherein the overhead stream comprises C 6 − hydrocarbons;
passing the overhead stream to a naphtha cracker to provide a product stream comprising the light olefins; and,
recycling a recycle stream from the naphtha cracker to the solvent extraction unit, wherein the recycle stream comprises butanes, butenes, and aromatics.

2. The process of claim 1 , wherein the hydrocarbon feedstream is a naphtha feedstream and the naphtha cracker is a catalytic naphtha cracker, or a naphtha steam cracker.

3. The process of claim 1 , wherein the mild reforming conditions comprise a temperature of about 300° C. to about 500° C.

4. The process of claim 3 , wherein the mild reforming conditions comprise a temperature of about 400° C. to about 475° C.

5. The process of claim 1 , wherein the mild reforming conditions comprise a pressure of about 0 kPa(g) to about 3500 kPa(g).

6. The process of claim 5 , wherein the mild reforming conditions comprise a pressure of about 275 kPa(g) to about 700 kPa(g).

7. The process of claim 1 , wherein the mild reforming conditions comprise a hydrogen to hydrocarbon molar ratio of about 1:1 to about 10:1.

8. The process of claim 7 , wherein the mild reforming conditions comprise a hydrogen to hydrocarbon molar ratio of about 2:1 to about 6:1.

9. The process of claim 1 , wherein the naphthene conversion is greater than about 80 mass % and the paraffin conversion is less than about 20 mass %.

10. The process of claim 9 , wherein the naphthene conversion is greater than about 90 mass % and the paraffin conversion is less than about 10 mass %.

11. The process of claim 1 , wherein the reforming catalyst comprises a noble metal comprising one or more of platinum, palladium, rhodium, ruthenium, osmium, and iridium.

12. The process of claim 11 wherein the reforming catalyst is supported on refractory inorganic oxide support comprising one or more of alumina, a chlorided alumina a magnesia, a titania, a zirconia, a chromia, a zinc oxide, a thoria, a boria, a silica-alumina, a silica-magnesia, a chromia-alumina, an alumina-boria, a silica-zirconia and a zeolite.

13. The process of claim 11 further comprising a modifier component selected from the group consisting of titanium, niobium, rare earth elements, tin, rhenium, zinc, germanium and mixtures thereof.

14. The process of claim 1 further comprising passing the reforming effluent stream to a fractionation column to provide a fractionator overhead stream comprising C 6 − hydrocarbons and a fractionator bottoms stream comprising C 6 + hydrocarbons and sending the fractionator bottoms stream to the solvent extraction unit.

15. The process of claim 14 further comprising sending the fractionator overhead stream to the cracking unit.

16. The process of claim 1 wherein the recycle stream comprises a pygas stream from the naphtha cracker.

17. A process for increasing light olefin yield comprising:
passing a naphtha feedstream comprising paraffins, naphthenes and aromatic hydrocarbons to a catalytic reforming unit, the naphtha feedstream being contacted with a reforming catalyst comprising at least one platinum-group metal component under mild reforming conditions comprising a pressure ranging from 0 to 3500 kPa(g), a temperature ranging from 300 to 500° C. to carry out mild catalytic reforming reaction so as to achieve a naphthene conversion of greater than 80 mass %, and a paraffin conversion of less than about 20 mass %, to provide a reforming effluent stream;
passing the reforming effluent stream to a solvent extraction unit to provide an overhead stream comprising predominantly paraffins and a bottoms stream comprising predominantly aromatics, wherein the overhead stream comprises C 6− hydrocarbons;
passing the overhead stream to a naphtha cracker to provide a product stream comprising the light olefins; and,
recycling a recycle stream from the naphtha cracker to the solvent extraction unit, wherein the recycle stream comprises butanes, butenes, and aromatics.

18. The process of claim 17 , wherein the mild reforming conditions comprise a temperature of about 400° C. to about 475° C.

19. The process of claim 17 , wherein the mild reforming conditions comprise a pressure of about 275 kPa(g) to about 700 kPa(g).

20. The process of claims 17 , wherein the naphthene conversion is greater than 90 mass %, and the paraffin conversion is less than about 10 mass %.

Assignees

• Uop Llc

Inventors

• Funk Gregory

Classifications

• C10G2400/30

  Aromatics · CPC title

• C10G2400/22

  Higher olefins · CPC title

• C10G63/04 Primary

  including at least one cracking step · CPC title

• C10G2400/20

  C2-C4 olefins · CPC title