Processes for catalytically reforming naphtha

Patent metadata

Field	Value
Publication number	US-9303217-B2
Application number	US-201213480837-A
Country	US
Kind code	B2
Filing date	May 25, 2012
Priority date	May 27, 2011
Publication date	Apr 5, 2016
Grant date	Apr 5, 2016

Abstract

Disclosed herein is a process for catalytically reforming naphtha, comprising, in the presence of hydrogen gas, contacting naphtha with at least one reforming catalyst under the conditions of a pressure ranging from 0.15 to 3.0 MPa, a temperature ranging from 300 to 540° C., a volume space velocity ranging from 2.1 to 50 h −1 , to carry out a shallow catalytic reforming reaction so as to achieve a naphthene conversion ratio of greater than 85 mass %, and a conversion ratio of paraffins to arenes and C4 − hydrocarbons of less than 30 mass %.

First claim

What is claimed is:

1. A process for catalytically reforming naphtha, comprising, in the presence of hydrogen gas, contacting naphtha with at least one reforming catalyst under the conditions of a pressure ranging from 0.15 to 3.0 MPa, a temperature ranging from 300 to 540° C. and a naphtha volume space velocity ranging from 8.0 to 25.0 h −1 to carry out a shallow catalytic reforming reaction, wherein naphthene in naphtha is converted to arenes, so as to achieve a naphthene conversion ratio of greater than 85 mass %, and a conversion ratio of paraffins to arenes and C 4 − hydrocarbons of less than 30 mass %, the naphtha is a straight run naphtha and comprises from 30 to 85 mass % of alkanes, from 10 to 50 mass % of naphthenes and from 5 to 30 mass % of arenes, and said reforming catalyst comprises from 0.01 to 5.0 mass % of a Group VIII metal, from 0.01 to 5.0 mass % of a halogen and from 90.0 to 99.97 mass % of an alumina support.

2. The process according to claim 1 , wherein the naphthene conversion ratio is greater than 90 mass %, and the conversion ratio of paraffins to arenes and C 4 − hydrocarbons is less than 10 mass %.

3. The process according to claim 1 , wherein the pressure ranges from 0.2 to 2.0 MPa, and the temperature ranges from 350 to 520° C.

4. The process according to claim 1 , wherein the hydrogen/hydrocarbon molar ratio in the reforming reaction ranges from 0.1:1 to 20:1.

5. The process according to claim 4 , wherein the hydrogen/hydrocarbon molar ratio in the reforming reaction ranges from 1:1 to 8:1.

6. The process according to claim 3 , wherein the temperature ranges from 400 to 500° C.

7. The process according to claim 1 , further comprising feeding the reforming reaction product into a gas-liquid separation device to separate hydrogen gas, a liquefied gas, and a reformate.

8. The process according to claim 7 , further comprising separating arenes and paraffins in the reformate by an arene separation device to obtain a fraction rich in arenes and a fraction rich in paraffins.

9. The process according to claim 8 , wherein the arene separation device is chosen from an arene extraction device and an arene adsorption-separation device.

10. The process according to claim 7 , wherein the reformate is a hydrocarbon mixture of C 5 + or C 6 + hydrocarbons.

11. The process according to claim 9 , wherein at least one extraction solvent is used in the arene extraction device and is chosen from sulfolane, dimethyl sulfoxide, dimethyl formamide, N-methylpyrrolidone, N-formylmorpholine, triglycol, tetraglycol, pentaglycol, methanol and acetonitrile.

12. The process according to claim 9 , wherein at least one extraction solvent and extraction feedstock are used in the arene extraction device, and the extraction solvent and the extraction feedstock used in the arene extraction device have a mass ratio ranging from 1:1 to 5:1.

13. The process according to claim 9 , wherein at least one adsorbent is used in the arene adsorption-separation device and is chosen from NaX and NaY.

14. The process according to claim 8 , further comprising feeding the fraction rich in paraffins into a steam cracking device to carry out a cracking reaction to produce ethylene.

15. The process according to claim 14 , wherein the cracking reaction is carried out under the conditions of a pressure ranging from 0.05 to 0.30 MPa, a reactant residence time ranging from 0.01 to 0.6 s, a water/oil mass ratio ranging from 0.3:1 to 1.0:1, and a cracking furnace outlet temperature ranging from 760 to 900° C.

16. The process according to claim 1 , wherein the naphtha is a hydrocarbon mixture having an ASTM D-86 initial boiling point ranging from 40 to 80° C. and a final boiling point ranging from 160 to 220° C.

17. The process according to claim 1 , wherein the straight run naphtha is a hydrorefined straight run naphtha comprising sulfur in an amount of less than 0.5 μg/g, nitrogen in an amount of less than 0.5 μg/g, arsenic in an amount of 1.0 ng/g, and lead in an amount of less than 10 ng/g.

Assignees

• Ma Aizeng
• Wang Jieguang
• Pan Jincheng
• China Petroleum & Chemical
• China Res Inst Of Petroleum Proc Sinopec

Inventors

• Ma Aizeng
• Wang Jieguang
• Pan Jincheng

Classifications

• C07C4/04

  Thermal processes {(C07C4/025 takes precedence)} · CPC title

• C10G63/04

  including at least one cracking step · CPC title

• C10G21/20

  Nitrogen-containing compounds · CPC title

• C10G2300/202

  Heteroatoms content, i.e. S, N, O, P · CPC title

• C10G61/06

  the refining step being a sorption process · CPC title