Method of reducing hydrogen sulfide levels in gaseous mixtures using triazines

Patent metadata

Field	Value
Publication number	US-10155911-B2
Application number	US-201615554896-A
Country	US
Kind code	B2
Filing date	Apr 4, 2016
Priority date	Apr 16, 2015
Publication date	Dec 18, 2018
Grant date	Dec 18, 2018

Abstract

The present invention relates to a scavenging composition capable of scavenging a wide variety of sulfur-bearing compounds, such as hydrogen sulfide and method of use thereof. Said scavenging composition comprises an aqueous solution of a triazine compound, an anionic surfactant, and optionally an alcohol and/or glycol ether solution. The composition may be used in any kind of sulfide-scavenging operation and is particularly useful for sulfide scavenging in the context of sulfide removal from oil or gas streams and in the treatment of oil or gas transmission lines or equipment.

First claim

What is claimed is:

1. A method of reducing H 2 S in a liquid or gaseous stream comprising H 2 S which comprises contacting the stream with an aqueous sulfide-scavenging composition comprising:
(a) one or more triazine compound of the formula:

wherein R 1 , R 2 , and R 3 are independently selected from a C 1 to C 20 straight or branched chain alkyl group,

wherein R 4 , R 5 , and R 6 are independently selected from a C 1 to C 6 alkyl group and wherein R 7 , R 8 , and R 9 are independently selected from hydrogen or a C 1 to C 6 alkyl group,

and
(b) an anionic surfactant selected from a dialkyl sulfosuccinate, a di-sulfonate, an alkylbenzene sulfonate, an alkyl sulfate, a carboxylic acid, or mixtures thereof,
wherein the amount of the anionic surfactant is sufficient to accelerate the H 2 S scavenging action of the triazine compound in comparison with the scavenging action of said triazine without the surfactant compound.

2. The method of claim 1 wherein the triazine compound (a) is 1, 3, 5-trimethyl-hexahydro-1, 3, 5-triazine or 1, 3, 5-tris(2-hydroxyethyl)hexahydro-s-triazine.

3. The method of claim 1 wherein the anionic surfactant (b) is a dialkyl sulfosuccinate of the following formula:

where R 10 and R 11 are the same or different linear or branched C 6 to C 10 alkyl groups and X is a sodium ion, a potassium ion, a lithium ion, or an ammonium ion.

4. The method of claim 3 wherein the dialkyl sulfosuccinate is 1,4-bis(2-ethylhexyl) sodium sulfosuccinate.

5. The method of claim 1 wherein the anionic surfactant (b) is a di-sulfonate of the following formula:

where R 12 is a C 3 to C 20 alkyl radical, preferably propyl, butyl, octyl, nonyl, decyl, or dodecyl, preferably a C 8 to C 12 alkyl radical and X is a sodium ion, a potassium ion, a lithium ion, or an ammonium ion.

6. The method of claim 5 wherein the di-sulfonate is selected from butyl diphenyl ether disulfonic acid sodium, nonyl diphenyl ether disulfonic acid sodium, dodecyl diphenyl ether disulfonic acid sodium, dodecyl diphenyl ether disulfonic acid potassium, butyl diphenyl ether disulfonic acid lithium, nonyl diphenyl ether disulfonic acid ammonium, dodecyl diphenyl ether disulfonic acid ammonium, dodecyl diphenyl ether disulfonic acid lithium, or mixtures thereof.

7. The method of claim 1 wherein the aqueous sulfide-scavenging composition further comprises an alcohol, a glycol ether, or mixtures thereof.

Assignees

• Dow Global Technologies Llc

Inventors

• Tan Runyu

Classifications

• B01D2257/304

  Hydrogen sulfide · CPC title

• B01D2252/20415

  Tri- or polyamines · CPC title

• B01D2256/24

  Hydrocarbons · CPC title

• C10L3/103

  Sulfur containing contaminants · CPC title

• B01D2252/20436

  Cyclic amines · CPC title