Oxidation catalyst and processes for using same

Patent metadata

Field	Value
Publication number	US-10731088-B2
Application number	US-201815868965-A
Country	US
Kind code	B2
Filing date	Jan 11, 2018
Priority date	Jul 15, 2015
Publication date	Aug 4, 2020
Grant date	Aug 4, 2020

Abstract

A catalytic composition and process for using same. The catalyst may be utilized for an oxidation reaction, for example, for the conversion of mercaptans to disulfides. The catalyst includes a metal component, for example, cobalt phthalocyanine structure. The organic component may comprise any number of different oxidation promoters that are capable of promoting the reduction of oxygen, preferably in a caustic, environment. The organic component may comprise an unsaturated six member ring having at least five carbon atoms, and wherein the sixth member of the six member ring is either C or N, and in which at least two substituent groups are present on the six membered ring.

First claim

The invention claimed is:

1. A catalytic composition comprising:
a metal component comprising a metal bonded to at least two nitrogen atoms; and,
an organic component comprising a six member ring having at least five carbon atoms, and wherein the sixth member of the six member ring is C, and
wherein at least two substituent groups of the six member ring form a six member fused ring or a five member fused ring.

2. The catalytic composition of claim 1 , wherein the five member fused ring includes N and wherein a third substituent group of the six member ring of the organic component comprises sulfonate.

3. A catalytic composition comprising:
a metal component comprising a metal bonded to at least two nitrogen atoms; and,
an organic component comprising a six member ring having at least five carbon atoms, and wherein the sixth member of the six member ring is N, and
wherein at least two substituent groups of the six member ring are each independently selected from hydroxyl, amino, amides, carbonyl, carboxyl, thiol, sulfonate, and pyridine, or form a fused ring, provided that if one substituent group is a pyridine ring, the other substituent group is an alkyl group, and wherein a first of the at least two substituent groups is pyridine and wherein the second of the at least two substituent groups is bonded to the N in the six member ring of the organic component.

4. A catalytic composition comprising:
a metal component comprising a metal bonded to at least two nitrogen atoms; and,
an organic component comprising a six member ring having at least five carbon atoms, and wherein the sixth member of the six member ring is C, and wherein the six member ring includes at least two substituent groups independently selected from:
at least one hydroxyl group and at least one amine group,
at least one hydroxyl group and at least one thiol group,
at least two hydroxyl groups and a halogen, and
at least three hydroxyl groups and a halogen.

5. A catalytic composition comprising:
a metal component comprising a metal bonded to at least two nitrogen atoms; and,
an organic component comprising a six member ring having at least five carbon atoms, and wherein the sixth member of the six member ring of the organic component is C and wherein the six member ring includes at least three hydroxyl groups.

6. The catalytic composition of claim 5 , wherein a fourth substituent group of the six member ring comprises a carboxyl group.

7. The catalytic composition of claim 5 , wherein a fourth substituent group of the six member ring comprises an ester group.

8. The catalytic composition of claim 5 wherein the metal component comprises a metal bonded to at least four nitrogen atoms.

9. The catalytic composition of claim 5 wherein the metal is cobalt.

10. A catalytic composition comprising:
a metal component comprising at least one of cobalt phthalocyanine, cobalt phthalocyanine disulfonate, cobalt phthalocyanine sulfonamide, B 12 vitamer, cobalamin, cobalt porphyrins, cobalt porphines, and cobalt tetra-aza macrocycles; and,
an organic component comprising
at least one of a bipyridinium core structure, a viologen core structure, a benzene with three or more hydroxyl groups, a benzene with two or more sulfonane groups, a indigo core structure, indigo carmine, benezenetriol, a benzenetriol substituted with a sulfate, an ester, ether or carboxyl, phenolic acids, diphenolic acids, trihydroxyl phenolic acids, and substituted phenolic acids.

11. A process for removing mercaptans from a hydrocarbon stream comprising: extracting mercaptans from a hydrocarbon stream in an extraction zone with a caustic stream to provide a rich caustic stream; and,
oxidizing the mercaptans in the rich caustic stream with an oxidation gas, in the presence of a catalyst, to produce disulfides, wherein the catalyst comprises a metal component comprising a metal bonded to at least two nitrogen atoms, and
an organic component comprising a six member ring having at least five carbon atoms, wherein the sixth member of the six member ring is C, and
wherein at least three substituent groups of the six member ring are hydroxyl groups.

Assignees

• Uop Llc

Inventors

• Shi Yili
• Thomas Neil

Classifications

• C10G27/00

  Refining of hydrocarbon oils in the absence of hydrogen, by oxidation · CPC title

• B01J31/22

  Organic complexes · CPC title

• B01J31/0217

  Mercaptans or thiols · CPC title

• B01J2231/70

  Oxidation reactions, e.g. epoxidation, (di)hydroxylation, dehydrogenation and analogues · CPC title

• B01J31/0244

  with nitrogen contained as ring member in aromatic compounds or moieties, e.g. pyridine · CPC title