Hybrid magnesium cement and method of manufacture

Patent metadata

Field	Value
Publication number	US-10150700-B2
Application number	US-201514968214-A
Country	US
Kind code	B2
Filing date	Dec 14, 2015
Priority date	Jun 30, 2011
Publication date	Dec 11, 2018
Grant date	Dec 11, 2018

Abstract

A hybrid magnesium cement composition formed from an A-side component and a B-side component. The A-side component includes an A1-component including a light-burn grade magnesium-containing material, and an A2-component including a non-metallic oxide salt. A B-side component having a metal silicate polymer is included.

First claim

What is claimed is:

1. A hybrid magnesium cement composition comprising:
a first composition having
a first component including a magnesium-containing material, and
a second component including a salt having a non-metallic oxide anion, the first composition being partially cured;

a second composition having a metal silicate polymer, the second composition being partially cured; and
inorganic polymer chains having at least 60 repeat units of SiP 2 O 7 .

2. The hybrid magnesium cement composition of claim 1 , wherein the magnesium-containing material includes calcium carbonate in an amount from 0 wt. % to 70 wt. % of the magnesium-containing material, calcium oxide in an amount less than 10 wt. % of the magnesium-containing material, magnesium carbonate in an amount of 0 wt. % to 25 wt. % of the magnesium-containing material, and magnesium oxide in an amount from 18 wt. % to 70 wt. % of the magnesium-containing material.

3. The hybrid magnesium cement composition of claim 2 , wherein the magnesium-containing material is a light-burn grade dolomite, pyroxenite, amphibolite, serpentine, dunite, or chlorite having a weight loss ranging from 23-28 dry wt. % relative to an uncalcined dolomite as measured by weighing dry dolomite after-calcining relative to before-calcining.

4. The hybrid magnesium cement composition of claim 3 , wherein the light-burn grade dolomite includes sand and a first hydraulic additive and an optional second hydraulic additive.

5. The hybrid magnesium cement composition of claim 4 , wherein the first hydraulic additive includes a ground granulated blast-furnace slag.

6. The hybrid magnesium cement composition of claim 1 , further comprising water.

7. The hybrid magnesium cement composition of claim 1 , wherein the metal silicate polymer comprises a mixture of a hydroxide anion and a silicate source including at least one of a flyash, slag, biomass ash and bottom ash.

8. The hybrid magnesium cement composition of claim 1 , wherein the salt is a phosphate salt capable of being solubilized in amount ranging from 3.0 wt. % to 5.3 wt. % of the first composition on a dry weight basis.

9. The hybrid magnesium cement composition of claim 1 , further comprising magnesium oxide wherein a weight ratio of the salt to magnesium oxide ranges from 0.1 to 1.2.

10. The hybrid magnesium cement composition of claim 1 wherein magnesium-containing material composition includes a magnesium oxide metal oxide salt.

11. The hybrid magnesium cement composition of claim 1 wherein magnesium-containing material composition includes a light burn grade dolomite and a salt having a non-metal oxide anion.

12. A magnesium-containing material composition, comprising:
calcium carbonate;
calcium oxide;
magnesium carbonate;
magnesium oxide; and
inorganic polymer chains having at least 60 repeat units of SiP 2 O 7 .

13. The magnesium-containing material composition of claim 12 , comprising:
calcium carbonate present in an amount from 30 wt. % to 70 wt. % of the magnesium-containing material composition;
calcium oxide in an amount less than 10 wt. % of the magnesium-containing material composition;
magnesium carbonate in an amount less than 25 wt. % of the magnesium-containing material composition; and
magnesium oxide present in an amount ranging from 18 wt. % to 70 wt. % of the magnesium-containing material composition.

14. The magnesium-containing material composition of claim 12 , comprising:
calcium carbonate present in an amount from 50 wt. % to 60 wt. % the magnesium-containing material composition;
calcium oxide present in an amount from 0.2. wt. % to 5 wt. % of the magnesium-containing material composition;
magnesium carbonate in an amount less than 5 wt. % of the magnesium-containing material composition; and
magnesium oxide present in an amount from 40 wt. % to 50 wt. % of the magnesium-containing material composition.

15. The magnesium-containing material composition of claim 12 , further comprising sand.

16. A hybrid magnesium cement composition comprising a reaction product of:
a first composition having
a first component including a magnesium-containing material, and
a second component including a salt having a non-metallic oxide anion, the first composition being partially cured; and

a second composition having a metal silicate polymer, the second composition being partially cured, the hybrid magnesium cement composition being formed by combining the first composition with the second composition, the hybrid magnesium cement composition including inorganic polymer chains having at least 60 repeat units of SiP 2 O 7 .

Assignees

• Univ Wayne State

Inventors

• Wu Hwai-Chung
• Warnemuende Kraig

Classifications

• C04B2111/00017

  Aspects relating to the protection of the environment · CPC title

• Y02P40/165

  Cross-Sectional Technologies · mapped topic

• C04B22/062

  of the alkali or alkaline-earth metals · CPC title

• C04B18/08

  Flue dust {, i.e. fly ash} · CPC title

• C04B18/141

  Slags · CPC title