Substrate having a functional coating and a temporary protection layer

Patent metadata

Field	Value
Publication number	US-10144841-B2
Application number	US-201414909673-A
Country	US
Kind code	B2
Filing date	Aug 5, 2014
Priority date	Aug 5, 2013
Publication date	Dec 4, 2018
Grant date	Dec 4, 2018

Abstract

A substrate includes two main faces defining two main surfaces separated by edges, the substrate bearing a functional coating deposited on at least one portion of one main surface and a temporary protective layer deposited on at least one portion of the functional coating. The temporary protective layer, cured by drying, by UV irradiation or by an electron beam, has a thickness of at least 1 micrometer and is not soluble in water. This temporary protective layer is obtained from a liquid composition including (meth)acrylate compounds selected from monomers, oligomers, prepolymers or polymers including at least one (meth)acrylate function.

First claim

The invention claimed is:

1. An article comprising a substrate comprising two main faces defining two main surfaces separated by edges, said substrate bearing:
a functional coating deposited on at least one portion of one main surface, and
a temporary protective layer deposited on at least one portion of the functional coating, wherein,
the temporary protective layer has a thickness of at least 1 micrometer,
the temporary protective layer is not soluble in water,
the temporary protective layer is obtained from a composition comprising (meth)acrylate compounds, and
wherein the temporary protective layer is deposited:
on each of the main surfaces of the substrate and/or
on at least one edge of the substrate and/or
on each of the edges of the substrate.

2. The article comprising a substrate as claimed in claim 1 , wherein the substrate bearing the functional coating has not undergone a heat treatment at a temperature above 400° C.

3. The article comprising a substrate as claimed in claim 1 , wherein the (meth)acrylate compounds that have reacted together represent at least 90% by weight of a weight of the temporary protective layer.

4. The article comprising a substrate as claimed in claim 1 , wherein the functional coating comprises a thin-film multilayer successively comprising, starting from the substrate, an alternation of n functional metallic layers based on silver or on a metal alloy containing silver, and of (n+1) antireflection coatings, each antireflection coating comprising at least one dielectric layer, so that each functional metallic layer is positioned between two antireflection coatings.

5. The article comprising a substrate as claimed in claim 1 , wherein the functional coating comprises an upper layer selected from nitrides, oxides or oxynitrides of titanium, of zirconium and/or of hafnium.

6. The article comprising a substrate as claimed in claim 5 , wherein the upper layer is selected from a layer:
of titanium nitride; of zirconium nitride; of hafnium nitride; of titanium zirconium nitride; of titanium zirconium hafnium nitride,
of titanium oxide; of zirconium oxide; of hafnium oxide; of titanium zirconium oxide; of titanium zirconium hafnium oxide.

7. A process for protecting an article comprising a substrate comprising two main faces defining two main surfaces separated by edges, said glass substrate bearing a functional coating deposited on at least one portion of one main surface, said protection process comprising:
preparing a liquid composition comprising (meth)acrylate compounds selected from monomers, oligomers, prepolymers or polymers comprising at least one (meth)acrylate function,
applying the composition to at least one portion of the functional coating over a thickness of at least 1 micrometer,
crosslinking the composition so as to form a temporary protective layer,
wherein the temporary protective layer is deposited:
on each of the main surfaces of the substrate and/or
on at least one edge of the substrate and/or
on each of the edges of the substrate.

8. The process for protecting an article comprising a substrate as claimed in claim 7 , further comprising removing said temporary protective layer by a heat treatment at high temperature of tempering, annealing and/or bending type.

9. The process for protecting an article comprising a substrate as claimed in claim 8 , wherein the temperature is above 200° C.

10. The process for protecting an article comprising a substrate as claimed in claim 9 , wherein the temperature is above 300° C.

11. The process for protecting an article comprising a substrate as claimed in claim 10 , wherein the temperature is above 400° C.

12. The process for protecting an article comprising a substrate as claimed in claim 7 , wherein the functional coating is deposited by magnetron sputtering and wherein the temporary protective layer is directly in contact with the functional coating.

13. The process for protecting an article comprising a glass substrate as claimed in claim 7 , wherein the liquid composition comprises less than 20% by weight of solvent with respect to the total weight of the liquid composition and has a viscosity between 0.05 and 5 Pa·s.

Assignees

• Saint Gobain

Inventors

• Nadaud Nicolas
• Morlens Stéphanie
• Rachet Vincent

Classifications

• C09D133/08 Primary

  Homopolymers or copolymers of acrylic acid esters · CPC title

• C23C14/58

  After-treatment · CPC title

• C23C14/5873

  Removal of material · CPC title

• C23C14/0641

  Nitrides (C23C14/0617 takes precedence) · CPC title

• C09D5/008

  Temporary coatings (C09D5/20 takes precedence) · CPC title