Medium-voltage or high-voltage electrical device

Patent metadata

Field	Value
Publication number	US-10134503-B2
Application number	US-201515528703-A
Country	US
Kind code	B2
Filing date	Nov 12, 2015
Priority date	Nov 26, 2014
Publication date	Nov 20, 2018
Grant date	Nov 20, 2018

Abstract

A semi-conductive crosslinked layer produced from a polymer composition includes at least one polymer A having at least one epoxy function. A cross-linking agent B includes at least one reactive function that can react with the epoxy function of said polymer A in order to allow the cross-linking of said polymer A. The polymer composition also has an electrically conductive filler having a specific surface area BET of at least 100 m2/g according to the ASTM standard D 6556.

First claim

The invention claimed is:

1. An electrical device comprising:
a semiconductive crosslinked layer obtained from a polymer composition comprising:
at least one polymer A comprising at least one epoxy functional group; and
a crosslinking agent B comprising at least one reactive functional group capable of reacting with the epoxy functional group of said polymer A in order to allow the crosslinking of said polymer A,
wherein the polymer composition additionally comprises an electrically conductive filler having a BET specific surface area of at least 100 m 2 /g according to ASTM standard D 6556 (2014), and wherein the electrical conductivity of the polymer composition is lower than the electrical conductivity of the crosslinked layer.

2. The electrical device as claimed in claim 1 , wherein the electrical conductivity of the polymer composition is preferably at least 10 times lower than the electrical conductivity of the crosslinked layer.

3. The electrical device as claimed in claim 1 , wherein the amount of said electrically conductive filler is sufficient to allow the polymer composition to undergo a dynamic percolation transition.

4. The electrical device as claimed in claim 1 , wherein the electrical conductivity of the crosslinked layer is at least 1·10 −3 S/m measured at 25° C. under a direct current.

5. The electrical device as claimed in claim 1 , wherein polymer A is obtained from at least one olefin polymer.

6. The electrical device as claimed in claim 1 , wherein the polymer composition comprises more than 50 parts by weight of polymer A per 100 parts by weight of polymer(s) in the polymer composition.

7. The electrical device as claimed in claim 1 , wherein the gel content of the crosslinked layer, according to ASTM standard D 2765-01, is at least 50%.

8. The device as claimed in claim 1 , wherein the aspect ratio of the electrically conductive filler is at least 10.

9. The device as claimed in claim 1 , wherein the electrically conductive filler is a carbon filler.

10. The device as claimed in claim 1 , wherein the electrically conductive filler is chosen from among carbon blacks, carbon fibers, graphites, graphenes, fullerenes, carbon nanotubes, and a mixture thereof.

11. The device as claimed in claim 1 , wherein the polymer composition comprises at most 20.0 parts by weight of electrically conductive filler per 100 parts by weight of polymer A.

12. The device as claimed in claim 1 , wherein the polymer composition is an electrical insulator.

13. The device as claimed in claim 1 , the polymer composition additionally comprises a compound C comprising:
at least one aromatic group; and
a reactive group capable of interacting physically with the hydroxy functional group formed by the opening of said epoxy functional group during the crosslinking of polymer A.

14. The device as claimed in claim 13 , wherein the reactive group of the compound C comprises a hydrogen atom.

15. The device as claimed in claim 13 , wherein the reactive group of the compound C takes the form of a hydroxy group (OH) and/or an amine group (NH).

16. The device as claimed in claim 1 , wherein the polymer A comprises at least one compound chosen from among the glycidyl esters.

17. The device as claimed in claim 1 , wherein the polymer A comprises at most 10% by weight of epoxy functional group.

18. The electrical device as claimed in claim 1 , wherein the crosslinking agent B is a non-polymeric compound.

19. The device as claimed in claim 1 , wherein the reactive functional group of the crosslinking agent B is chosen from among an anhydride functional group, a carboxyl functional group and an amine functional group.

20. The device as claimed in claim 1 , wherein the crosslinking agent comprises an amine functional group and a carboxyl functional group.

21. The device as claimed in claim 1 , wherein the device is an electrical cable comprising an elongated electrically conductive element surrounded by said semiconductive crosslinked layer.

22. The device as claimed in claim 21 , wherein the electrical cable comprises a first semiconductive layer surrounding the elongated electrically conductive element, an electrically insulating layer surrounding the first semiconductive layer, and a second semiconductive layer surrounding the electrically insulating layer, the crosslinked layer being the first and/or the second semiconductive layer.

23. The device as claimed in claim 1 , wherein said device is an accessory for an electrical cable, said accessory comprising said crosslinked layer.

24. The device as claimed in claim 23 , wherein the accessory is a junction or a termination for an electrical cable.

Assignees

• Nexans

Inventors

• Combessis Anthony
• Keromnes Laurent
• Maugin Melek
• Carteron Lucile

Classifications

• H01R4/10

  effected solely by twisting, wrapping, bending, crimping, or other permanent deformation · CPC title

• H01B3/40 Primary

  epoxy resins · CPC title

• H01B3/447

  from acrylic compounds · CPC title

• H01B3/441

  from alkenes · CPC title

• C08F224/00

  Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a heterocyclic ring containing oxygen (cyclic esters of polyfunctional acids C08F218/00; cyclic anhydrides of unsaturated acids C08F220/00, C08F222/00) · CPC title