Fissure-detection agent, method for the production thereof and use of the fissure-detection agent

Patent metadata

Field	Value
Publication number	US-10132759-B2
Application number	US-201415028124-A
Country	US
Kind code	B2
Filing date	Oct 7, 2014
Priority date	Oct 9, 2013
Publication date	Nov 20, 2018
Grant date	Nov 20, 2018

Abstract

The invention relates to fissure-detection agents for fault detection according to the penetration method of metallic and/or non-metallic components, which are a microemulsion comprising at least 10 wt. % of water A), at least 0.1 wt. % of at least one dye B), at least 5 wt. % of at least one substantially water-insoluble liquid phase C) and at least 2 wt. % of at least one surfactant D) selected from non-ionic, anionic and/or amphoteric surfactants, the sum of all constituents being 100 wt. %, wherein the fissure-detection agent has a mean particle size in the range of 1 to 250 nm and a transparency of at least 70% at 600 nm. The invention also relates to the production of said fissure-detection agents, to a process for their preparation or/and disposal, and their use.

First claim

The invention claimed is:

1. A penetrant testing medium for defect detection comprising a microemulsion comprising:
A) at least 10 wt. % water;
B) at least 0.1 wt. % of at least one dye, wherein the dye comprises a solubility in water of less than 0.1 g/L at 20° C. and atmospheric pressure;
C) at least 5 wt. % of at least one substantially water-insoluble liquid phase comprising one or more organic compounds, wherein the one or more organic compounds exhibit a solubility of at most 60 g/L in distilled water at 20° C. and atmospheric pressure;
D) at least 2 wt. % of at least one surfactant selected from non-ionic surfactants, anionic surfactants, amphoteric surfactants and combinations thereof;

wherein the penetrant testing medium comprises an average particle size ranging from 1 to 250 nm measured with a Malvern Zetasizer Nano ZS, and the penetrant testing medium comprises a transparency of at least 70% at 600 nm in a quartz cuvette for a 10 mm thickness of an irradiated liquid at a temperature of 20° C. and atmospheric pressure measured by a Hach Lange GmbH CADA 100-V photometer using the microemulsion absent the at least one dye.

2. The penetrant testing medium of claim 1 comprising an oil-in-water microemulsion (O/W) or water-in-oil microemulsion (W/O), wherein instead of oil, at least one other water-immiscible liquid is used.

3. The penetrant testing medium of claim 2 , wherein the O/W comprises at least 30 wt. % water.

4. The penetrant testing medium of claim 2 , wherein the penetrant testing medium comprises an O/W microemulsion and the penetrant testing medium further comprises:
30 wt. % to 80 wt. % water (A);
0.1 wt. % to 10 wt. % of at least one dye (B), wherein the at least one dye (B) comprises yellow fluorescent dye, red fluorescent dye, or combinations thereof;
5 wt. % to 50 wt. % of the at least one substantially water-insoluble liquid phase (C); and
2 wt. % to 60 wt. % of the at least one surfactant (D).

5. The penetrant testing medium of claim 2 , wherein the penetrant testing medium comprises an O/W microemulsion and the penetrant testing medium further comprises:
30 wt. % to 70 wt. % water (A);
0.1 wt. % to 10 wt. % of at least one dye (B), wherein the at least one dye (B) comprises red dye, white dye or combinations thereof;
5 wt. % to 45 wt. % of the at least one substantially water-insoluble liquid phase (C); and
2 wt. % to 55 wt. % of the at least one surfactant (D).

6. The penetrant testing medium of claim 2 , wherein the penetrant testing medium comprises an O/W microemulsion and the penetrant testing medium further comprises:
10 wt. % to 60 wt. % water (A);
0.1 wt. % to 10 wt. % of at least one dye (B), wherein the at least one dye (B) comprises yellow fluorescent dye, red fluorescent dye, or combinations thereof;
5 wt. % to 40 wt. % of the at least one substantially water-insoluble liquid phase (C); and
2 wt. % to 50 wt. % of the at least one surfactant (D).

7. The penetrant testing medium of claim 2 , wherein the penetrant testing medium comprises an O/W microemulsion and the penetrant testing medium further comprises:
10 wt. % to 60 wt. % water (A);
0.1 wt. % to 10 wt. % of at least one dye (B), wherein the at least one dye (B) comprises white dye, red dye, or combinations thereof;
5 wt. % to 40 wt. % of the at least one substantially water-insoluble liquid phase (C); and
2 wt. % to 40 wt. % of the at least one surfactant (D).

8. The penetrant testing medium of claim 1 , wherein the dye is selected from fluorescent dyes, dyes comprising a color in a visible light region, dyes detectable under UV light and combinations thereof.

9. The penetrant testing medium of claim 1 , wherein the at least one substantially water insoluble liquid phase (C) comprises an organic solvent, the microemulsion comprises less than 40 wt. % surfactant (D) and wherein the at least one dye (B) is completely dissolved or dissolved as completely as possible in at least one compound of the substantially water-insoluble phase (C).

10. The penetrant testing medium of claim 1 , wherein one or more organic compounds of the at least one substantially water insoluble liquid phase (C) are selected from alcohols, esters of carboxylic acids, amides of carboxylic acids, phosphoric esters, ethers, ketones, oils, ether derivatives of diols, ester derivatives of diols, ether derivatives of polyols, ester derivatives of polyols, and combinations thereof and derivatives thereof.

11. The penetrant testing medium of claim 1 , wherein the at least one surfactant (D) also acts as an emulsifier and comprises at least one non-ionic surfactant and at least one anionic surfactant (D).

12. The penetrant testing medium of claim 1 , wherein the microemulsion further comprises at least one additive (E) selected from preservatives, corrosion inhibitors, neutralizing agents, solubilizers, rheological additives and combinations thereof.

13. The penetrant testing medium of claim 1 , wherein the microemulsion is single-phase, two phase or three phase.

14. The penetrant testing medium of claim 1 further comprising a luminosity of at least 60%.

15. A method for producing the penetrant testing medium of claim 1 comprising:
dissolving the at least one dye (B) in at least a portion of the substantially water-insoluble liquid phase (C) to form a solution;
introducing the at least one surfactant (D) into the solution to form a mixture; and
introduction water (A) into the mixture;

wherein the at least one surfactant (D) is introduced in a solution, dispersion or combination thereof.

Assignees

• Chemetall Gmbh

Inventors

• Bons Peter
• Rein Rüdiger
• Wörner Jörg
• Aiston Finlay

Classifications

• G01M3/22

  for pipes, cables or tubes; for pipe joints or seals; for valves; {for welds; for containers, e.g. radiators} · CPC title

• C09B67/0071

  Process features in the making of dyestuff preparations; Dehydrating agents; Dispersing agents; Dustfree compositions · CPC title

• G01N21/91 Primary

  using penetration of dyes, e.g. fluorescent ink · CPC title

• C09B67/0033

  Blends of pigments; Mixtured crystals; Solid solutions · CPC title