Method for smut removal during stripping of coating

Patent metadata

Field	Value
Publication number	US-10125425-B2
Application number	US-201313932394-A
Country	US
Kind code	B2
Filing date	Jul 1, 2013
Priority date	Jul 1, 2013
Publication date	Nov 13, 2018
Grant date	Nov 13, 2018

Abstract

Stripping a metallic bond coat from an article using a wet chemical process. An article removed from service and having a metallic bond coat applied over a surface of its metallic substrate is provided. The metallic bond coat is used to improve the adhesion of a TBC to the article, so grit blasting to first remove any TBC applied over the bond coat and which still remains on the article initially may be required. The bond coated article is then immersed in an acid solution of HCl/H 3 PO 4 at a predetermined temperature for a predetermined amount of time, the HCl/H 3 PO 4 solution reacting with the bond coat applied over the metallic substrate to form a smut on the surface. The article is then removed from the HCl/H 3 PO 4 solution and quickly immersed in a solution of NaOH for a predetermined amount of time to at least partially desmut the surface.

First claim

The invention claimed is:

1. A method for stripping a metallic bond coating from an article, comprising the steps of:
providing the article having the metallic bond coating applied over a surface of a metallic substrate, wherein the metallic bond coating is a MCrAlX metallic bond coating, wherein M is selected from the group consisting of Ni, Co, Fe, and combinations thereof and X is selected from the group consisting of Y, Ti, Ta, Re, Mo, W, B, C, Hf, and Zr;
immersing the article in a first solution consisting essentially of HCl, H 3 PO 4 , and water for a first immersion such that the first solution reacts with the metallic bond coating to form a first smut; then
removing the article from the first solution and immersing the article in a second solution comprising NaOH to remove the first smut; then
removing the article from the second solution and rinsing the article with water to remove any residual first smut; then
immersing the article in the first solution for a second immersion such that the first solution reacts with any remaining metallic bond coating to form a second smut; then
removing the article from the first solution and immersing the article in a third solution comprising NaOH to remove any additional second smut; then
removing the article from the third solution.

2. The method of claim 1 further including the additional step, after removing the article from the third solution, of rinsing the article with water to remove any residual second smut and neutralizing the NaOH.

3. The method of claim 1 further including the additional steps of:
after providing the article, the article having the metallic bond coating comprising an aluminide bond coat, first masking any cooling holes in the article, then
grit blasting the article to remove any thermal barrier coating overlying the aluminide bond coat.

4. The method of claim 1 further including a step of mechanically removing any residual first smut from the article after the first rinsing with water step.

5. The method of claim 1 wherein the step of providing the article having the metallic bond coating applied includes providing a turbine component selected from the group consisting of a turbine bucket, a turbine vane, a shroud, a liner, and a combustor.

6. The method of claim 1 wherein the step of immersing the article in the first solution includes immersing the article in the first solution at a temperature of 145-155° F.

7. The method of claim 1 wherein the first solution consists essentially of, in weight percent, 25-35% HCl, 30-40% H 3 PO 4 , and the balance water.

8. A method for stripping a thermal barrier coating and a metallic bond coating from an article, comprising the steps of:
providing the article having the thermal barrier coating overlying the metallic bond coating applied over a surface of a metallic substrate, the metallic bond coating being intermediate the substrate and the thermal barrier coating;
stripping the thermal barrier coating overlying the bond coating to remove the thermal barrier coating; then
immersing the article in a first solution consisting of HCl, H 3 PO 4 , and water for a first immersion such that the first solution reacts with the bond coating to form a first smut; then
removing the article from the first solution and immersing the article in a basic desmutting agent to remove the first smut; then
removing the article from the basic desmutting agent and dipping the article in water at a temperature of at least 90° F. having a neutral pH; then
inspecting the article; then
mechanically removing any residual first smut from the article if residual first smut is identified during article inspection;
immersing the article in a second solution of HCl, H 3 PO 4 , and water for a second immersion such that the second solution reacts with any remaining metallic bond coating to form a second smut; then
removing the article from the second solution and immersing the article in a basic solution to remove any second smut; then
removing the article from the basic solution and contacting the article with water to remove any residual second smut.

9. The method of claim 8 wherein the step of stripping the thermal barrier coating includes grit blasting.

10. The method of claim 8 wherein the first solution consists of, in weight percent, 25-35% HCl, 30-40% H 3 PO 4 , and the balance water.

11. The method of claim 10 wherein the first solution consists of, in weight percent, 30% HCl, 35% H 3 PO 4 , and the balance water.

12. The method of claim 8 wherein the step of immersing the article in a basic desmutting agent further includes NaOH as the basic desmutting agent.

13. The method of claim 12 wherein the NaOH has a concentration, in weight percent, in the range of 15-30% and a pH above 10.

14. The method of claim 12 wherein the NaOH is maintained at a temperature in the range of 60−90° F.

15. A method for stripping a metallic bond coating from an article, comprising the steps of:
providing the article having the metallic bond coating applied over a surface of a metallic substrate;
immersing the article in a first solution consisting of HCl, H 3 PO 4 , and water for a first immersion such that the first solution reacts with the metallic bond coating to form a first smut then
removing the article from the first solution and immersing the article in a second solution comprising NaOH to remove the first smut then
removing the article from the second solution and rinsing the article with water to remove any residual first smut then
immersing the article in the first solution for a second immersion such that the first solution reacts with any remaining metallic bond coating to form a second smut then
removing the article from the first solution and immersing the article in a third solution comprising NaOH to remove any additional second smut then
removing the article from the third solution.

16. A method for stripping a metallic bond coating from a turbine component removed from service, comprising the steps of:
providing the turbine component having the metallic bond coating applied over a surface of a metallic substrate;
immersing the turbine component in a first solution consisting of HCl, H 3 PO 4 , and water for a first immersion, wherein the first solution reacts with the metallic bond coating to form a first smut; then
removing the turbine component from the first solution and immersing the turbine component in a second solution comprising NaOH to remove the first smut; then
removing the turbine component from the second solution and rinsing the turbine component with water to remove any residual first smut; then
immersing the turbine component in the first solution for a second immersion, wherein the first solution reacts with any remaining metallic bond coating to form a second smut; then
removing the turbine component from the first solution and immersing the turbine component in a third solution comprising NaOH to remove the second smut; then
removing the turbine component from the third solution.

17. The method of claim 16 further including the additional steps of:
after providing the turbine component, the metallic bond coating comprising an aluminide bond coat, first masking any cooling holes in the turbine component, then
grit blasting the turbine component to remove any thermal barrier coating overlying the aluminide bond coat.

18. The method of claim 16 further including a step of mechanically removing any residual first smut from the turbine component after the first rinsing with water step.

Assignees

• Gen Electric

Inventors

• Ward Jr John David
• Zhang Liming

Classifications

• C23G1/20

  Other heavy metals · CPC title

• C23G1/02 Primary

  with acid solutions · CPC title

• C23F1/20 Primary

  for etching aluminium or alloys thereof · CPC title

• C23F1/44

  Compositions for etching metallic material from a metallic material substrate of different composition · CPC title

• F01D5/005

  Repairing methods or devices · CPC title