Method for the separation of diamond particle clusters

Patent metadata

Field	Value
Publication number	US-10125065-B2
Application number	US-201314396093-A
Country	US
Kind code	B2
Filing date	Apr 26, 2013
Priority date	Apr 27, 2012
Publication date	Nov 13, 2018
Grant date	Nov 13, 2018

Abstract

A method for the separation of diamond particle clusters into discrete diamond particles and/or into smaller diamond particle clusters comprising fewer diamond particles is disclosed.
The diamond particle clusters are combined with at least one liquid phase organic or inorganic compound, or with a solution of at least one organic or inorganic compound in at least one solvent to form a reaction mixture. Mechanical means are then used to separate the diamond particle clusters into discrete diamond particles and/or into smaller clusters within the reaction mixture producing diamond particles with dangling bonds or free bonding sites on the surface of the diamond particles. The at least one organic or inorganic compound then reacts with these dangling bonds present on the diamond particle surface. The surfaces of the diamond particles are functionalized by the reaction with the organic or inorganic compounds and the diamond particles and/or smaller clusters produced are well dispersed in dry powder form, as well as in solution.

First claim

The invention claimed is:

1. A method for the separation of diamond particle clusters having a diameter of less than or equal to 1.0 mm into discrete diamond particles and/or into smaller clusters comprising fewer diamond particles, the method comprising the steps of:
a) combining the diamond particle clusters with at least one liquid phase unsaturated organic compound, or with a solution of at least one unsaturated organic compound in at least one solvent, to form a reaction mixture, the unsaturated organic compound comprising at least one carbon-carbon double bond or carbon-carbon triple bond; and
b) introducing milling beads to the reaction mixture and producing diamond particles with dangling bonds on the surface of the diamond particles by imparting kinetic energy to the diamond particle clusters within the reaction mixture using mechanical means to break up the diamond particle clusters into discrete diamond particles and/or into smaller clusters comprising fewer diamond particles causing the at least one unsaturated organic compound to react with at least some of the dangling bonds on the diamond particles;
wherein imparting kinetic energy to the diamond particle clusters is performed in a plurality of cycles, with each cycle of imparting kinetic energy to the diamond particle clusters being followed by a period of cooling the reaction mixture.

2. A method according to claim 1 , wherein step b) includes shaking or stirring the reaction mixture or applying ultrasonication to the reaction mixture.

3. A method according to claim 2 , wherein the reaction mixture is shaken at a frequency of at least 10 Hz.

4. A method according to claim 2 , wherein ultrasonication is applied to the reaction mixture at a frequency of not more than 80 kHz.

5. A method according to claim 1 , wherein the milling beads are ceramic milling beads.

6. A method according to claim 5 , wherein the milling beads are selected from the group comprising zirconia beads and silica beads and mixtures thereof.

7. A method according to claim 1 , wherein the milling beads are larger than the diamond particles by a factor of between 100 and 100000.

8. A method according to claim 1 , wherein the diamond particles have a diameter of 0.5 mm or less.

9. A method according to claim 1 , wherein the diamond particles are nanodiamond particles and have a diameter in the range 1 to 1000 nm.

10. A method according to claim 1 , wherein the at least one unsaturated organic compound is a straight chain alkene.

11. A method according to claim 1 , wherein the at least one unsaturated organic compound is unsaturated at the first position.

12. A method according to claim 1 , wherein the at least one unsaturated organic compound comprises a number of carbon atoms in the range 6 to 12.

13. A method according to claim 1 , wherein the period of cooling the reaction mixture cools the liquid phase unsaturated organic compound to a temperature of not more than the boiling point of the reaction mixture.

14. A method according to claim 1 , further comprising:
c) separating the discrete diamond particles from the milling beads.

15. A method according to claim 14 , wherein in step c) the diamond particles are separated from the milling beads using a method selected from the group comprising: filtration, centrifugation, extraction, precipitation, decantation and combinations thereof.

16. A method according to claim 1 , further comprising the step of isolating the discrete diamond particles in solid form.

17. A method for the separation of diamond particle clusters having a diameter of less than or equal to 1.0 mm into discrete diamond particles and/or into smaller clusters comprising fewer diamond particles, the method comprising the steps of:
a) combining the diamond particle clusters with at least one liquid phase unsaturated organic compound, or with a solution of at least one unsaturated organic compound in at least one solvent, to form a reaction mixture, the unsaturated organic compound comprising at least one carbon-carbon double bond or carbon-carbon triple bond; and
b) creating diamond particles with dangling bonds on the surface of the diamond particles by imparting kinetic energy to the diamond particle clusters within the reaction mixture using mechanical means to break up the diamond particle clusters into discrete diamond particles and/or into smaller clusters comprising fewer diamond particles causing the at least one unsaturated organic compound to react with at least some of the dangling bonds on the diamond particles.

Assignees

• Univ Newcastle

Inventors

• Siller Lidija
• Butenko Yuriy

Classifications

• C07C9/22 Primary

  with more than fifteen carbon atoms · CPC title

• C07C2/86

  by condensation between a hydrocarbon and a non-hydrocarbon · CPC title

• C01B32/28 Primary

  After-treatment, e.g. purification, irradiation, separation or recovery · CPC title

• B82B3/0061

  Methods for manipulating nanostructures · CPC title

• B82B3/0009

  Forming specific nanostructures · CPC title