Coated article

Patent metadata

Field	Value
Publication number	US-10113069-B2
Application number	US-201615153167-A
Country	US
Kind code	B2
Filing date	May 12, 2016
Priority date	Dec 27, 2013
Publication date	Oct 30, 2018
Grant date	Oct 30, 2018

Abstract

To provide a coated article, in which formation of a cured film having a fluororesin layer and a polyester layer is not cumbersome, and the cured film is excellent in weather resistance. A coated article having a cured film formed by coating a substrate with a powder coating material comprising a fluorinated polymer (A), a polyester polymer (B), an ultraviolet absorber (C) and titanium oxide (E), wherein the thickness of the cured film is from 20 to 1,000 μm, the atom number concentration of Ti element present in a region (I) within 5 μm in depth from the surface of the cured film is from 0 to 9%, the atom number concentration of Ti element present in a region (II) beyond 10 μm in depth from the surface of the cured film is from 8.5 to 10%, and the proportion of the ultraviolet absorber (D) contained in the region (I) (100 mass %) is from 0.5 to 10 mass %.

First claim

What is claimed is:

1. A coated article comprising:
a substrate: and
a cured film of a powder coating material formed on the substrate, the powder coating material comprising a fluorinated polymer (A), a polyester polymer (B), an ultraviolet absorber (D) and titanium oxide (E), wherein
the thickness of the cured film is from 20 to 1,000 μm,
the atom number concentration of Ti element in region (I) within 5 μm in depth from a surface of the cured film is from 0 to 7.5% as obtained by method (1), with respect to 100% of the total of the atom number concentrations of C element, O element, F element and Ti element present in region (I),
the atom number concentration of Ti element in region (II) beyond 10 μm in depth from the surface of the cured film is from 8.5 to 15% as obtained by method (2), with respect to 100% of the total of the atom number concentrations of C element, O element, F element and Ti element present in region (II), and
the proportion of the ultraviolet absorber (D) contained in region (I) (100 mass %) as obtained by method (3) is from 0.5 to 10 mass %:
method (1):
by observing a cross section of the cured film by a scanning electron microscope equipped with an energy dispersive X-ray analyzer, the respective atom number concentrations of C element, O element, F element and Ti element present in region (I) are analyzed by the energy dispersive X-ray analyzer, to determine the atom number concentration of Ti element, when the total of the respective atom number concentrations of C element, O element, F element and Ti element is set to be 100%,
method (2):
by observing a cross section of the cured film by a scanning electron microscope equipped with an energy dispersive X-ray analyzer, with respect to region (II-1) in a case where the thickness of the cured film is at least 20 μm and less than 30 μm, regions (II-1) to (II-2) in a case where the thickness of the cured film is at least 30 μm and less than 40 μm, regions (II-1) to (II-3) in a case where the thickness of the cured film is at least 40 μm and less than 50 μm, regions (II-1) to (II-4) in a case where the thickness of the cured film is at least 50 μm and less than 60 μm, regions (II-1) to (II-5) in a case where the thickness of the cured film is at least 60 μm, the respective atom number concentrations of C element, O element, F element and Ti element present in the respective regions are analyzed by the energy dispersive X-ray analyzer, to determine the atom number concentration of Ti element, when the total of the respective atom number concentrations of C element, O element, F element and Ti element is set to be 100%, in each region, whereupon the atom number concentrations of Ti element in the respective regions are summed up and divided by the number of regions to obtain an average value,
region (II-1): a region beyond 10 μm and at most 20 μm in depth from the surface of the cured film,
region (II-2 ): a region beyond 20 μm and at most 30 μm in depth from the surface of the cured film,
region (II-3): a region beyond 30 μm and at most 40 μm in depth from the surface of the cured film,
region (II-4): a region beyond 40 μm and at most 50 μm in depth from the surface of the cured film,
region (II-5): a region beyond 50 μm and at most 60 μm in depth from the surface of the cured film,
method (3):
a powder obtained by scraping off region (I) with a cutter is subjected to high performance liquid chromatography analysis, whereby the amount of the ultraviolet absorber (D) per unit mass in the powder is obtained from a peak derived from the ultraviolet absorber (D) by using a calibration curve prepared beforehand.

2. The coated article according to claim 1 , wherein the coating is one-coating.

3. The coated article according to claim 1 , wherein the thickness of the cured film is from 20 to 300 μm.

4. The coated article according to claim 1 , wherein the powder coating material further comprises a curing agent (C).

5. The coated article according to claim 1 , wherein the fluorinated polymer (A) is at least one member selected from the group consisting of a hydroxy group-containing fluorinated polymer (A1), a carboxy group-containing fluorinated polymer (A2) and a polyvinylidene fluoride.

6. The coated article according to claim 1 , wherein the polyester polymer (B) is a polyester polymer having units derived from a C 8-15 aromatic polycarboxylic acid compound and units derived from a C 2-10 polyhydric alcohol compound.

7. The coated article according to claim 1 , wherein the ultraviolet absorber (D) is an organic ultraviolet absorber.

8. The coated article according to claim 1 , wherein the content ratio ((A)/(B)) of the fluorinated polymer (A) to the polyester polymer (B) in the powder coating material is from 90/10 to 10/90 by mass ratio.

9. The coated article according to claim 1 , wherein the content of the ultraviolet absorber (D) in the powder coating material, is from 0.1 to 20 parts by mass, with respect to 100 parts by mass of the fluorinated polymer (A).

10. The coated article according to claim 1 , wherein the content of titanium oxide (E) in the powder coating material, is from 20 to 200 parts by mass, with respect to 100 parts by mass of the polyester polymer (B).

11. The coated article according to claim 1 , wherein the powder coating material is a powder coating material (I) comprising a powder (X) made of a composition (α) comprising the fluorinated polymer (A), the polyester polymer (B), the ultraviolet absorber (D) and titanium oxide (E).

12. The coated article according to claim 11 , wherein the composition (α) comprises a curing agent (C).

13. The coated article according to claim 1 , wherein the powder coating material is a powder coating material (II) which comprises a powder (Y) made of a composition (β) comprising the fluorinated polymer (A), and a powder (Z) made of a composition (γ) comprising the polyester polymer (B) and not comprising the fluorinated polymer (A), wherein either one or both of the composition (β) and the composition (γ) comprise the ultraviolet absorber (D), and either one or both of the composition (β) and the composition (γ) comprise titanium oxide (E).

14. The coated article according to claim 13 , wherein either one or both of the composition (β) and the composition (γ) comprise contain a curing agent (C).

15. The coated article according to claim 1 , wherein the ratio ((A)/(B)) of the cured product of the fluorinated polymer (A) as calculated as the fluorinated polymer (A) to the cured product of the polyester polymer (B) as calculated as the polyester polymer (B), contained in the entire cured film, is from 90/10 to 10/90 by mass ratio.

16. The coated article according to claim 1 , wherein titanium oxide (E) is surface-treated with at least one selected from silica, alumina, zirconia, selenium, and an organic component.

17. The coated article according to claim 1 , wherein the content of titanium oxide (E) in the powder coating material, is from 50 to 200 parts by mass, to 100 parts by mass of the polyester polymer (B).

Assignees

• Asahi Glass Co Ltd
• Agc Inc

Inventors

• Saito Shun
• Aikawa Masataka

Classifications

• C09D129/10

  Homopolymers or copolymers of unsaturated ethers (C09D135/08 takes precedence) · CPC title

• C09D5/036 Primary

  Stabilisers (organic stabilisers for paints C09D7/48) · CPC title

• C09D7/40

  Additives · CPC title

• B05D5/083

  involving the use of fluoropolymers · CPC title

• B32B5/16

  characterised by features of a layer formed of particles, e.g. chips, powder {or granules (layer formed of natural mineral particles B32B19/00; layer being formed of wood fibres, chips or particles B32B21/02)} · CPC title