Dispersant attached polytetrafluoroethylene particle, composition, layered material, electrophotographic photoreceptor, process cartridge, and image forming apparatus

US2020002525A1 · US · A1

Patent metadata
FieldValue
Publication numberUS-2020002525-A1
Application numberUS-201916567458-A
CountryUS
Kind codeA1
Filing dateSep 11, 2019
Priority dateJun 15, 2018
Publication dateJan 2, 2020
Grant date

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  1. Title

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  5. First independent claim

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Abstract

Official abstract text for this publication.

A dispersant attached polytetrafluoroethylene particle on whose surface a dispersant having a fluorine atom is attached has a content of perfluorooctanoic acid of from 0 ppb to 25 ppb with respect to the polytetrafluoroethylene particle, and a composition contains a polytetrafluoroethylene particle and a dispersant having a fluorine atom in which a content of perfluorooctanoic acid is from 0 ppb to 25 ppb with respect to the polytetrafluoroethylene particle.

First claim

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What is claimed is: 1 . A dispersant attached polytetrafluoroethylene particle on whose surface a dispersant having a fluorine atom is attached, wherein a content of perfluorooctanoic acid is from 0 ppb to 25 ppb with respect to the polytetrafluoroethylene particle. 2 . The dispersant attached polytetrafluoroethylene particle as claimed in claim 1 , which has an average particle diameter of from 0.2 μm to 4.5 μm. 3 . The dispersant attached polytetrafluoroethylene particle as claimed in claim 1 , wherein the dispersant having a fluorine atom is a polymer obtained by homopolymerization or copolymerization of a polymerizable compound having a fluorinated alkyl group. 4 . The dispersant attached polytetrafluoroethylene particle as claimed in claim 3 , wherein the polymer obtained by homopolymerization or copolymerization of a polymerizable compound having a fluorinated alkyl group is a fluorinated alkyl group-containing polymer having a structural unit represented by the following formula (FA) or a fluorinated alkyl group-containing polymer having a structural unit represented by the following formula (FA) and a structural unit represented by the following formula (FB): wherein, in the formulae (FA) and (FB), each of R F1 , R F2 , R F3 and R F4 independently represents a hydrogen atom or an alkyl group; X F1 represents an alkylene chain, a halogen-substituted alkylene chain, —S—, —O—, —NH— or a single bond; Y F1 represents an alkylene chain, a halogen-substituted alkylene chain, —C fx H 2fx-1 (OH))- or a single bond; Q F1 represents —O— or —NH—; each of fl, fm and fn independently represents an integer of 1 or more; each of fp, fq, fr and fs independently represents 0 or an integer of 1 or more; ft represents an integer of 1 to 7; and fx represents an integer of 1 or more. 5 . The dispersant attached polytetrafluoroethylene particle as claimed in claim 1 , wherein a content of the dispersant having a fluorine atom is from 0.5% by weight to 10% by weight with respect to the polytetrafluomethylene particle. 6 . The dispersant attached polytetrafluomethylene particle as claimed in claim 5 , wherein the content of the dispersant having a fluorine atom is from 1% by weight to 7% by weight with respect to the polytetrafluoroethylene particle. 7 . A composition comprising a polytetrafluoroethylene particle and a dispersant having a fluorine atom, wherein a content of perfluorooctanoic acid is from 0 ppb to 25 ppb with respect to the polytetrafluoroethylene particle. 8 . The composition as claimed in claim 7 , wherein an average particle diameter of the polytetrafluoroethylene particle is from 0.2 μm to 4.5 μm. 9 . The composition as claimed in claim 7 , which is in a liquid state or in a solid state. 10 . The composition as claimed in claim 7 , wherein the dispersant having a fluorine atom is a polymer obtained by homopolymerization or copolymerization of a polymerizable compound having a fluorinated alkyl group. 11 . The composition as claimed in claim 10 , wherein the polymer obtained by homopolymerization or copolymerization of a polymerizable compound having a fluorinated alkyl group is a fluorinated alkyl group-containing polymer having a structural unit represented by the following formula (FA) or a fluorinated alkyl group-containing polymer having a structural unit represented by the following formula (FA) and a structural unit represented by the following formula (FB): wherein, in the formulae (FA) and (FB), each of R F1 , R F2 , R F3 and R F4 independently represents a hydrogen atom or an alkyl group; X F1 represents an alkylene chain, a halogen-substituted alkylene chain, —S—, —O—, —NH— or a single bond; Y F1 represents an alkylene chain, a halogen-substituted alkylene chain, —C fx H 2fx-1 (OH))— or a single bond; Q F1 represents —O— or —NH—; each of fl, fm and fn independently represents an integer of 1 or more; each of fp, fq, fr and fs independently represents 0 or an integer of 1 or more; ft represents an integer of 1 to 7; and fx represents an integer of 1 or more. 12 . The composition as claimed in claim 7 , wherein a content of the dispersant having a fluorine atom is from 0.5% by weight to 10% by weight with respect to the polytetrafluoroethylene particle. 13 . The composition as claimed in claim 12 , wherein the content of the dispersant having a fluorine atom is from 1% by weight to 7% by weight with respect to the polytetrafluoroethylene particle. 14 . A layered material comprising a polytetrafluoroethylene particle and a dispersant having a fluorine atom, wherein a content of perfluorooctanoic acid is from 0 ppb to 25 ppb with respect to the polytetrafluomethylene particle. 15 . The layered material as claimed in claim 14 , wherein an average particle diameter of the polytetrafluoroethylene particle is from 0.2 μm to 4.5 μm. 16 . The layered material as claimed in claim 14 , wherein the dispersant having a fluorine atom is a polymer obtained by homopolymerization or copolymerization of a polymerizable compound having a fluorinated alkyl group. 17 . The layered material as claimed in claim 16 , wherein the polymer obtained by homopolymerization or copolymerization of a polymerizable compound having a fluorinated alkyl group is a fluorinated alkyl group-containing polymer having a structural unit represented by the following formula (FA) or a fluorinated alkyl group-containing polymer having a structural unit represented by the following formula (FA) and a structural unit represented by the following formula (FB): wherein, in the formulae (FA) and (FB), each of R F1 , R F2 , R F3 and R F4 independently represents a hydrogen atom or an alkyl group; X F1 represents an alkylene chain, a halogen-substituted alkylene chain, —S—, —O—, —NH— or a single bond; Y F1 represents an alkylene chain, a halogen-substituted alkylene chain, —C fx H 2fx-1 (OH))— or a single bond; Q F1 represents —O— or —NH—; each of fl, fm and fn independently represents an integer of 1 or more; each of fp, fq, fr and fs independently represents 0 or an integer of 1 or more; ft represents an integer of 1 to 7; and fx represents an integer of 1 or more. 18 . The layered material as claimed in claim 14 , wherein a content of the dispersant having a fluorine atom is from 0.5% by weight to 10% by weight with respect to the polytetrafluoroethylene particle. 19 . The layered material as claimed in claim 18 , wherein the content of the dispersant having a fluorine atom is from 1% by weight to 7% by weight with respect to the polytetrafluoroethylene particle. 20 . An electrophotographic photoreceptor comprising a conductive substrate and a photosensitive layer, wherein an outermost surface layer of the electrophotographic photoreceptor is a layer comprising the layered material as claimed in claim 14 . 21 . The electrophotographic photoreceptor as claimed in claim 20 , wherein the outermost surface layer is a surface protective layer having a crosslinked structure. 22 . A process cartridge comprising the electrophotographic photoreceptor as claimed in claim 20 , wherein the process cartridge is detachably attached to an image forming apparatus.

Assignees

Inventors

Classifications

  • Details relating to xerographic drum, band or plate, e.g. replacing, testing (electrographic recording members per se G03G5/00) · CPC title

  • Stabilisers (organic stabilisers for paints C09D7/48) · CPC title

  • Anti-settling agents · CPC title

  • Homopolymers or copolymers or tetrafluoroethene · CPC title

  • Homopolymers or copolymers of tetrafluoroethene · CPC title

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What does patent US2020002525A1 cover?
A dispersant attached polytetrafluoroethylene particle on whose surface a dispersant having a fluorine atom is attached has a content of perfluorooctanoic acid of from 0 ppb to 25 ppb with respect to the polytetrafluoroethylene particle, and a composition contains a polytetrafluoroethylene particle and a dispersant having a fluorine atom in which a content of perfluorooctanoic acid is from 0 pp…
Who is the assignee on this patent?
Fuji Xerox Co Ltd
What technology area does this patent fall under?
Primary CPC classification C08L33/14. Mapped technology areas include Chemistry & Metallurgy.
When was this patent published?
Publication date Thu Jan 02 2020 00:00:00 GMT+0000 (Coordinated Universal Time) (A1). Legal status and post-grant events are not shown on this page.
What related patents are in patentsdb?
We list 2 related publications on this page (citations in our corpus or others sharing the same primary CPC).