Catalyst components for the polymerization of olefins

Patent metadata

Field	Value
Publication number	US-9481745-B2
Application number	US-201414917549-A
Country	US
Kind code	B2
Filing date	Sep 8, 2014
Priority date	Sep 9, 2013
Publication date	Nov 1, 2016
Grant date	Nov 1, 2016

Abstract

The present technology relates to a solid catalyst component for the polymerization of olefins comprising Mg, Ti and an electron donor of the general formula (I):

where R 1 is selected from C 1 -C 15 hydrocarbon groups, the R 2 groups are equal to or different from each other, are hydrogen, or the R 1 groups can be fused together to form one or more cycles and A is a bivalent bridging group. The catalyst components of the present disclosure exhibit high activity and stereospecificity in the polymerization of olefins.

First claim

What is claimed is:

1. A solid catalyst component for the polymerization of olefins comprising Mg, Ti and an electron donor of formula (I)

where R 1 is selected from C 1 -C 15 hydrocarbon groups, optionally containing a heteroatom selected from halogen, P, S, N and O; R 2 groups, equal to or different from each other, are hydrogen or R 1 groups which can be fused together to form one or more cycles and A is a bivalent bridging group.

2. The catalyst component of claim 1 , in which A is bivalent bridging group with chain length between the two free radicals being 1-10 atoms.

3. The catalyst component of claim 1 , in which the bridging group has formula —(ZR 3 m ) n — in which, independently, Z is selected from C, Si, Ge, O, N, S or P, the R 3 groups, equal to or different from each other, are hydrogen or C 1 -C 20 hydrocarbon radicals, optionally containing a heteroatom selected from halogen, P, S, N, O and Si, which can be fused together to form one or more cycles, m is a number satisfying the valences of Z and n is an integer ranging from 1 to 10.

4. The catalyst component of claim 3 , in which the bridging group is an aliphatic or alicyclic bridging group having a bridging chain length of 1-6 carbon atoms.

5. The catalyst component of claim 4 , in which the bridging group has formula —(CR 4 p ) s — in which R 4 is, independently, hydrogen or a C 1 -C 20 hydrocarbon radical, optionally substituted with heteroatoms selected from halogen, P, S, N, O and Si, which can be fused together to form one or more cycles, p is a number satisfying the available valence of carbon and s is a number from 1 to 6.

6. The catalyst component of claim 5 , in which the bridging group is selected from the group consisting of methyliden, ethane-1,2-diyl, butane-2,3-diyl, pentane-2,4-diyl, 2,2-diisobutylpropane-1,3-diyl, cyclohexane-1,2-diyl, and cyclopentane -1,2-diyl.

7. The catalyst component of claim 1 , in the which R 1 groups are selected from aryl and alkylaryl groups.

8. The catalyst component of claim 7 , in which R 1 groups are selected from phenyl groups.

9. The catalyst component of claim 8 , in which the phenyl groups are substituted with halogen and/or C 1 -C 5 alkyl groups.

10. The catalyst component of claim 1 , in which R 2 groups are independently selected from hydrogen or C 1 -C 10 alkyl groups.

11. The catalyst component of claim 3 , in which the bridging group is the one based on cyclic aromatic groups which through the carbon ring atoms can link the two oxygen of formula (I).

12. The catalyst component of claim 11 , in which the electron donor is selected from those having the following formula (II):

in which R 1 and R 2 have the same meaning according to claim 1 , and R 5 , independently, is selected from hydrogen, halogens or C 1 -C 15 hydrocarbon groups optionally substituted with heteroatoms selected from halogen, P, S, N, O and Si, with the proviso that at least one of R 5 is different from hydrogen.

13. A catalyst for the polymerization of olefins comprising the product of the reaction between:
(i) the solid catalyst component according to any of the preceding claims and
(ii) an alkylaluminum compound and optionally,
(iii) an external electron donor compound.

14. The catalyst of claim 13 , further comprising an external electron donor compound.

15. A process for the (co)polymerization of olefins CH 2 ═CHR, in which R is hydrogen or a hydrocarbyl radical with 1-12 carbon atoms, carried out in the presence of a catalyst system comprising the product of the reaction between:
i. the solid catalyst component of claim 1 ;
ii. an alkylaluminum compound and,
iii. optionally an external donor compound.

Assignees

• Basell Poliolefine Italia Srl

Inventors

• Mignogna Alessandro
• Chevalier Reynald
• Morini Giampiero
• Schneider Martin

Classifications

• C07C271/12

  to hydrogen atoms or to carbon atoms of unsubstituted hydrocarbon radicals · CPC title

• C08F110/06 Primary

  Propene · CPC title

• C08F4/651

  Pretreating with non-metals or metal-free compounds · CPC title

• C08F10/00

  Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond · CPC title

• C08F2500/12

  Melt flow index or melt flow ratio · CPC title