Process for recovering rubber from natural rubber latex

Patent metadata

Field	Value
Publication number	US-10113011-B2
Application number	US-201615364527-A
Country	US
Kind code	B2
Filing date	Nov 30, 2016
Priority date	Apr 14, 2008
Publication date	Oct 30, 2018
Grant date	Oct 30, 2018

Abstract

Processes for recovering natural rubber from an aqueous natural rubber latex that contains extractables and one or more additives and that is essentially free of lignocellulosic plant material are described. Natural rubber in the latex is separated from the water. Preferably, the amount of non-rubber extractables in the natural rubber is reduced by one or more extraction steps yielding a dried natural rubber.

First claim

What is claimed is:

1. A process for recovering rubber from an aqueous non- Hevea natural rubber latex that contains natural rubber, water, non-rubber extractables including resin, and one or more additives, and is essentially free of lignocellulosic plant material, comprising the steps of:
freezing the latex, whereby at least 75% of the natural rubber coagulates and a mixture containing coagulated natural rubber, water, and extractables is formed;
thawing the mixture;
collecting the coagulated natural rubber;
contacting the coagulated natural rubber with an extraction solution comprising at least one organic polar solvent in order to preferentially solvate the extractables; and
drying the coagulated natural rubber to create a resultant natural rubber wherein the resultant natural rubber has an amount of acetone extractables of 5% by weight or less.

2. The process as claimed in claim 1 , further comprising, prior to freezing the latex, the step of adding carbon black to the latex in an amount between 0.5% and 6% by weight of the resultant dried natural rubber.

3. The process as claimed in claim 1 , further comprising, prior to contacting the coagulated natural rubber with the extraction solution, the step of adding carbon black to the coagulated natural rubber in an amount between 0.5% and 6% by weight of the resultant dried natural rubber.

4. The process as claimed in claim 1 , wherein said at least one organic polar solvent is selected from the group consisting of alcohols having from 1 to 8 carbon atoms, ketones having from 3 to 8 carbon atoms, and combinations thereof.

5. The process as claimed in claim 2 , wherein said at least one organic polar solvent is selected from the group consisting of alcohols having from 1 to 8 carbon atoms, ketones having from 3 to 8 carbon atoms, and combinations thereof.

6. The process as claimed in claim 3 , wherein said at least one organic polar solvent is selected from the group consisting of alcohols having from 1 to 8 carbon atoms, ketones having from 3 to 8 carbon atoms, and combinations thereof.

7. The process as claimed in claim 1 , wherein the amount of acetone extractables in the resultant dried natural rubber is 2% by weight or less.

8. The process as claimed in claim 2 , wherein the amount of acetone extractables in the resultant dried natural rubber is 2% by weight or less.

9. The process as claimed in claim 3 , wherein the amount of acetone extractables in the resultant dried natural rubber is 2% by weight or less.

10. The process as claimed in claim 1 , wherein the at least one organic polar solvent comprises acetone.

11. A process for recovering rubber from an aqueous guayule natural rubber latex that contains guayule natural rubber, water, non-rubber extractables including resin, and one or more additives, and is essentially free of lignocellulosic plant material, comprising the steps of:
freezing the latex, whereby at least 75% of the guayule natural rubber coagulates and a mixture containing coagulated guayule natural rubber, water, and extractables is formed;
thawing the mixture;
collecting the coagulated guayule natural rubber;
contacting the coagulated guayule natural rubber with an extraction solution comprising at least one organic polar solvent in order to preferentially solvate the extractables; and
drying the coagulated guayule natural rubber to create a resultant natural rubber wherein the resultant guayule natural rubber has an amount of acetone extractables of 5% by weight or less.

12. The process as claimed in claim 11 , further comprising, prior to freezing the latex, the step of adding carbon black to the latex in an amount between 0 .5% and 6% by weight of the resultant dried natural rubber.

13. The process as claimed in claim 11 , further comprising, prior to contacting the coagulated natural rubber with the extraction solution, the step of adding carbon black to the coagulated natural rubber in an amount between 0.5% and 6% by weight of the resultant dried natural rubber.

14. The process as claimed in claim 11 , wherein said at least one organic polar solvent is selected from the group consisting of alcohols having from 1 to 8 carbon atoms, ketones having from 3 to 8 carbon atoms, and combinations thereof.

15. The process as claimed in claim 11 , wherein the amount of acetone extractables in the resultant dried natural rubber is 2% by weight or less.

16. The process as claimed in claim 11 , wherein the at least one organic polar solvent comprises acetone.

17. A process for recovering rubber from an aqueous guayule natural rubber latex that contains guayule natural rubber, water, non-rubber extractables including resin, and one or more additives, and is essentially free of lignocellulosic plant material, comprising the steps of:
freezing the latex, whereby at least 75% of the guayule natural rubber coagulates and a mixture containing coagulated guayule natural rubber, water, and extractables is formed;
thawing the mixture;
collecting the coagulated guayule natural rubber;
contacting the coagulated guayule natural rubber with an extraction solution comprising at least one organic polar solvent in order to preferentially solvate the extractables; and
drying the coagulated guayule natural rubber to create a resultant natural rubber wherein the resultant guayule natural rubber has an amount of acetone extractables of 2% by weight or less.

18. The process as claimed in claim 17 , further comprising, prior to freezing the latex, the step of adding carbon black to the latex in an amount between about 0.5% and about 6% by weight of the resultant dried natural rubber.

19. The process as claimed in claim 17 , further comprising, prior to contacting the coagulated natural rubber with the extraction solution, the step of adding carbon black to the coagulated natural rubber in an amount between about 0.5% and about 6% by weight of the resultant dried natural rubber.

20. The process as claimed in claim 17 , wherein said at least one organic polar solvent is selected from the group consisting of alcohols having from 1 to 8 carbon atoms, ketones having from 3 to 8 carbon atoms, and combinations thereof.

Assignees

• Bridgestone Corp

Inventors

• Cole William M
• Bohm Georg G A
• Tomaszewski Walter
• Huang Yingyi

Classifications

• C08C3/00

  Treatment of coagulated rubber · CPC title

• C08C1/02

  Chemical or physical treatment of rubber latex before or during concentration · CPC title

• C08C1/04 Primary

  Purifying; Deproteinising · CPC title

• C08C1/14

  Coagulation · CPC title

• C08C3/02

  Purification · CPC title