Calcium carbonate microparticles and processes for preparing them

Patent metadata

Field	Value
Publication number	US-10112844-B2
Application number	US-201515300465-A
Country	US
Kind code	B2
Filing date	Mar 31, 2015
Priority date	Mar 31, 2014
Publication date	Oct 30, 2018
Grant date	Oct 30, 2018

Abstract

The present invention aims to provide techniques for efficiently preparing calcium carbonate particles having an average primary particle size of less than 1 μm. Calcium carbonate microparticles having an average primary particle size of less than 1 μm can be synthesized efficiently by synthesizing calcium carbonate in the presence of cavitation bubbles.

First claim

The invention claimed is:

1. A process for preparing calcium carbonate particles having an average primary particle size of less than 1 μm, comprising synthesizing calcium carbonate while injecting under pressure a liquid into a reaction solution in a reaction vessel, wherein the pressure in the vessel is from 0.05 MPa to 0.9 MPa.

2. The process of claim 1 , comprising reacting an aqueous suspension of slaked lime and a gas containing carbon dioxide.

3. The process of claim 1 , comprising generating cavitation bubbles by injecting a liquid into a reaction vessel and synthesizing calcium carbonate in the presence of the cavitation bubbles.

4. The process of claim 3 , wherein the cavitation bubbles are generated by injecting an aqueous suspension of slaked lime into a reaction vessel.

5. The process of claim 2 , wherein the reaction solution is circulated from the reaction vessel.

6. The process of claim 1 , further comprising modifying the calcium carbonate particles.

7. A calcium carbonate having an average primary particle size of less than 1 μm prepared by the process of claim 1 .

8. A product comprising the calcium carbonate particles of claim 7 .

9. The product of claim 8 , which is a sheet containing the calcium carbonate particles as an internal filler.

10. A coating color comprising the calcium carbonate particles of claim 7 .

11. The product of claim 8 , which is a kneaded resin obtained by kneading the calcium carbonate particles with a resin.

12. The process of claim 1 , wherein the pressure of the injecting liquid is from 2 MPa to 15 MPa.

13. The process of claim 1 , wherein the ratio between the pressure in the vessel and the pressure of the injecting liquid is from 0.001 to 0.5.

Assignees

• Jujo Paper Co Ltd

Inventors

• Fukuoka Moe
• Nakatani Toru
• Goto Shisei

Classifications

• B01J19/008

  Processes for carrying out reactions under cavitation conditions · CPC title

• C01P2004/03

  obtained by SEM · CPC title

• C01P2004/62

  Submicrometer sized, i.e. from 0.1-1 micrometer · CPC title

• D21H19/385

  Oxides, hydroxides or carbonates · CPC title

• C08L23/12

  Polypropene · CPC title