Method for forming a subsequently drying a composite comprising a nanofibrillated polysaccharide

Patent metadata

Field	Value
Publication number	US-9562328-B2
Application number	US-201314441268-A
Country	US
Kind code	B2
Filing date	Nov 6, 2013
Priority date	Nov 9, 2012
Publication date	Feb 7, 2017
Grant date	Feb 7, 2017

Abstract

A method for the production of a composite material comprising nanofibrillated polysaccharide, the method comprising the following steps:
(i) providing a liquid suspension of the nanofibrillated polysaccharide; (ii) bringing said liquid suspension in contact with at least one additive, thereby forming a composite material suspension, wherein the composite comprises the nanofibrillated polysaccharide and the at least one additive, (iii) increasing the solid contents of said composite material suspension, thereby forming a high solid contents composite material suspension.

First claim

The invention claimed is:

1. A method for the production of a composite material comprising any one of a microfibrillated cellulose and a nanofibrillated cellulose, the method comprising the following steps:
(i) providing a liquid suspension of the microfibrillated or nanofibrillated cellulose; wherein the solids content of the microfibrillated or nanofibrillated cellulose is over 2%,
(ii) bringing said liquid suspension in contact with two or more additives, wherein said additives are allowed to react with each other, wherein said additives are calcium carbonate or precursors thereof, thereby forming a composite material suspension, wherein the composite comprises the microfibrillated or nanofibrillated cellulose and the calcium carbonate or the precursors thereof, and wherein said calcium carbonate is formed or precipitated onto fibers or fibrils of the microfibrillated or nanofibrillated cellulose;
(iii) increasing the solid contents of said composite material suspension, thereby forming a high solid contents composite material suspension;
(iv) drying said high solid contents composite material suspension, through a simultaneous heating and mixing operation, whereby a substantially dry composite product is formed.

2. The method as claimed in claim 1 , wherein in step (i) the solids content of the microfibrillated or nanofibrillated cellulose is higher than 4 wt-%.

3. The method as claimed in claim 2 , wherein in step (ii) of bringing said liquid suspension in contact with at least one additive, thereby forming a composite material suspension, the ratio between the microfibrillated or nanofibrillated cellulose and the at least one additive is greater than 1:1.

4. The method as claimed in claim 2 , wherein in step (ii) of bringing said liquid suspension in contact with at least one additive, thereby forming a composite material suspension, the ratio between the microfibrillated or nanofibrillated cellulose and the at least one additive is greater than 3:1.

5. The method as claimed in claim 2 , wherein in step (ii) of bringing said liquid suspension in contact with at least one additive, thereby forming a composite material suspension, the ratio between the microfibrillated or nanofibrillated cellulose and the at least one additive is greater than 6:1.

6. The method as claimed in claim 1 , wherein the additive is provided by an in-line production method, wherein the additive or additives are provided into the liquid flow of a paper machine by feeding said additive simultaneously as said aqueous suspension of microfibrillated or nanofibrillated cellulose, thereby forming a composite material suspension in the liquid flow of the paper machine.

7. The method according to claim 1 , wherein the additives are carbon dioxide and lime milk.

8. The method for drying as claimed in claim 1 , wherein in step (iii), the solid contents of the composite material is increased to >20% by weight.

9. The method as claimed in claim 1 , wherein at/in step (iv) the temperature of the composite material is in the range of 75-99° C.

10. The method as claimed in claim 9 , wherein at step (iv) the composite material is heated from about room temperature to the range of 75-99° C.

11. The method of drying as claimed in claim 1 , where step (iv) is performed under vacuum.

12. The method as claimed in claim 1 , wherein in step (iv) there is further provided a drying additive.

13. The method for drying as claimed in claim 1 , wherein in step (iii), the solid contents of the composite material is increased to >25% by weight.

14. The method for drying as claimed in claim 1 , wherein in step (iii), the solid contents of the composite material is increased to >30% by weight.

15. The method as claimed in claim 1 , wherein at/in step (iv) the temperature of the composite material is about 85° C.

Assignees

• Stora Enso Oyj

Inventors

• Axrup Lars
• Saxell Heidi
• Jokela Veikko
• Kastinen Henri
• Kauppi Anna
• Backfolk Kaj
• Ruohoniemi Nina
• Laitinen Risto
• Heiskanen Isto
• Laukala Teija

Classifications

• D21C9/007

  by mechanical or physical means · CPC title

• C08L1/04

  Oxycellulose; Hydrocellulose {, e.g. microcrystalline cellulose} · CPC title

• C08B15/02 Primary

  Oxycellulose; Hydrocellulose; {Cellulosehydrate, e.g. microcrystalline cellulose} · CPC title

• D21H17/24

  Polysaccharides · CPC title

• D21H11/18 Primary

  Highly hydrated, swollen or fibrillatable fibres · CPC title