Agglomerated boron nitride particles, production method for agglomerated boron nitride particles, resin composition including agglomerated boron nitride particles, moulded body, and sheet

Patent metadata

Field	Value
Publication number	US-10106413-B2
Application number	US-201615229619-A
Country	US
Kind code	B2
Filing date	Aug 5, 2016
Priority date	Feb 5, 2014
Publication date	Oct 23, 2018
Grant date	Oct 23, 2018

Abstract

The present invention addresses the problem of providing agglomerated boron nitride particles which are suitable to be used as a thermally conductive filler for a heat dissipation sheet of a power semiconductor device, and which exhibit excellent isotropy of thermal conductivity, excellent degradation resistance, and excellent kneadability with respect to resin.
The agglomerated boron nitride particles are obtained by agglomerating boron nitride primary particles. The agglomerated BN articles are characterized in that: a peak area intensity ratio ((100)/(004)) of a (100) plane to a (004) plane of the BN primary particles is 0.25 or more, and the average crystallite size of the BN primary particles obtained from a (002) plane peak of the BN primary particles is 375 Å or more.

First claim

The invention claimed is:

1. An agglomerated boron nitride particle (hereinafter referred to as “agglomerated BN particle”) constituted by boron nitride primary particles (hereinafter referred to as “BN primary particles”), wherein a peak area intensity ratio ((100)/(004)) of a (100) plane to a (004) plane of the BN primary particles is 0.25 or more, the peak intensity ratio being obtained by subjecting, to a powder X-ray diffraction measurement, a pellet-shaped sample moulded at a moulding pressure of 0.85 ton/cm 2 using a 10 mmφ powder pellet moulding machine, the average crystallite size of the BN primary particles obtained from a (002) plane peak of the BN primary particles is 375 Å or more, the average crystallite size being obtained as a result of filling a glass sample plate having a depth of 0.2 mm with the agglomerated BN particles in such a way that the sample surface becomes smooth, and subjecting the agglomerated BN particles to a powder X-ray diffraction measurement, and a specific surface area of the agglomerated BN particle is 8 m 2 /g or less.

2. The agglomerated BN particle according to claim 1 , wherein an average particle diameter D 50 of the agglomerated BN particle is 26 μm or more.

3. The agglomerated BN particle according to claim 1 , wherein the agglomerated BN particle is spherical.

4. The agglomerated BN particle according to claim 1 , wherein the agglomerated BN particle has a card-house structure.

5. A composition of the agglomerated BN particle which is a mixture of the agglomerated BN particle according to claim 1 and filler.

6. A resin composition comprising agglomerated BN particle, comprising resin and the agglomerated BN particles according to claim 1 .

7. A moulded body comprising the agglomerated BN particle according to claim 1 .

8. A method of producing the agglomerated BN particle according to claim 1 , comprising:
granulating slurry of raw material boron nitride powder (hereinafter referred to as “BN slurry”); and
performing heating treatment, wherein in the granulating, a viscosity of the BN slurry is 200 mPa·s or more and 5000 mPa·s or less, and the heating treatment is performed at 1800° C. or more and 2300° C. or less.

9. The method according to claim 8 , wherein an oxygen concentration in the raw material boron nitride powder is 1% by mass or more and 10% by mass or less.

10. A sheet comprising agglomerated boron nitride particles (hereinafter referred to as “agglomerated BN particles”),
wherein a peak intensity ratio ((100)/(004)) of a (100) plane to a (004) plane of boron nitride primary particles (hereinafter referred to as “BN primary particles”) in the sheet obtained by subjecting the sheet to an X-ray diffraction measurement is 1.0 or more,
an average crystallite size of the BN primary particles obtained from a (002) plane peak of the BN primary particles in the sheet obtained by subjecting the sheet to an X-ray diffraction measurement is 375 Å or more, and a specific surface area of the agglomerated BN particle is 8 m 2 /g or less.

11. The sheet according to claim 10 , wherein the peak area intensity ratio ((100)/(004)) of the (100) plane to the (004) plane of the boron nitride primary particles (hereinafter referred to as “BN primary particles”) in the sheet obtained by subjecting the sheet to an X-ray diffraction measurement is 0.6 or more.

12. A device comprising the sheet according to claim 10 as a part of a member of the device.

Assignees

• Mitsubishi Chem Corp

Inventors

• Ikemiya Katsura
• Yamazaki Masanori
• Suzuki Takuya
• Takeda Kazuki
• Sawamura Toshiyuki
• Hiramatsu Sawa
• Isojima Tatsushi

Classifications

• C01P2004/04

  obtained by TEM, STEM, STM or AFM · CPC title

• C08L101/00

  Compositions of unspecified macromolecular compounds · CPC title

• C09K5/14

  Solid materials, e.g. powdery or granular · CPC title

• C08K3/38

  Boron-containing compounds · CPC title

• C01P2002/72

  by d-values or two theta-values, e.g. as X-ray diagram · CPC title