Butadiene sequestration via sulfur dioxide charged zeolite beds

Patent metadata

Field	Value
Publication number	US-10105646-B2
Application number	US-201715835209-A
Country	US
Kind code	B2
Filing date	Dec 7, 2017
Priority date	Jun 24, 2015
Publication date	Oct 23, 2018
Grant date	Oct 23, 2018

Abstract

In an example, a method of butadiene sequestration includes receiving an input stream that includes butadiene. The method includes directing the input stream to a first sulfur dioxide charged zeolite bed for butadiene sequestration via a first chemical reaction of butadiene and sulfur dioxide to form sulfolene.

First claim

The invention claimed is:

1. A method of controlling a butadiene sequestration process, the method comprising:
receiving, at a control device, an indication from a butadiene detector that butadiene detected in an output stream exceeds a butadiene threshold;
sending a first valve positioning signal from the control device to a first valve to redirect an input stream that includes butadiene to a first zeolite bed charged with sulfur dioxide; and
forming sulfolene from the butadiene and the sulfur dioxide by a first chemical reaction.

2. The method of claim 1 , further comprising:
sending a second valve positioning signal from the control device to a second valve to provide a first fluid path for removing sulfolene from the first zeolite bed; and
sending a third valve positioning signal from the control device to a third valve to provide a second fluid path for providing additional sulfur dioxide to a second zeolite bed charged with sulfur dioxide.

3. The method of claim 2 , further comprising forming the additional sulfur dioxide by a second chemical reaction that forms butadiene and sulfur dioxide from the sulfolene that is removed from the first zeolite bed.

4. The method of claim 2 , further comprising:
recovering sulfolene by scrubbing one or more of the first and second zeolite beds; and
performing recharging of one or more of the first and second zeolite beds using sulfur dioxide.

5. The method of claim 4 , wherein at least a portion of the sulfur dioxide used for recharging is formed from thermal processing of the sulfolene that is recovered from one or more of the first and second zeolite beds.

6. The method of claim 1 , wherein the first zeolite bed includes a plurality of sulfur dioxide molecules at a plurality of zeolite bed pore locations.

7. The method of claim 1 , further comprising performing a first set of operations to remove the sulfolene from the first zeolite bed in response to determining that the butadiene detected in the output stream exceeds the butadiene threshold, wherein the first set of operations comprises performing a second chemical reaction to form butadiene and sulfur dioxide from the sulfolene that is formed via the first chemical reaction.

8. The method of claim 7 , wherein the first set of operations includes utilizing one or more solvents to remove the sulfolene from the first zeolite bed.

9. The method of claim 7 , further comprising performing a second set of operations to provide additional sulfur dioxide to the first zeolite bed in response to determining that butadiene detected in the output stream exceeds the butadiene threshold wherein the second set of operations comprises providing the sulfur dioxide that is formed in the second chemical reaction as the additional sulfur dioxide.

10. A method of controlling a butadiene sequestration process, the method comprising:
receiving, at a control device, an indication from a butadiene detector that butadiene detected in an output stream exceeds a butadiene threshold;
sending a first valve positioning signal from the control device to a first valve to redirect an input stream that includes butadiene to a first zeolite bed charged with sulfur dioxide;
forming sulfolene from the butadiene and the sulfur dioxide by a first chemical reaction;
sending a second valve positioning signal from the control device to a second valve to provide a first fluid path for removing sulfolene from the first zeolite bed; and
sending a third valve positioning signal from the control device to a third valve to provide a second fluid path for providing additional sulfur dioxide to a second zeolite bed charged with sulfur dioxide.

11. The method of claim 10 , wherein the additional sulfur dioxide is formed via a second chemical reaction to form butadiene and sulfur dioxide from the sulfolene that is removed from the first zeolite bed.

12. The method of claim 10 , further comprising:
recovering sulfolene by scrubbing one or more of the first and second zeolite beds; and
performing recharging of one or more of the first and second zeolite beds using sulfur dioxide.

13. The method of claim 12 , wherein at least a portion of the sulfur dioxide used for recharging is formed from thermal processing of the sulfolene that is recovered from one or more of the first and second zeolite beds.

14. The method of claim 10 , wherein the first zeolite bed includes a plurality of sulfur dioxide molecules at a plurality of zeolite bed pore locations.

15. The method of claim 10 , further comprising performing a first set of operations to remove the sulfolene in response to determining that the butadiene detected in the output stream exceeds the butadiene threshold, wherein the first set of operations comprises performing a second chemical reaction to form butadiene and sulfur dioxide from the sulfolene that is formed via the first chemical reaction.

16. The method of claim 15 , wherein the first set of operations includes utilizing one or more solvents to remove the sulfolene from the first zeolite bed.

17. The method of claim 15 , further comprising performing a second set of operations to provide additional sulfur dioxide to the first zeolite bed in response to determining that butadiene detected in the output stream exceeds the butadiene threshold wherein the second set of operations comprises providing the sulfur dioxide that is formed in the second chemical reaction as the additional sulfur dioxide.

18. A method of controlling a butadiene sequestration process, the method comprising:
receiving, at a control device, an indication from a butadiene detector that butadiene detected in an output stream exceeds a butadiene threshold;
receiving, at a control device, an indication from a butadiene detector that butadiene detected in an output stream exceeds a butadiene threshold;
sending a first valve positioning signal from the control device to a first valve to redirect an input stream that includes butadiene to a first zeolite bed charged with sulfur dioxide;
forming sulfolene from the butadiene and the sulfur dioxide by a first chemical reaction;
sending a second valve positioning signal from the control device to a second valve to provide a first fluid path for removing sulfolene from the first zeolite bed;
sending a third valve positioning signal from the control device to a third valve to provide a second fluid path for providing additional sulfur dioxide to a second zeolite bed charged with sulfur dioxide;
recovering sulfolene by scrubbing one or more of the first and second zeolite beds; and
performing recharging of one or more of the first and second zeolite beds using sulfur dioxide.

Assignees

• IBM

Inventors

• Boday Dylan J
• Kuczynski Joseph
• Mauldin Timothy C

Classifications

• C07C7/17

  with acids or sulfur oxides · CPC title

• B01D53/76

  Gas phase processes, e.g. by using aerosols · CPC title

• B01D2259/40088

  by heating · CPC title

• B01D53/44 Primary

  Organic components · CPC title

• B01D53/346

  Controlling the process · CPC title