Butadiene sequestration via sulfur dioxide charged zeolite beds

Patent metadata

Field	Value
Publication number	US-9566548-B2
Application number	US-201514748742-A
Country	US
Kind code	B2
Filing date	Jun 24, 2015
Priority date	Jun 24, 2015
Publication date	Feb 14, 2017
Grant date	Feb 14, 2017

Abstract

In an example, a method of butadiene sequestration includes receiving an input stream that includes butadiene. The method includes directing the input stream to a first sulfur dioxide charged zeolite bed for butadiene sequestration via a first chemical reaction of butadiene and sulfur dioxide to form sulfolene.

First claim

The invention claimed is:

1. A butadiene sequestration system comprising:
a first fluid interface to receive an input stream that includes butadiene;
a first sulfur dioxide charged zeolite bed to sequester butadiene from the input stream via a chemical reaction of butadiene and sulfur dioxide to form sulfolene; and
a second fluid interface to provide an output stream from the first sulfur dioxide charged zeolite bed.

2. The butadiene sequestration system of claim 1 , further comprising a second sulfur dioxide charged zeolite bed to sequester butadiene from the input stream via a chemical reaction of the butadiene and sulfur dioxide to form sulfolene.

3. The butadiene sequestration system of claim 2 , further comprising:
a butadiene detector to monitor butadiene in the output stream;
a control device communicatively coupled to the butadiene detector, wherein the control device is configured to send a valve positioning signal to a valve responsive to a determination that butadiene detected in the output stream exceeds a butadiene threshold, and wherein the valve is configured to direct the input stream to the second sulfur dioxide charged zeolite bed for butadiene sequestration responsive to receiving the valve positioning signal.

4. The butadiene sequestration system of claim 3 , wherein the control device includes a programmable logic controller (PLC) device, and wherein the valve positioning signal includes instructions to close a first fluid path to the first sulfur dioxide charged zeolite bed and to open a second fluid path to the second sulfur dioxide charged zeolite bed.

5. The butadiene sequestration system of claim 1 , further comprising:
a second fluid interface for removal of the sulfolene from the first sulfur dioxide charged zeolite bed; and
a third fluid interface for providing additional sulfur dioxide to the first sulfur dioxide charged zeolite bed for butadiene sequestration.

Assignees

• IBM

Inventors

• Boday Dylan J
• Kuczynski Joseph
• Mauldin Timothy C

Classifications

• C07D333/48 Primary

  by oxygen atoms · CPC title

• B01D2257/7022

  Aliphatic hydrocarbons · CPC title

• C07C1/322

  the hetero-atom being a sulfur atom · CPC title

• B01J19/24

  Stationary reactors without moving elements inside (B01J19/08, B01J19/26 take precedence; with stationary particles B01J8/02) · CPC title

• B01D53/44 Primary

  Organic components · CPC title