Method of manufacturing hexagonal ferrite powder, hexagonal ferrite powder, and magnetic recording medium

Patent metadata

Field	Value
Publication number	US-10102874-B2
Application number	US-201514671125-A
Country	US
Kind code	B2
Filing date	Mar 27, 2015
Priority date	Mar 28, 2014
Publication date	Oct 16, 2018
Grant date	Oct 16, 2018

Abstract

An aspect of the present invention relates to A method of manufacturing hexagonal ferrite powder, which comprises heating to equal to or higher than 300° C. and pressurizing to equal to or higher than 20 MPa a hexagonal ferrite precursor-containing water-based solution, to convert the precursor to hexagonal ferrite, wherein the water-based solution comprises at least a reducing compound selected from the group consisting of a reducing inorganic compound and a reducing organic compound that have a reducing property and exist as a solid or a liquid at ordinary temperature and ordinary pressure, as well as, when the reducing compound is a reducing inorganic compound, the water-based solution further comprises an organic compound.

First claim

What is claimed is:

1. A method of manufacturing hexagonal ferrite powder, which comprises:
preparing a hexagonal ferrite precursor-containing water-based solution by:
mixing an iron salt, a divalent metal salt, a reducing compound, and a base in a water-based solvent, wherein the reducing compound is selected from the group consisting of a reducing inorganic compound and a reducing organic compound that have a reducing property and exist as a solid or a liquid at ordinary temperature and ordinary pressure to prepare a first solution,
mixing the first solution and a second solution which contains an organic compound other than the reducing organic compound; and
heating to equal to or higher than 300° C. and pressurizing to equal to or higher than 20 MPa the hexagonal ferrite precursor-containing water-based solution, to convert the precursor to hexagonal ferrite.

2. The method of manufacturing hexagonal ferrite powder according to claim 1 , wherein, in the mixing, the reducing compound is mixed in an amount ranging from 2 mole parts to 300 mole parts per 100 mole parts of a combined amount of the iron salt and the divalent metal salt.

3. The method of manufacturing hexagonal ferrite powder according to claim 1 , wherein the reducing compound comprises at least a reducing organic compound that has a reducing property and exists as a solid or a liquid at ordinary temperature and ordinary pressure.

4. The method of manufacturing hexagonal ferrite powder according to claim 1 , wherein the reducing compound comprises at least a reducing inorganic compound that has a reducing property and exists as a solid or a liquid at ordinary temperature and ordinary pressure.

5. The method of manufacturing hexagonal ferrite powder according to claim 1 , wherein the reducing compound comprises at least a hydrazine compound.

6. The method of manufacturing hexagonal ferrite powder according to claim 5 , wherein the hydrazine compound is hydrazine.

7. The method of manufacturing hexagonal ferrite powder according to claim 1 , wherein the reducing compound comprises at least an amine compound.

8. The method of manufacturing hexagonal ferrite powder according to claim 7 , wherein the amine compound is triethylamine.

9. The method of manufacturing hexagonal ferrite powder according to claim 7 , wherein the amine compound is triethanolamine.

10. The method of manufacturing hexagonal ferrite powder according to claim 1 , wherein the organic compound is selected from the group consisting of an organic carboxylic acid and a salt thereof.

11. The method of manufacturing hexagonal ferrite powder according to claim 1 , wherein a flow passage continuously feeding the precursor solution and a flow passage continuously feeding the organic compound solution are converged to mix the precursor solution and organic compound solution.

12. The method of manufacturing hexagonal ferrite powder according to claim 1 , wherein a mixed solution of the precursor solution and organic compound solution is mixed with water that has been heated and pressurized, and then fed to a reaction flow passage within which a fluid flowing therein is subjected to heating to equal to or higher than 300° C. and pressurizing to equal to or higher than 20 MPa to convert the precursor to hexagonal ferrite.

13. The method of manufacturing hexagonal ferrite powder according to claim 12 , wherein the flow passage within which the mixed solution is being continuously fed and a flow passage within which heated and pressurized water is being continuously fed are converged to mix the mixed solution with heated and pressurized water.

14. The method of manufacturing hexagonal ferrite powder according to claim 1 , wherein the hexagonal ferrite that is obtained by the conversion of the precursor is selected from the group consisting of barium ferrite, strontium ferrite, and a mixed crystal thereof.

Assignees

• Fujifilm Corp

Inventors

• Shirata Masashi

Classifications

• C01P2004/64

  Nanometer sized, i.e. from 1-100 nanometer · CPC title

• G11B5/70678 Primary

  Ferrites · CPC title

• H01F1/11

  in the form of particles {(for magnetic record carriers G11B5/70626)} · CPC title

• C01G49/0036

  containing one alkaline earth metal, magnesium or lead · CPC title

• C01G49/0018

  Mixed oxides or hydroxides, (C01G49/0009 takes precedence) · CPC title