Measuring total organic carbon of shales using thermal expansion

Patent metadata

Field	Value
Publication number	US-10101494-B2
Application number	US-201615159425-A
Country	US
Kind code	B2
Filing date	May 19, 2016
Priority date	May 19, 2016
Publication date	Oct 16, 2018
Grant date	Oct 16, 2018

Abstract

A tool having an energy source and a surface roughness measurement device is provided. A baseline measurement of surface roughness of a sample is made. The sample is then exposed to energy from the energy source, causing the temperature of the sample to increase. A second measurement of surface roughness of the sample is made. The change in surface roughness of the sample is determined. Formation properties such as the total organic carbon in the sample is inferred based on the determined change in surface roughness of the sample. The tool may be disposed in a wellbore and may use packers to isolate a portion of the wellbore, or it may use a hydraulic seal on an extendible member to isolate a sample portion of the wellbore wall. The energy source may be a laser that produces radiation that selectively heats a particular component of the sample constituent material.

First claim

What is claimed is:

1. A method, comprising:
providing an energy source and a surface roughness measurement device;
making a baseline measurement of surface roughness of a sample using the surface roughness measurement device;
exposing the sample to energy from the energy source, thereby causing a temperature of at least a portion of the sample to change;
making a second measurement of surface roughness of the sample using the surface roughness measurement device;
determining a change in surface roughness of the sample using the baseline measurement and the second measurement; and
inferring a total organic carbon in the sample based on the determined change in surface roughness of the sample.

2. The method of claim 1 , wherein the energy source is selected from a group consisting of: a laser and an oven.

3. The method of claim 1 , wherein the surface roughness measurement device is selected from a group consisting of: a stylus device, an optical device, and a scanning microscopy device.

4. The method of claim 1 , wherein the sample is exposed to the energy uniformly or selectively.

5. The method of claim 1 , wherein the energy source is a laser that produces radiation that is readily absorbed by one constituent component comprising the sample but not readily absorbed by any other constituent component comprising the sample.

6. The method of claim 1 , wherein the sample is a shale comprising background minerals and organic patches.

7. The method of claim 6 , wherein, as the sample is exposed to the energy, the organic patches thermally expand more than the background minerals.

8. The method of claim 1 , wherein the sample is in situ in a wellbore, and further comprising isolating the sample from drilling fluid and/or wellbore fluid.

9. The method of claim 8 , wherein the isolating the sample comprises using packers disposed in the wellbore or using a hydraulic seal to enclose the sample.

10. The method of claim 1 , wherein the making a measurement comprises scanning the sample to produce a plurality of surface profiles.

11. The method of claim 10 , further comprising integrating substantially equal height profile components and comparing the obtained integrated value to a corresponding total surface area of the sample.

12. An apparatus, comprising:
a tool body on which an energy source and a surface roughness measurement device are carried, the tool body being disposed in a wellbore, and wherein the energy source is capable of delivering energy to a sample, and at least the surface roughness measurement device is carried on an extendible arm of the tool body; and
a sealing mechanism disposed in the wellbore and isolating a section of the wellbore, wherein at least the surface roughness measurement device and the sample are located within the isolated section of the wellbore.

13. The apparatus of claim 12 , wherein the energy source is selected from a group consisting of: a laser and an oven.

14. The apparatus of claim 12 , wherein the surface roughness measurement device is selected from a group consisting of: a stylus device, an optical device, and a scanning microscopy device.

15. The apparatus of claim 12 , wherein the sealing mechanism is selected from the group consisting of: a pair of packers and a sealing ring.

16. The apparatus of claim 12 , wherein the sealing mechanism is a pair of packers wherein one packer is sealingly engaged to a wellbore wall above the sample and the other packer is sealingly engaged to the wellbore wall below the sample.

17. The apparatus of claim 12 , wherein the sealing mechanism is a sealing ring and the sealing ring is brought into sealing engagement with a wellbore wall by the extendible arm.

18. The apparatus of claim 12 , wherein the energy source is a laser that produces radiation that is readily absorbed by one constituent component comprising the sample but not readily absorbed by any other constituent component comprising the sample.

19. The apparatus of claim 12 , wherein the sample is a shale comprising background minerals and organic patches.

20. The apparatus of claim 19 , wherein, as the sample is exposed to the energy, the organic patches thermally expand more than the background minerals.

21. A method, comprising:
providing a downhole tool that comprises an energy source and a surface roughness measurement device, and disposing the downhole tool in a wellbore that penetrates a formation;
bringing an extendible portion of the downhole tool into sealing engagement with a wall of the wellbore;
evacuating fluid within an interior region enclosed by the extendible portion of the downhole tool and the wellbore wall;
making a baseline measurement of surface roughness of a sample portion of the wellbore wall enclosing the interior region using the surface roughness measurement device;
exposing the sample portion of the wellbore wall to energy from the energy source to cause uneven thermal expansion of constituent components of the sample portion of the wellbore wall;
making a second measurement of surface roughness of the sample portion of the wellbore wall using the surface roughness measurement device;
determining a change in surface roughness of the sample portion of the wellbore wall using the baseline measurement and the second measurement; and
inferring one or more formation properties based on the determined change in surface roughness of the sample portion of the wellbore wall.

22. The method of claim 21 , wherein the extendible portion is selected from the group consisting of: a pair of packers and a sealing ring carried on a moveable member.

23. The method of claim 21 , wherein the inferring comprises comparing a total elevated area to a corresponding total surface area.

Assignees

• Schlumberger Technology Corp

Inventors

• Badri Mohammed
• Taherian Reza

Classifications

• E21B49/00 Primary

  Testing the nature of borehole walls; Formation testing; Methods or apparatus for obtaining samples of soil or well fluids, specially adapted to earth drilling or wells · CPC title

• G01N25/16

  by investigating thermal coefficient of expansion · CPC title

• E21B25/00

  Apparatus for obtaining or removing undisturbed cores, e.g. core barrels or core extractors (core bits E21B10/02) · CPC title

• G01V9/005 Primary

  by thermal methods, e.g. after generation of heat by chemical reactions · CPC title

• E21B33/12

  Packers; Plugs (used for cementing E21B33/134, E21B33/16) · CPC title