Oxidation electrode and photoelectrochemical device

Patent metadata

Field	Value
Publication number	US-10100418-B2
Application number	US-201615261446-A
Country	US
Kind code	B2
Filing date	Sep 9, 2016
Priority date	Mar 14, 2014
Publication date	Oct 16, 2018
Grant date	Oct 16, 2018

Abstract

According to one embodiment, an oxidation electrode includes: a collector; an oxidation catalyst formed on the collector; and a modified organic molecule which is bonded to the surface of the oxidation catalyst, and comprises a cationic functional group.

First claim

What is claimed is:

1. An oxidation electrode comprising:
a collector;
an oxidation catalyst formed on the collector; and
an organic molecule which is chemically bonded to the surface of the oxidation catalyst, and comprises a cationic functional group.

2. The electrode of claim 1 , wherein the cationic functional group comprises a quaternary nitrogen cation.

3. The electrode of claim 2 , wherein the quaternary nitrogen cation comprises at least one of ammonium cations, imidazole cations, pyridinium cations, piperidinium cations, and pyrrolidinium cations.

4. The electrode of claim 1 , wherein the modified organic molecule further comprises at least one of alkyl groups having 1 to 20 carbon atoms.

5. The electrode of claim 1 , wherein the modified organic molecule further comprises an anionic functional group having hydrophilicity.

6. The electrode of claim 5 , wherein the anionic functional group comprises at least one of tetrafluoroborate anions, dicyanamide anions, hydrogen carbonate anions, nitrate anions, borate anions, sulfate anions, phosphate anions, perchlorate anions, and halogen anions.

7. The electrode of claim 1 , wherein the modified organic molecule further comprises a reactive functional group binding the cationic functional group and the oxidation catalyst.

8. The electrode of claim 7 , wherein the reactive functional group comprises at least one of a carboxylate group, a phosphonate group, a halogenated silyl group, and an alkoxysilyl group.

9. The electrode of claim 1 , wherein the oxidation catalyst comprises at least one oxide of manganese, iron, cobalt, nickel, iridium, tin, indium, and ruthenium.

10. The electrode of claim 1 , wherein the collector, oxidation catalyst, and modified organic molecule oxidize water in the electrolytic solution containing an amine or amine cation.

11. A photoelectrochemical device comprising;
a reduction electrode;
an oxidation electrode which comprises a collector, an oxidation catalyst formed on the collector, and an organic molecule chemically bonded to the surface of the oxidation catalyst and containing a cationic functional group; and
a power source element electrically connected to the reduction electrode and oxidation electrode.

12. The device of claim 11 , wherein the power source element includes a semiconductor layer causing charge separation by light energy.

13. The device of claim 12 , wherein the semiconductor layer is formed between the oxidation electrode and reduction electrode.

14. The device of claim 11 , wherein the cationic functional group comprises a quaternary nitrogen cation.

15. The device of claim 14 , wherein the quaternary nitrogen cation comprises at least one of ammonium cations, imidazole cations, pyridinium cations, piperidinium cations, and pyrrolidinium cations.

16. The device of claim 11 , wherein the modified organic molecule further comprises at least one of alkyl groups having 1 to 20 carbon atoms.

17. The device of claim 11 , wherein the modified organic molecule further comprises an anionic functional group having hydrophilicity.

18. The device of claim 17 , wherein the anionic functional group comprises at least one of tetrafluoroborate anions, dicyanamide anions, hydrogen carbonate anions, nitrate anions, borate anions, sulfate anions, phosphate anions, perchlorate anions, and halogen anions.

19. The device of claim 11 , wherein the modified organic molecule comprises a reactive functional group binding the cationic functional group and the oxidation catalyst.

20. The device of claim 19 , wherein the reactive functional group comprises at least one of a carboxylate group, a phosphonate group, a halogenated silyl group, and an alkoxysilyl group.

Assignees

• Toshiba Kk

Inventors

• Tamura Jun
• Mikoshiba Satoshi
• Ono Akihiko
• Kudo Yuki
• Kitagawa Ryota
• Huang Chingchun

Classifications

• C25B1/10

  Chemistry & Metallurgy · mapped topic

• C25B9/08

  Chemistry & Metallurgy · mapped topic

• C25B11/0489 Primary

  Chemistry & Metallurgy · mapped topic

• C25B1/003

  Chemistry & Metallurgy · mapped topic

• C25B3/04

  Chemistry & Metallurgy · mapped topic