Honeycomb structure and method for manufacturing honeycomb structure

Patent metadata

Field	Value
Publication number	US-10094257-B2
Application number	US-201715467087-A
Country	US
Kind code	B2
Filing date	Mar 23, 2017
Priority date	Mar 31, 2016
Publication date	Oct 9, 2018
Grant date	Oct 9, 2018

Abstract

A honeycomb structure includes honeycomb segments each having a porous partition wall defining a plurality of cells, and includes a porous bonding layer containing a crystalline anisotropic ceramic and disposed so as to bond side surfaces of the honeycomb segments to each other. A ratio of a pore volume (cc/g) of a fine pore defined as a pore in the bonding layer having a pore diameter of 10 μm or more and less than 50 μm with respect to a pore volume (cc/g) of a coarse pore defined as a pore in the bonding layer having a pore diameter of 50 μm or more and 300 μm or less is from 2.0 to 3.5, the pore volume of the fine pore is from 0.15 to 0.4 cc/g, and the pore volume of the coarse pore is from 0.05 to 0.25 cc/g.

First claim

What is claimed is:

1. A honeycomb structure comprising:
a plurality of pillar-shaped honeycomb segments each having a porous partition wall defining a plurality of cells that extend from a first end face as one end face to a second end face as the other end face and that serve as a channel of a fluid; and
a porous bonding layer containing a crystalline anisotropic ceramic and disposed so as to bond side surfaces of the plurality of honeycomb segments to each other, wherein
a pore having a pore diameter of 10 μm or more and less than 50 μm in a pore distribution of the bonding layer is defined as a fine pore, and a pore having a pore diameter of 50 μm or more and 300 μm or less in a pore distribution of the bonding layer is defined as a coarse pore,
a ratio of a pore volume (cc/g) of the fine pore with respect to a pore volume (cc/g) of the coarse pore is from 2.0 to 3.5,
the pore volume of the fine pore is from 0.15 to 0.4 cc/g, and
the pore volume of the coarse pore is from 0.05 to 0.25 cc/g.

2. The honeycomb structure according to claim 1 , wherein the bonding layer has a porosity of 65 to 75%.

3. The honeycomb structure according to claim 2 , wherein the crystalline anisotropic ceramic is at least one selected from a group consisting of wollastonite, mica, talc, sepiolite, an alumina fiber, a mullite fiber, a carbon fiber, a silicon carbide fiber, a boron nitride fiber, a potassium titanate fiber, and a zinc oxide fiber.

4. The honeycomb structure according to claim 3 , wherein the bonding layer has a Young's modulus of 100 MPa or less after being heated at 600° C. for 30 minutes, and has a Young's modulus of 120 MPa or less after being heated at 900° C. for 300 minutes.

5. The honeycomb structure according to claim 4 , wherein the bonding layer has a shear strength of 2000 kPa or less after being heated at 900° C. for 300 minutes.

6. A method for manufacturing the honeycomb structure according to claim 5 , comprising:
a honeycomb segments preparation step of preparing a plurality of honeycomb segments each having a porous partition wall defining a plurality of cells that extend from a first end face as one end face to a second end face as the other end face and that serve as a channel of a fluid, by firing honeycomb formed bodies each formed of a kneaded material;
a honeycomb segments with plugging portions preparation step of preparing a plurality of honeycomb segments with plugging portions which are the plurality of honeycomb segments each including plugging portions, by filling end portions of predetermined cells of each of the plurality of honeycomb segments with a plugging slurry; and
a bonded body preparation step of preparing a bonded body by bonding the plurality of honeycomb segments with plugging portions to each other using a bonding slurry, wherein the bonding slurry contains
a crystalline anisotropic ceramic having an aspect ratio of 7 or more, a short diameter of 5 μm or more, and a long diameter of 50 μm or more,
a fine particle pore former having an average particle diameter of 60 μm or less, and
a coarse particle pore former having an average particle diameter of 80 μm or more.

7. The method for manufacturing a honeycomb structure according to claim 6 , wherein a ratio of a long diameter of the crystalline anisotropic ceramic with respect to an average particle diameter of the coarse particle pore former is from 0.7 to 1.3.

8. The method for manufacturing a honeycomb structure according to claim 7 , wherein a content ratio of the crystalline anisotropic ceramic in a solid content of the bonding slurry is from 5 to 40% by mass.

9. The honeycomb structure according to claim 1 , wherein the crystalline anisotropic ceramic is at least one selected from a group consisting of wollastonite, mica, talc, sepiolite, an alumina fiber, a mullite fiber, a carbon fiber, a silicon carbide fiber, a boron nitride fiber, a potassium titanate fiber, and a zinc oxide fiber.

10. The honeycomb structure according to claim 1 , wherein the bonding layer has a Young's modulus of 100 MPa or less after being heated at 600° C. for 30 minutes, and has a Young's modulus of 120 MPa or less after being heated at 900° C. for 300 minutes.

11. The honeycomb structure according to claim 1 , wherein the bonding layer has a shear strength of 2000 kPa or less after being heated at 900° C. for 300 minutes.

12. A method for manufacturing the honeycomb structure according to claim 1 , comprising:
a honeycomb segments preparation step of preparing a plurality of honeycomb segments each having a porous partition wall defining a plurality of cells that extend from a first end face as one end face to a second end face as the other end face and that serve as a channel of a fluid, by firing honeycomb formed bodies each formed of a kneaded material;
a honeycomb segments with plugging portions preparation step of preparing a plurality of honeycomb segments with plugging portions which are the plurality of honeycomb segments each including plugging portions, by filling end portions of predetermined cells of each of the plurality of honeycomb segments with a plugging slurry; and
a bonded body preparation step of preparing a bonded body by bonding the plurality of honeycomb segments with plugging portions to each other using a bonding slurry, wherein the bonding slurry contains
a crystalline anisotropic ceramic having an aspect ratio of 7 or more, a short diameter of 5 μm or more, and a long diameter of 50 μm or more,
a fine particle pore former having an average particle diameter of 60 μm or less, and
a coarse particle pore former having an average particle diameter of 80 μm or more.

13. The method for manufacturing a honeycomb structure according to claim 12 , wherein a ratio of a long diameter of the crystalline anisotropic ceramic with respect to an average particle diameter of the coarse particle pore former is from 0.7 to 1.3.

14. The method for manufacturing a honeycomb structure according to claim 12 , wherein a content ratio of the crystalline anisotropic ceramic in a solid content of the bonding slurry is from 5 to 40% by mass.

Assignees

• Ngk Insulators Ltd

Inventors

• Kimura Keisuke
• Kouno Ryuta
• Ichikawa Shuichi

Classifications

• F01N2330/06

  Ceramic, e.g. monoliths · CPC title

• C04B2237/597

  whereby the interlayer is continuous but porous, e.g. containing hollow or porous particles, macro- or micropores or cracks · CPC title

• F01N2330/04

  Methods of manufacturing · CPC title

• C04B2235/3208

  Calcium oxide or oxide-forming salts thereof, e.g. lime · CPC title

• B01D2265/04

  Permanent measures for connecting different parts of the filter, e.g. welding, glueing or moulding · CPC title