Method and system for purifying synthesis gas, in particular for ammonia synthesis
US-9464246-B2 · Oct 11, 2016 · US
US10093875B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-10093875-B2 |
| Application number | US-201615198341-A |
| Country | US |
| Kind code | B2 |
| Filing date | Jun 30, 2016 |
| Priority date | Apr 14, 2009 |
| Publication date | Oct 9, 2018 |
| Grant date | Oct 9, 2018 |
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A system for producing a syngas from a biomass material. The system compacts a loose biomass material to form a compacted biomass material at an entrance of a reactor tube, and then heats the compacted biomass material within the tube to form ash and a fuel gas mixture. The fuel gas mixture is withdrawn from the tube and the ash is removed from the tube through an exit thereof. Ingress of air into the tube is inhibited by forming a plug of the biomass material at the entrance of the tube and a plug of ash at the exit of the tube. A neutral atmospheric pressure is maintained in the reactor tube relative to pressure outside the reactor tube by monitoring and adjusting a volumetric rate of the fuel gas mixture withdrawn from the reactor tube based on pressures at the entrance and the exit of the reactor tube.
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The invention claimed is: 1. A system for producing syngas from biomass materials, the system comprising: a reactor containing a reactor tube having an internal passage within which a neutral atmospheric pressure exists relative to pressure outside the reactor tube, an entrance to the internal passage, and an exit to the internal passage, the reactor tube and the internal passage thereof being adapted to contain a compacted biomass material moving through the internal passage and to contain a pyrolysis reaction of the compacted biomass material by which a fuel gas mixture comprising carbon monoxide and hydrogen gases is formed therefrom within the reactor tube; means for compacting a loose biomass material and forming therefrom the compacted biomass material at the entrance of the reactor tube; means for heating the compacted biomass material within the reactor tube to a temperature at which the pyrolysis reaction occurs whereby organic molecules within the compacted biomass material break down to form ash and the fuel gas mixture; means for withdrawing the fuel gas mixture from the reactor tube; means for removing the ash from the reactor tube through the exit thereof; means comprising the compacting means, the entrance and the exit of the reactor tube, and the removing means for inhibiting ingress of air into the reactor tube and maintaining the neutral atmospheric pressure within the reactor tube relative to pressure outside the reactor tube by sufficiently compacting the biomass material at the entrance of the reactor tube to form a plug of the compacted biomass material at the entrance, compacting the ash at the exit of the reactor tube to form a plug of the ash at the exit, and monitoring and adjusting a volumetric rate of the fuel gas mixture withdrawn from the reactor tube. 2. A system of producing syngas from biomass materials, the system comprising: means for compacting a loose biomass material and simultaneously introducing the compacted biomass material into an entrance of a reactor tube; means for heating the compacted biomass material within the reactor tube to a temperature at which organic molecules within the compacted biomass material break down to form ash and a fuel gas mixture comprising carbon monoxide and hydrogen gases; means for withdrawing the carbon monoxide and hydrogen gases from the reactor tube; means for removing the ash from the reactor tube through an exit thereof; means for inhibiting ingress of air into the reactor tube by sufficiently compacting the biomass material at the entrance of the reactor tube to form a plug of the compacted biomass material at the entrance and compacting the ash at the exit of the reactor tube to form a plug of the ash at the exit; means for monitoring pressures at the entrance and the exit of the reactor tube; and means for maintaining a neutral atmospheric pressure in the reactor tube relative to pressure outside the reactor tube by monitoring and adjusting a volumetric rate of the fuel gas mixture withdrawn from the reactor tube based on the pressures at the entrance and the exit of the reactor tube. 3. The system according to claim 2 , wherein the reactor tube comprises first and second heating zones through which the biomass material travels in sequence, and the second heating zone is at a higher temperature than the first heating zone. 4. The system according to claim 2 , further comprising means for injecting a gasification agent into the reactor tube. 5. The system according to claim 4 , wherein the gasification agent is steam. 6. The system according to claim 4 , wherein the reactor tube comprises first and second heating zones through which the biomass material travels in sequence, the second heating zone is at a higher temperature than the first heating zone, and the gasification agent is introduced into the second heating zone within the reactor tube. 7. The system according to claim 2 , further comprising a hopper from which the biomass material is transported to the entrance of the reactor tube. 8. The system according to claim 2 , wherein the entrance of the reactor tube is flared to promote compaction of the biomass material within the entrance. 9. The system according to claim 2 , further comprising a manifold that the ash enters from the exit of the reactor tube, wherein the manifold is tapered to promote compaction of the ash within the exit of the reactor tube.
Biomass · CPC title
by filtration · CPC title
with storage facilities for intermediate, feed and/or product · CPC title
Details of feeding means · CPC title
with one stream being water/steam · CPC title
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