Method and system for purifying synthesis gas, in particular for ammonia synthesis

Patent metadata

Field	Value
Publication number	US-9464246-B2
Application number	US-201314414177-A
Country	US
Kind code	B2
Filing date	Jul 4, 2013
Priority date	Jul 12, 2012
Publication date	Oct 11, 2016
Grant date	Oct 11, 2016

Abstract

The invention relates to a method for purifying synthesis gas, in particular for ammonia synthesis, wherein a partial stream ( 26 ) of an H 2 -rich, CO-containing synthesis gas stream is burned, in particular to generate electrical energy, and wherein at least one component contained in the remaining H 2 -rich, CO-containing synthesis gas stream ( 26 a ), in particular in the form of carbon dioxide, methanol and/or water, is absorbed by an adsorber at low temperatures, after which said absorbed component is desorbed from the adsorber by flushing using nitrogen ( 33 ) at higher temperatures. According to the invention the H 2 -rich partial stream ( 26 ) is diluted using the nitrogen ( 35 ) used for the flushing before being burned. The invention further relates to a system ( 1 ) for purifying synthesis gas, in particular for ammonia synthesis.

First claim

The invention claimed is:

1. A method for purifying synthesis gas, said method comprising
combusting a partial stream ( 26 ) of an H 2 -rich, CO-containing synthesis gas stream
introducing the remaining H 2 -rich, CO-containing synthesis gas stream ( 26 a ), into an adsorber ( 14 ) wherein at least one component contained in the remaining H 2 -rich, CO-containing synthesis gas stream ( 26 a ) is adsorbed at low temperatures and
desorbing said at least one adsorbed component from the adsorber ( 14 ) by purging with nitrogen ( 33 ) at a temperature higher than the temperature used for adsorption of the at least one component, and at a pressure of 20 to 40 bar,
wherein, prior to combustion, said partial stream ( 26 ) of the H 2 -rich, CO-containing synthesis gas stream is diluted with the nitrogen used for purging ( 35 ) said adsorber ( 14 ).

2. The method as claimed in claim 1 , wherein nitrogen ( 31 ), which has not been used previously for purging the adsorber ( 14 ), is added to the H 2 -rich, CO-containing partial stream ( 26 ) prior to combustion, to dilute the H 2 -rich, CO-containing partial stream.

3. The method as claimed in claim 2 , wherein the nitrogen ( 31 ) used for dilution of the H 2 -rich, CO-containing partial stream is produced by cryogenic separation ( 17 ) of air.

4. The method as claimed in claim 1 , said H 2 -rich, CO-containing synthesis gas stream ( 26 a ) is obtained from a crude gas stream containing hydrogen and carbon monoxide ( 22 ) produced by gasification of carbon ( 21 ) by partial oxidation with oxygen ( 28 ).

5. The method as claimed in claim 4 , wherein before adsorption of said at least one component in said adsorber ( 14 ), sour gas contained in said crude gas stream ( 23 ) is washed out ( 13 ) by means of a detergent.

6. The method as claimed in claim 5 , wherein said sour gas contained in said crude gas stream comprises CO 2 , H 2 S and/or COS.

7. The method as claimed in claim 5 , wherein detergent is methanol.

8. The method as claimed in claim 4 , wherein said oxygen ( 28 ) for said partial oxidation is obtained from separation of air ( 17 ).

9. The method as claimed in claim 4 , further comprising subjecting said crude gas stream ( 22 ) to a water-gas shift reaction ( 12 ) wherein carbon monoxide contained in said crude gas stream ( 22 ) is reacted with H 2 O to produce hydrogen and carbon dioxide.

10. The method as claimed in claim 1 , further comprising, after adsorption of said at least one component in said adsorber ( 14 ), subjecting the H 2 -rich, CO-containing synthesis gas stream ( 26 a ) to liquid nitrogen scrubbing ( 15 ) to remove carbon monoxide and produce an H 2 -rich, CO-depleted synthesis gas stream ( 24 ).

11. The method as claimed in claim 10 , further comprising converting the H 2 -rich, CO-depleted synthesis gas stream ( 24 ) to ammonia ( 25 ).

12. The method as claimed in claim 10 , wherein said liquid nitrogen scrubbing is conducted at a temperature in the range from −185° C. to −193° C. and at a pressure in the range from 30 bar to 80 bar.

13. The method as claimed in claim 1 , wherein said at least one component contained in the remaining H 2 -rich, CO-containing synthesis gas stream ( 26 a ) is carbon dioxide, methanol and/or water.

14. The method as claimed in claim 1 , wherein said adsorber ( 14 ) is a temperature-swing adsorber, and adsorption of said at least one components is conducted at a temperature in the range from −70° to 45° C. and desorption is conducted at a temperature in the range from 150° C. to 250° C.

15. A system for purifying synthesis gas comprising:
a sour gas scrubber ( 13 ), which is configured for scrubbing a sour gas from a crude gas stream containing hydrogen and carbon monoxide ( 23 ), resulting in an H 2 -rich, CO-containing synthesis gas stream ( 26 a ),
a temperature-swing adsorption unit ( 14 ), arranged downstream of the sour gas scrubber ( 13 ), and configured for separating at least one component from the H 2 -rich, CO-containing synthesis gas stream ( 26 a ) by adsorption on an adsorber of the temperature-swing adsorption unit ( 14 ) at low temperatures and to regenerate the adsorber by purging with nitrogen at higher temperatures and at a pressure of 20 to 40 bar,
a nitrogen feed line ( 33 ) leading into the temperature-swing adsorption unit ( 14 ) for charging the temperature-swing adsorption unit ( 14 ) with the nitrogen required for purging the adsorber,
a nitrogen discharge line ( 35 ) of the temperature-swing adsorption unit ( 14 ), which is configured for withdrawing the nitrogen used for purging from the temperature-swing adsorption unit ( 14 ),
a combustion unit ( 18 ) configured for burning an H 2 -rich partial stream of the H 2 -rich, CO-containing synthesis gas stream for generating energy, and
a hydrogen feed line ( 26 ) connecting the sour gas scrubber ( 13 ) to the combustion unit ( 18 ), which is configured for conveying said H 2 -rich partial stream from the sour gas scrubber ( 13 ) into the combustion unit ( 18 ),
wherein said nitrogen discharge line ( 35 ) is connected to the hydrogen feed line ( 26 ) for diluting the H 2 -rich partial stream with nitrogen.

16. The system as claimed in claim 15 , wherein an air separation unit ( 17 ), which is configured for separating air into nitrogen and oxygen, the air separation unit being connected via the nitrogen feed line ( 33 ) to the temperature-swing adsorption unit ( 14 ), in order to convey nitrogen for purging the adsorber from the air separation unit ( 17 ) to the temperature-swing adsorption unit ( 14 ).

17. The system as claimed in claim 16 , wherein another nitrogen feed line ( 31 ) is provided, which is connected to the hydrogen feed line ( 26 ), so that nitrogen can be fed from the air separation unit ( 17 ), bypassing the temperature-swing adsorption unit ( 14 ), into the hydrogen feed line ( 26 ), to dilute the H 2 -rich partial stream with nitrogen.

18. The system as claimed in claim 15 , wherein a gasification reactor ( 11 ) is provided, which is configured, for producing said crude gas stream ( 22 ), to gasify carbon by means of partial oxidation with oxygen, and an oxygen feed line ( 28 ) is provided, which is configured for conveying the oxygen produced in the air separation unit ( 17 ) into the gasification reactor ( 11 ), and downstream of the gasification reactor ( 11 ) and downstream of the sour gas scrubber ( 12 ), a water gas-shift reactor ( 12 ) is provided, which is configured for reacting carbon monoxide contained in the crude gas stream ( 22 ) by a water-gas shift reaction with H 2 O to hydrogen and carbon dioxide.

19. The system as claimed in claim 15 , wherein downstream of the temperature-swing adsorption unit ( 14 ), a liquid nitrogen scrubbing unit ( 15 ) is provided, which is configured for washing out carbon monoxide from the H 2 -rich, CO-containing synthesis gas stream with liquid nitrogen for producing an H 2 -rich and correspondingly CO-depleted synthesis gas stream ( 24 ).

Assignees

• Linde Ag

Inventors

• Klein Bernd
• Heinzel Albrecht

Classifications

• C01B2203/042

  Purification by adsorption on solids · CPC title

• C10J2300/1846

  Partial oxidation, i.e. injection of air or oxygen only · CPC title

• C10J2300/0959

  Oxygen · CPC title

• C10J2200/15

  Details of feeding means · CPC title

• C10J2300/1612

  CO2-separation and sequestration, i.e. long time storage · CPC title