Method for producing sic single crystal having low defects by solution process

Patent metadata

Field	Value
Publication number	US-10087549-B2
Application number	US-201415021762-A
Country	US
Kind code	B2
Filing date	Sep 1, 2014
Priority date	Sep 13, 2013
Publication date	Oct 2, 2018
Grant date	Oct 2, 2018

Abstract

A SiC single crystal having low density of threading screw dislocations, threading edge dislocations, micropipe defects, base plane dislocations and stacking faults is provided. This is achieved by a method for producing a SiC single crystal in which a SiC seed crystal substrate is contacted with a Si—C solution having a temperature gradient such that the temperature decreases from the interior toward the surface, to grow a SiC single crystal, the method including: a first step in which a SiC single crystal is grown with a (1-100) plane as the growth surface, a second step in which a {0001} plane is exposed from the grown SiC single crystal, and a third step in which the SiC single crystal having the exposed {0001} plane is used as a seed crystal, and the {0001} plane is used as the growth surface for growth of a SiC single crystal.

First claim

What is claimed is:

1. A method for producing a SiC single crystal in which a SiC seed crystal substrate is contacted with a Si—C solution having a temperature gradient such that the temperature decreases from the interior toward the surface, to grow a SiC single crystal, the method consisting of:
a first step in which a SiC single crystal is grown with a (1-100) plane as the growth surface,
a second step in which a {0001} plane is exposed from the grown SiC single crystal, and
a third step in which the SiC single crystal having the exposed {0001} plane is used as a seed crystal, and the {0001} plane is used as the growth surface for growth of a SiC single crystal,
wherein the first, second, and third steps are performed sequentially,
wherein in the first step, the temperature gradient in the surface region of the Si—C solution is increased at least once during growth of the SiC single crystal, and
when the temperature gradient is increased in the first step, the SiC single crystal is continuously grown and the temperature gradient is increased so that an original crystal growth rate is not exceeded.

2. The method according to claim 1 , wherein the {0001} plane is a (000-1) plane.

3. The method according to claim 1 , wherein the Si—C solution used in the first step and the third step has the same composition.

4. The method according to claim 1 , wherein the Si—C solution used in the first step and the third step contains Si and Cr.

5. The method according to claim 1 , wherein at least one of the first step and the third step includes:
(A) a step in which a SiC crystal is grown from a seed crystal,
(B) a step in which at least part of polycrystalline sections and/or low crystalline single crystal sections is removed from the side faces with respect to the growth direction of the SiC crystal grown in step (A) or step (C), and
(C) a step in which a SiC crystal is grown from the SiC crystal grown in step (A) or the SiC crystal obtained in step (B), and
wherein step (B) and step (C) are carried out one or more times.

6. The method according to claim 1 , wherein in the first step,
the temperature gradient in the surface region of the Si—C solution is no greater than 10° C./cm, and
the ratio of the growth rate of the SiC single crystal with respect to the temperature gradient (single crystal growth rate/temperature gradient) is less than 20×10 −4 cm 2 /h·° C.

Assignees

• Toyota Motor Co Ltd

Inventors

• Danno Katsunori

Classifications

• C30B19/12 Primary

  characterised by the substrate · CPC title

• C30B19/04

  the solvent being a component of the crystal composition · CPC title

• C30B29/36

  Carbides · CPC title