Rare earth based magnet

Patent metadata

Field	Value
Publication number	US-10083783-B2
Application number	US-201414579315-A
Country	US
Kind code	B2
Filing date	Dec 22, 2014
Priority date	Dec 20, 2013
Publication date	Sep 25, 2018
Grant date	Sep 25, 2018

Abstract

The present invention provides a rare earth based magnet in which the demagnetization rate at a high temperature can be inhibited even if the amount of heavy rare earth element(s) such as Dy and Tb is evidently decreased compared to the past or no such heavy rare earth element is used. The rare earth based magnet of the present invention is a sintered magnet which comprises R 2 T 14 B crystal grains as the main phases and the crystal boundary phases among R 2 T 14 B crystal grains. The microstructure of the sintered body is controlled by at least containing the first crystal boundary phases and the second crystal boundary phases, wherein the first crystal boundary phases contain at least R-T-M in the ranges of 20 to 40 atomic % for R, 60 to 75 atomic % for T and 1 to 10 atomic % for M, and the second crystal boundary phases contains at least R-T-M in the ranges of 50 to 70 atomic % for R, 10 to 30 atomic % for T and 1 to 20 atomic % for M.

First claim

What is claimed is:

1. A rare earth based magnet, comprising,
R 2 T 14 B main phase crystal grains and crystal boundary phases, with at least a first crystal boundary phase and a second crystal boundary phase being contained,
wherein, the first crystal boundary phase contains at least R-T-M in the following ranges,
R: 20 to 40 atomic %,
T: 60 to 75 atomic %,
M: 1 to 10 atomic %;
the second crystal boundary phase contains at least R-T-M in the following ranges,
R: 50 to 70 atomic %,
T: 10 to 30 atomic %,
M: 1 to 20 atomic %;
R represents the rare earth element, T represents at least one iron family element with Fe as essential, and M represents at least one element selected from the group consisting of Al, Ge, Si, Sn and Ga;
the rare earth based magnet contains O, C, and N, and
the numbers of O, C, and N atoms contained in the rare earth based magnet are referred to as [O], [C], and [N], in which
[O]/([C]+[N])<0.60, and

an absolute value of a demagnetization rate D at a high temperature is inhibited to 4% or less, in which
D=100×(B1−B0)/B0(%),

B0: residual magnetic flux at room temperature (25° C.), and
B1: residual magnetic flux brought back to room temperature after being exposed to a temperature of 140° C. for 2 hours.

2. The rare earth based magnet of claim 1 , wherein,
the ratio of the area of said first crystal boundary phase to the area of said second crystal boundary phases is 0.5 or more at any section having about 200 main phase grains.

3. The rare earth based magnet of claim 1 , wherein,
the rare earth based magnet contains Nd, Pr, B, C, and M, and
the numbers of Nd, Pr, B, C, and M atoms contained in the rare earth based magnet are referred to as [Nd], [Pr], [B], [C] and [M], in which
0.27<[B]/([Nd]+[Pr])<0.40 and 0.07<([M]+[C])/[B]<0.60.

4. The rare earth based magnet of claim 1 , wherein, the second crystal boundary phase contains R in the following range,
R: 54.3 to 66.3 atomic %.

5. The rare earth based magnet of claim 1 , wherein, the ratio of the area of said first crystal boundary phase to the area of said second crystal boundary phases is 0.5 or more to 3.5 or less at any section having about 200 main phase grains.

Assignees

• Tdk Corp

Inventors

• Fujikawa Yoshinori
• Nagamine Yuki
• Okawa Wakako
• Ishizaka Chikara
• Kato Eiji
• Sato Katsuo

Classifications

• H01F1/057 Primary

  and IIIa elements, e.g. Nd2Fe14B · CPC title

• H01F1/0577 Primary

  sintered · CPC title