Method for on-line imaging of mesophase particles

Patent metadata

Field	Value
Publication number	US-10072219-B2
Application number	US-201815870864-A
Country	US
Kind code	B2
Filing date	Jan 13, 2018
Priority date	Aug 2, 2016
Publication date	Sep 11, 2018
Grant date	Sep 11, 2018

Abstract

On-line detection of mesophase particles employs a laser diode light source to illuminate a target area with a pulsed laser linearly or circularly polarized probe beam. Analysis of images determines extent of presence the birefringent mesophase particles, which are precursors to coking in catalytic hydrocracking processes. The inherently polarized low-coherence, unfocused but sufficiently collimated, pulsed laser beam yield sharp imaging with high depth of field of very small mesophase particles that are present in a moving, dark reactor liquid environment.

First claim

What is claimed is:

1. A method of converting a heavy hydrocarbon feed into light hydrocarbon products comprising the steps of:
(a) mixing a heavy hydrocarbons liquid feed with catalyst particles to form a slurry;
(b) hydrocracking heavy hydrocarbons in the slurry in the presence of hydrogen in a reactor to produce a hydrocracked slurry product comprising lighter hydrocarbon products wherein the slurry product is withdrawn from the reactor;
(c) monitoring mesophase particles in the reactor by (i) directing a pulsed laser probe beam from a laser diode light source along a first beam path into a continuous reactor fluid stream wherein the probe beam comprises linearly polarized light such that an output beam emerges from the continuous reactor fluid stream along a second beam path, (ii) obtaining an image of the mesophase particles in the continuous reactor fluid stream, and (iii) analyzing the image to determine at least one of volume fraction or size distribution of mesophase particles in the continuous reactor fluid stream; and
(d) adjusting reactor conditions to reduce levels of mesophae particles formed during hydrocracking.

2. The method of claim 1 wherein the laser diode light source generates a pulsed laser probe beam without employing a polarizer filter.

3. A method of converting a heavy hydrocarbon feed into light hydrocarbon products comprising the steps of:
(a) mixing a heavy hydrocarbons liquid feed with catalyst particles to form a slurry;
(b) hydrocracking heavy hydrocarbons in the slurry in the presence of hydrogen in a reactor to produce a hydrocracked slurry product comprising lighter hydrocarbon products wherein the slurry product is withdrawn from the reactor;
(c) monitoring mesophase particles in the reactor by (i) directing a pulsed laser probe beam from a laser diode light source along a first beam path into a continuous reactor fluid stream wherein the probe beam comprises circularly polarized light and a quarter-wave plate converts linearly polarized light from the laser diode light source into circularly polarized light such that an output beam emerges from the continuous reactor fluid stream along a second beam path, (ii) obtaining an image of the mesophase particles in the continuous reactor fluid stream, and (iii) analyzing the image to determine at least one of volume fraction or size distribution of mesophase particles in the continuous reactor fluid stream; and
(d) adjusting reactor conditions to reduce levels of mesophae particles formed during hydrocracking.

4. The method of claim 1 wherein the probe beam is reflected from a target area in the reactor fluid stream to form the output beam.

5. The method of claim 1 wherein the probe beam is transmitted through a target area in the reactor fluid stream to form the output beam.

6. The method of claim 1 wherein the probe beam illuminates a target area in the reactor fluid stream that is about 20 to 25 sq. mm.

7. The method of claim 1 wherein the laser diode light source comprises a plurality of laser bars wherein each laser bar comprises one or more laser diodes and wherein the laser bars each emit a laser beam that is multiplexed to form the pulsed laser probe beam.

8. The method of claim 7 wherein each laser bar emits light of a different wavelength.

9. The method of claim 3 wherein the laser diode light source generates a pulsed laser probe beam without employing a polarizer filter.

10. The method of claim 3 wherein the probe beam is reflected from a target area in the reactor fluid stream to form the output beam.

11. The method of claim 3 wherein the probe beam is transmitted through a target area in the reactor fluid stream to form the output beam.

12. The method of claim 3 wherein the probe beam illuminates a target area in the reactor fluid stream that is about 20 to 25 sq. mm.

13. The method of claim 3 wherein the laser diode light source comprises a plurality of laser bars wherein each laser bar comprises one or more laser diodes and wherein the laser bars each emit a laser beam that is multiplexed to form the pulsed laser probe beam and wherein each laser bar emits light of a different wavelength.

14. A method of converting a heavy hydrocarbon feed into light hydrocarbon products comprising the steps of:
(a) mixing a heavy hydrocarbons liquid feed with catalyst particles to form a slurry;
(b) hydrocracking heavy hydrocarbons in the slurry in the presence of hydrogen in a reactor to produce a hydrocracked slurry product comprising lighter hydrocarbon products wherein the slurry product is withdrawn from the reactor;
(c) monitoring mesophase particles in the reactor by (i) directing a pulsed laser probe beam from a laser diode light source along a first beam path into a target area in a continuous reactor fluid stream, wherein the target area is about 20 to 25 sq. mm, and wherein the probe beam comprises linearly polarized light or circularly polarized light such that an output beam emerges from the continuous reactor fluid stream along a second beam path, (ii) obtaining an image of the mesophase particles in the continuous reactor fluid stream, and (iii) analyzing the image to determine at least one of volume fraction or size distribution of mesophase particles in the continuous reactor fluid stream; and
(d) adjusting reactor conditions to reduce levels of mesophae particles formed during hydrocracking.

15. The method of claim 14 wherein the laser diode light source generates a pulsed laser probe beam without employing a polarizer filter.

16. The method of claim 14 wherein the laser diode light source comprises a plurality of laser bars wherein each laser bar comprises one or more laser diodes and wherein the laser bars each emit a laser beam that is multiplexed to form the pulsed laser probe beam.

17. The method of claim 16 wherein each laser bar emits light of a different wavelength.

18. A method of converting a heavy hydrocarbon feed into light hydrocarbon products comprising the steps of:
(a) mixing a heavy hydrocarbons liquid feed with catalyst particles to form a slurry;
(b) hydrocracking heavy hydrocarbons in the slurry in the presence of hydrogen in a reactor to produce a hydrocracked slurry product comprising lighter hydrocarbon products wherein the slurry product is withdrawn from the reactor;
(c) monitoring mesophase particles in the reactor by (i) directing a pulsed laser probe beam from a laser diode light source along a first beam path into a continuous reactor fluid stream wherein the probe beam comprises linearly polarized light or circularly polarized light such that an output beam emerges from the continuous reactor fluid stream along a second beam path, wherein the laser diode light source comprises a plurality of laser bars wherein each laser bar comprises one or more laser diodes and wherein the laser bars each emit a laser beam that is multiplexed to form the pulsed laser probe beam and wherein each laser bar emits light of a different wavelength (ii) obtaining an image of the mesophase particles in the continuous reactor fluid stream, and (iii) analyzing the image to determine at least one of volume fraction or size distribution of mesophase particles in the continuous reactor fluid stream; and
(d) adjusting reactor conditions to reduce levels of mesophae particles formed during hydrocracking.

19. The method of claim 18 wherein the laser diode light source generates a pulsed laser probe beam without employing a polarizer filter.

20. The method of claim 18 wherein the probe beam illuminat

Assignees

• Honeywell Ltd

Inventors

• Kellomaki Markku

Classifications

• C10G47/02

  characterised by the catalyst used · CPC title

• G01N15/0205

  by optical means · CPC title

• C10G47/36 Primary

  Controlling or regulating · CPC title

• G01N2015/0693

  Physics · mapped topic

• G01N15/06

  Investigating concentration of particle suspensions (by weighing G01N5/00; investigating sedimentation of particle suspensions G01N15/04; investigating individual particles G01N15/10) · CPC title