Method for monitoring performance of process catalysts

Patent metadata

Field	Value
Publication number	US-9429532-B2
Application number	US-201615062965-A
Country	US
Kind code	B2
Filing date	Mar 7, 2016
Priority date	May 20, 2010
Publication date	Aug 30, 2016
Grant date	Aug 30, 2016

Abstract

Disclosed is a method for determining when to replace a guard bed material used to remove one or more catalyst poisons from a feed based on a parameter change in a process. A guard bed having a guard bed material is in fluid communication with a catalyst bed having a catalyst. At least three monitors are positioned in said guard bed or said catalyst bed and at least one parameter of the guard bed or catalyst bed is monitored. A feed component comprising one or more catalyst poisons is supplied to said guard bed or said catalyst bed. The feed is contacted with said guard bed material or said catalyst to remove at least a portion of a catalyst poison and to form a product which produces an increase or a decrease in said parameter. The monitored parameters are compared to determine when to replace the guard bed material.

First claim

The invention claimed is:

1. A method for determining when to replace a guard bed material used to remove a catalyst poison from an alkylation feed based on a temperature change in an alkylation process, said method comprising the steps of:
(a) providing a guard bed comprising a guard bed material;
(b) providing an alkylation catalyst bed located downstream of and in fluid communication with said guard bed, wherein said alkylation catalyst bed has an inlet, and a downstream outlet;
(c) loading an alkylation catalyst in said alkylation catalyst bed such that said alkylation catalyst extends from said inlet to said outlet of said catalyst bed;
(d) placing at least three alkylation catalyst bed monitors proximate said alkylation catalyst bed, wherein a first alkylation catalyst bed monitor is located upstream of said inlet to said alkylation catalyst bed, a second alkylation catalyst bed monitor is located downstream of said inlet and upstream of said outlet of said alkylation catalyst bed, and a third alkylation catalyst bed monitor is located downstream of said second alkylation catalyst bed monitor;
(e) monitoring the temperature of said alkylation catalyst bed with each of said alkylation catalyst bed monitors;
(f) at least intermittently supplying said alkylation feed to said guard bed and said alkylation catalyst bed, wherein said alkylation feed comprises an alkylatable aromatic component, an alkylating agent component and a catalyst poison;
(g) contacting said alkylation feed with said guard bed material under suitable guard bed treatment conditions to remove at least a portion of said catalyst poison from said alkylation feed and to form a treated alkylation feed comprising an alkylated aromatic component;
(h) contacting said treated alkylation feed with said alkylation catalyst under suitable alkylation conversion conditions to form a product, wherein said contacting produces an increase in said alkylation catalyst bed temperature;
(i) determining a first alkylation catalyst bed delta as the absolute value of the difference between said alkylation catalyst bed temperature at said first alkylation catalyst bed monitor and said alkylation catalyst bed temperature at said third alkylation catalyst bed monitor;
(j) determining a second alkylation catalyst bed delta as the absolute value of the difference between said alkylation catalyst bed temperature at said first alkylation catalyst bed monitor and said alkylation catalyst bed temperature at said second alkylation catalyst bed monitor; and
(k) replacing said guard bed material when the ratio of said second alkylation catalyst bed delta to said first alkylation catalyst bed delta is less than 1.

2. The method of claim 1 , wherein said second catalyst bed monitor is placed at 1%, 5%, or 10% of the distance measured from said inlet to said outlet of said catalyst bed.

3. The method of claim 1 , wherein said ratio of said second catalyst bed delta to said first catalyst bed delta is selected from the group consisting of 0.9, 0.8, and 0.7.

4. The method of claim 1 , wherein said catalyst poison comprises an impurity having at least one of the following elements: nitrogen, halogens, oxygen, sulfur, arsenic, selenium, tellurium, phosphorus, and Group 1 through Group 12 metals.

5. The method of claim 1 , wherein said alkylation catalyst is selected from the group consisting of zeolite beta, faujasite, zeolite Y, Ultrastable Y (USY), Dealuminized Y (Deal Y), Rare Earth Y (REY), Ultrahydrophobic Y (UHP-Y), mordenite, TEA-mordenite, ZSM-3, ZSM-4, ZSM-14, ZSM-18, ZSM-20, and combinations thereof.

6. The method of claim 1 , wherein said guard bed material is a solid acid.

7. The method of claim 6 , wherein said solid acid is selected from the group consisting of acidic aluminas, acidic silica-aluminas, acidic clays, acidic zeolites, and acidic mesoporous aluminosilicates.

8. The method of claim 6 , wherein said solid acid comprises a molecular sieve selected from the group consisting of ZSM-5, ZSM-11, ZSM-35, clinoptilolite, ferrierite, stilbite, EU-1, NU-87, mordenite, omega, beta, faujasites, gmelinite, ZSM-12, cancrinite, and zeolite L.

9. The method of claim 1 , wherein said alkylatable aromatic component comprises benzene.

10. The method of claim 9 , wherein said alkylating agent component comprises ethylene and said alkylated aromatic component comprises ethylbenzene.

11. The method of claim 9 , wherein said alkylating agent component comprises propylene and said alkylated aromatic component comprises cumene.

12. The method of claim 9 , wherein said alkylating agent component comprises butene and said alkylated aromatic component comprises sec-butyl benzene.

13. The method of claim 1 , wherein said alkylation catalyst comprises a MCM-22 family material.

14. The method of claim 13 , wherein said MCM-22 family material comprises a molecular sieve having unit cells of MWW framework topology.

15. The method of claim 14 , wherein said molecular sieve having unit cells of MWW framework topology is characterized by an X-ray diffraction pattern, including d-spacing maxima at 12.4±0.25, 3.57±0.07, and 3.42±0.07 Angstroms.

16. The method of claim 14 , wherein said MCM-22 family material is selected from the group consisting of ERB-1, ITQ-1, ITQ-2, ITQ-30, PSH-3, SSZ-25, MCM-22, MCM-36, MCM-49, MCM-56, UZM-8, EMM-10, EMM-10P, EMM-12, EMM-13, and mixtures thereof.

Assignees

• Exxonmobil Chemical Patents Inc

Inventors

• Vincent Matthew J
• Fletcher David L
• Nanda Vijay

Classifications

• B01J29/7038

  MWW-type, e.g. MCM-22, ERB-1, ITQ-1, PSH-3 or SSZ-25 · CPC title

• C10G2300/205

  Metal content · CPC title

• G01N25/00 Primary

  Investigating or analyzing materials by the use of thermal means (G01N3/00 - G01N23/00 take precedence) · CPC title

• C10G29/205

  by reaction with hydrocarbons added to the hydrocarbon oil · CPC title

• C10G2300/202

  Heteroatoms content, i.e. S, N, O, P · CPC title