Phosphor and light-emitting equipment using phosphor

Patent metadata

Field	Value
Publication number	US-10072207-B2
Application number	US-201715626372-A
Country	US
Kind code	B2
Filing date	Jun 19, 2017
Priority date	Nov 26, 2003
Publication date	Sep 11, 2018
Grant date	Sep 11, 2018

Abstract

Phosphors include a CaAlSiN 3 family crystal phase, wherein the CaAlSiN 3 family crystal phase comprises at least one element selected from the group consisting of Mn, Ce, Pr, Nd, Sm, Eu, Tb, Dy, Ho, Er, Tm, and Yb.

First claim

What is claimed is:

1. A light source, comprising:
a light-emitting source; and
at least one phosphor;
wherein:
the phosphor comprises an inorganic compound which is a composition containing at least M Element, A Element, D Element, E Element, and X Element;
the M Element is one or two or more elements selected from the group consisting of Mn, Ce, Pr, Nd, Sm, Eu, Tb, Dy, Er, Tm, and Yb;
the A Element is one or two or more elements selected from the group consisting of divalent metal elements other than M Element;
the D Element is one or two or more elements selected from the group consisting of tetravalent metal elements;
the E Element is one or two or more elements selected from the group consisting of trivalent metal elements;
the X Element is one or two or more elements selected from the group consisting of O, N, and F; and
the inorganic compound is a composition given by:
M a A b D c E d X e

where:
a+b=1;
0.00001≤a≤0.1;
0.5≤c≤1.8;
0.5≤d≤1.8;
0.8×(2/3+4/3×c+d)≤e; and
e≤1.2×(2/3+4/3×c+d.

2. The light source according to claim 1 , wherein the inorganic compound has at least one of:
the same crystal structure as CaAlSiN 3 ; and
the same X-ray diffraction pattern as CaAlSiN 3 .

3. The light source according to claim 2 , wherein:
the inorganic compound has the same X-ray diffraction pattern as CaAlSiN 3 ; and
the X-ray diffraction pattern of the inorganic compound exhibits at least ten peaks present in the X-ray diffraction pattern of CaAlSiN 3 .

4. The light source according to claim 1 , wherein the A element is at least one divalent element selected from the group consisting of Mg, Ca, Sr, and Ba.

5. The light source according to claim 1 , wherein the A element is at least one divalent element selected from the group consisting of Ca and Sr.

6. The light source according to claim 1 , wherein the D element is
at least one tetravalent element selected from the group consisting of Si, Ge, Sn, Ti, Zr, and Hf.

7. The light source according to claim 1 , wherein the D element is
at least one tetravalent element selected from the group consisting of Si, Ge, Ti, Zr, and, Hf.

8. The light source according to claim 1 , wherein the E element is
at least one trivalent element selected from the group consisting of B, Al, Ga, In, Sc, Y, La, Gd, and Lu.

9. The light source according to claim 1 , wherein the E element is
at least one trivalent element selected from the group consisting of Al, Sc, and Y.

10. The light source according to claim 1 , wherein the inorganic compound comprises at least Eu, Ca, Al, Si, and N.

11. The light source according to claim 1 , wherein the X element is at least one element selected from the group consisting of O and N.

12. The light source according to claim 11 , wherein the inorganic compound comprises 0 and N in amounts satisfying:
0.5≤(number of atoms of N)/{(number of atoms of N)+(number of atoms of O)}≤1.

13. The light source according to claim 1 , wherein the inorganic compound comprises Ca and Sr in amounts satisfying:
0.02≤(number of atoms of Ca)/{(number of atoms of Ca)+(number of atoms of Sr)}<1.

14. The light source according to claim 1 , wherein, when irradiated by an excitation source, the phosphor emits light having a peak emission intensity at a wavelength of from 15 nm to 700 nm.

15. The light source according to claim 1 , wherein, when irradiated by an excitation source, the phosphor emits light having a color satisfying:
0.45 ≤x≤ 0.7

as a value of (x, y) on the CIE chromaticity coordinates.

16. The light source according to claim 1 , wherein the inorganic compound comprises impurity elements of Fe, Co, and N amount of 50 ppm or less.

17. The light source according to claim 1 , wherein:
the phosphor comprises the inorganic compound and a further crystal phase or amorphous phase; and
the inorganic compound is present in an amount of at least 20% by weight based on a total weight of the inorganic compound and the further crystal phase or amorphous phase.

18. Lighting equipment, comprising the light source according to claim 1 .

19. An image display unit, comprising the light source according to claim 1 .

Assignees

• Mitsubishi Chem Corp
• Nat Inst Materials Science
• Nichia Corp
• Citizen Electronics
• Citizen Electronics

Inventors

• Hirosaki Naoto
• Ueda Kyota
• Yamamoto Hajime

Classifications

• H10W90/756

  between a chip and a stacked lead frame, conducting package substrate or heat sink · CPC title

• H10W74/00

  Encapsulations, e.g. protective coatings · CPC title

• H10W72/884

  Die-attach connectors and bond wires · CPC title

• C04B2235/3262

  Manganese oxides, manganates, rhenium oxides or oxide-forming salts thereof, e.g. MnO · CPC title

• C01B21/0821

  Oxynitrides of metals, boron or silicon · CPC title