Coating composition and articles made therefrom

Patent metadata

Field	Value
Publication number	US-9598601-B2
Application number	US-201113983921-A
Country	US
Kind code	B2
Filing date	Mar 2, 2011
Priority date	Mar 2, 2011
Publication date	Mar 21, 2017
Grant date	Mar 21, 2017

Abstract

The instant invention provides an aqueous dispersion, a coating composition, coating layers and coated article made therefrom. The coating composition according to the present invention comprises: (1) the inventive aqueous dispersion comprising the melt blending product of: (a) from 50 to 99 percent by weight of one or more polyethylene terephthalate resins, based on the total solid content of the dispersion; (b) from 1 to 50 percent by weight of one or more stabilizing agents comprising at least one second polyester, based on the total solid content of the dispersion, wherein said second polyester (i) has a carboxylic acid group and an acid number equal to or greater than 15, based on the solid content of the second polyester; or (ii) is a self-dispersing sulfopolyester; (c) one or more neutralizing agents; and (d) from 15 to 90 percent by weight of water, based on the total weight of the dispersion; wherein said dispersion has a solid content of 10 to 85 percent, based on the total weight of the dispersion; and (2) optionally one or more cross-linking agents.

First claim

We claim:

1. An aqueous dispersion comprising the melt blending product of:
(a) from 50 to 99 percent by weight of one or more polyethylene terephthalate resins, based on the total solid content of the dispersion, wherein the one or more polyethylene terephthalate having an acid number of less than 5 mg KOH/g, a glass transition temperature (Tg) in the range of from 50 to 130° C., a heat distortion temperature according to ASTM D648@264 psi (1.82 MPa) in the range of from 60 to 120° C., and an intrinsic viscosity in the range of from 0.5 to 1.0 Dl/g as measured at 25° C., in a solvent mixture consisting of 60 wt % phenol and 40 wt % tetrachloroethane;
(b) from 1 to 50 percent by weight of one or more stabilizing agents comprising at least one second polyester, based on the total solid content of the dispersion, wherein said second polyester has a carboxylic acid group and an acid number in the range of from 20 to 80 mg KOH/g, based on the solid content of the second polyester;
(c) optionally one or more neutralizing agents; and
(d) from 15 to 90 percent by weight of water, based on the total weight of the dispersion;
wherein said dispersion has a solid content of 10 to 85 percent, based on the total weight of the dispersion, and wherein the volume average particle size of the dispersion is less than 5 microns.

2. A coating composition comprising:
the aqueous dispersion of claim 1 ;
optionally one or more cross-linking agents;
optionally one or more cross-linking catalysts;
optionally one or more solvents;
optionally one or more selected from the group consisting of a polyolefin dispersion, acrylic latex, alkyd dispersion, epoxy resin dispersion, polyurethane dispersion, vinyl acetate dispersion, and ethylene vinyl acetate dispersion; and
optionally one or more additives.

3. A method for making a coated article comprising the steps of:
selecting a substrate;
selecting the coating composition of claim 2 ;
applying said coating composition to at least one surface of said substrate;
removing at least a portion of the water from said the coating composition;
thereby forming one or more coating layers associated with said substrate; and
forming said coated substrate into a coated article.

4. A method for making a coated article comprising the steps of:
selecting a substrate;
forming said substrate into article;
selecting the coating composition of claim 2
applying said the coating composition to at least one surface of said article;
removing at least a portion of the water from said the coating composition;
thereby forming one or more coating layers associated with at least one surface of said article; and
thereby forming said coated article.

5. A can or coil coating composition comprising the coating composition of claim 2 .

6. A coating layer comprising one or more film layers derived from the dispersion of claim 1 or the coating composition of claim 2 .

7. A coated article comprising:
one or more substrates;
at least one or more coating layers derived from the dispersion of claim 1 or the coating composition of claim 2 .

8. The coated article of claim 7 , wherein said substrate is a pre-coated substrate.

9. A method for producing a aqueous dispersion comprising the steps of:
selecting one or more polyethylene terephthalate resins, wherein the one or more polyethylene terephthalate having an acid number of less than 5 mg KOH/g, a glass transition temperature (Tg) in the range of from 50 to 130° C., a heat distortion temperature according to ASTM D648@264 psi (1.82 MPa) in the range of from 60 to 120° C., and an intrinsic viscosity in the range of from 0.5 to 1.0 Dl/g as measured at 25° C., in a solvent mixture consisting of 60 wt % phenol and 40 wt % tetrachloroethane;
selecting one or more stabilizing agents comprising at least one second polyester, wherein said second polyester wherein said second polyester has a carboxylic acid group and an acid number in the range of from 20 to 80 mg KOH/g, based on the solid content of the second polyester;
optionally selecting one or more neutralizing agents;
melt-blending said one or more polyethylene terephthalate resins, one or more stabilizing agents in the presence of water and optionally one or more neutralizing agents; and
thereby producing an aqueous dispersion having a solid content of 10 to 85 percent, based on the total weight of the dispersion, and wherein the volume average particle size of the dispersion is less than 5 microns.

Assignees

• Malotky David L
• Kainz Bernhard
• Diehl Charles F
• Lindenmuth Denise
• Young Timothy J
• Argyropoulos John N
• Dow Global Technologies Llc
• Rohm & Haas

Inventors

• Malotky David L
• Kainz Bernhard
• Diehl Charles F
• Lindenmuth Denise
• Young Timothy J
• Argyropoulos John N

Classifications

• B05D2401/20

  Aqueous dispersion or solution · CPC title

• Y10T428/31786

  Of polyester [e.g., alkyd, etc.] · CPC title

• C08L2205/03

  containing three or more polymers in a blend · CPC title

• C09D123/08

  Copolymers of ethene (C09D123/16 takes precedence) · CPC title

• C09D131/04

  Homopolymers or copolymers of vinyl acetate · CPC title